Cobalt contact and interconnect structures
View Patent ↗Methods and structures for forming cobalt contact and/or cobalt interconnects includes depositing a stress control layer onto the cobalt layer prior to annealing after which the stress control layer can be removed. The stress control layer prevents formation of defects that can occur in the absence of the stress control layer.
1. An intermediate semiconductor structure, comprising:
a patterned interlayer dielectric overlaying a semiconductor substrate, wherein the patterned interlayer dielectric comprises at least one opening extending through the interlayer dielectric to the semiconductor substrate;
a cobalt metal filling the at least one opening; and
a stress control layer on top of the cobalt metal filling, wherein the cobalt metal filling is substantially void free subsequent to an annealing process with the stress control layer on top of the cobalt metal filling
wherein an aspect ratio of a height and a width of the at least one opening is at least about 10:1.