Multi-layer plasma resistant coating by atomic layer deposition
Described herein are articles, systems and methods where a plasma resistant coating is deposited onto a surface of a chamber component using an atomic layer deposition (ALD) process. The plasma resistant coating has a stress relief layer and a rare earth metal-containing oxide layer and uniformly covers features, such as those having an aspect ratio of about 3:1 to about 300:1.
1. An article comprising:
a portion having an aspect ratio of length to diameter of about 3:1 to about 300:1; and
a plasma resistant coating on a surface of the portion of the article, wherein the plasma resistant coating comprises:
a stress relief layer having a thickness of about 10 nm to about 1.5 μm; and
a stack of alternating layers of a rare earth metal-containing oxide and a second oxide, the stack of alternating layers comprising:
a plurality of layers of the rare earth metal-containing oxide each having a thickness of about 1 angstrom to about 100 angstroms and having a polycrystalline or amorphous structure; and
a plurality of layers of the second oxide each having a thickness of about 0.5 angstroms to about 4 angstroms,
wherein the rare earth metal-containing oxide naturally occurs in a crystalline structure, wherein the plurality of layers of the second oxide cause the plurality of layers of the rare earth metal-containing oxide to have the polycrystalline or amorphous structure rather than the crystalline structure, and wherein a thickness ratio of the plurality of layers of the rare earth metal-containing oxide to the plurality of layers of the second oxide is 2:1 to 25:1; and
wherein the plasma resistant coating uniformly covers the portion, is resistant to cracking and delamination at a temperature of up to 350° C. and is porosity-free.
2. The article of claim 1 , wherein the article is a chamber component selected from a group consisting of a chamber wall, a plasma generation unit, a shower head, a diffuser, a nozzle, gas distribution hub assembly and a gas line.
3. The article of claim 2 , wherein the article is a chamber component selected from a group consisting of a plasma generation unit, a shower head, a diffuser, a nozzle and a gas distribution hub assembly.
4. The article of claim 1 , wherein the aspect ratio is about 10:1 to about 200:1.
5. The article of claim 1 , wherein the stress relief layer comprises amorphous Al 2 O 3 , and wherein the stress relief layer is a barrier to prevent diffusion of impurities from the article.
6. The article of claim 1 , wherein the rare earth metal-containing oxide layer comprises a mixture of about 0.1 mol % to about 90 mol % Y 2 O 3 and about 0.1 mol % to about 90 mol % of another metal oxide.
7. The article of claim 1 , wherein:
the layers of the second oxide have a same material composition as the stress relief layer;
the stress relief layer has a thickness of about 10 nm-1.5 μm; and
the stack of alternating layers has a total thickness of about 10 nm-1.5 μm.
8. The article of claim 1 , wherein the rare earth metal-containing oxide layer comprises a material having a naturally crystalline structure selected from a group consisting of Y 2 O 3 , Y 3 Al 5 O 12 (YAG), Er 2 O 3 , Er 3 Al 5 O 12 (EAG), Gd 2 O 3 , a solid solution of Y 2 O 3 —ZrO 2 comprising 10 mol % to 90 mol % Y 2 O 3 and 10 mol % to 90 mol % ZrO 2 , and a ceramic compound comprising Y 4 Al 2 O 9 and a solid-solution of Y 2 O 3 —ZrO 2 .
9. A method comprising:
depositing a plasma resistant coating onto a surface of a chamber component using an atomic layer deposition process, comprising:
depositing a stress relief layer on the surface using atomic layer deposition to a thickness of about 10 nm to about 1.5 μm; and
depositing a stack of alternating layers of a rare-earth metal-containing oxide and a second oxide on the stress relief layer using atomic layer deposition, the stack of alternating layers comprising:
a plurality of layers of the rare earth metal-containing oxide each having a thickness of about 1 angstrom to about 100 angstroms and having a polycrystalline or amorphous structure; and
a plurality of layers of the second oxide each having a thickness of about 0.5 angstroms to about 4 angstroms,
wherein the rare earth metal-containing oxide naturally occurs in a crystalline structure, wherein the plurality of layers of the second oxide cause the plurality of layers of the rare earth metal-containing oxide to have the polycrystalline or amorphous structure rather than the crystalline structure, and wherein a thickness ratio of the plurality of layers of the rare earth metal-containing oxide to the plurality of layers of the second oxide is 2:1 to 25:1, and
wherein the plasma resistant coating uniformly covers the surface of the chamber component, is resistant to cracking and delamination at a temperature of up to 350° C. and is porosity-free.
10. The method of claim 9 , wherein depositing the stress relief layer comprises depositing amorphous aluminum oxide.
11. The method of claim 9 , wherein at least one of the plurality of layers of the rare-earth metal-containing oxide comprises a yttrium-containing oxide and is deposited by:
performing a deposition cycle comprising:
injecting a yttrium-containing precursor into a deposition chamber containing the chamber component to cause the yttrium-containing precursor to adsorb onto a surface of the stress relief layer to form a first half reaction; and
injecting an oxygen-containing reactant into the deposition chamber to form a second half reaction; and
repeating the deposition cycle one or more times until a target thickness is achieved.
12. The method of claim 9 , wherein depositing at least one of the plurality of layers of the rare-earth metal-containing oxide comprises alternating deposition of a yttrium-containing oxide and one or more additional metal oxides to form a single phase or multi-phase yttrium-containing oxide layer by:
performing a deposition cycle comprising:
injecting a yttrium-containing precursor into a deposition chamber containing the chamber component to cause the yttrium-containing precursor to adsorb onto a surface of the stress relief layer to form a first half reaction; and
injecting an oxygen-containing reactant into the deposition chamber to form a second half reaction and a first layer;
injecting a metal-containing precursor into the deposition chamber to cause the metal-containing precursor to adsorb onto a surface of the first layer to form a third half reaction; and
injecting the oxygen-containing reactant or an alternative oxygen-containing reactant into the deposition chamber to form a fourth half reaction; and
repeating the deposition cycle one or more times until a target thickness is reached.
13. The method of claim 9 , wherein depositing at least one of the plurality of layers of the rare-earth metal-containing oxide comprises co-depositing a yttrium-containing oxide and an additional metal oxide to form a single phase or multi-phase yttrium-containing oxide layer by:
performing a deposition cycle comprising:
co-injecting a mixture of a first precursor for the yttrium-containing oxide and a second precursor for the additional metal oxide into a deposition chamber containing the chamber component to cause the first precursor and the second precursor to adsorb onto a surface of the stress relief layer to form a first half reaction; and
injecting an oxygen-containing reactant into the deposition chamber to form a second half reaction; and
repeating the deposition cycle one or more times until a target thickness is reached.
14. The method of claim 13 , wherein the additional metal oxide is selected from a group consisting of Er 2 O 3 , Al 2 O 3 , and ZrO 2 .
15. The method of claim 13 , wherein the yttrium-containing oxide layer comprises a mixture of about 0 mol % to about 90 mol % Y 2 O 3 and about 0.1 mol % to about 90 mol % of the additional metal oxide.
16. The method of claim 13 , wherein the yttrium-containing oxide layer is selected from a group consisting of Y 3 Al 5 O 12 (YAG), a solid solution of Y 2 O 3 —ZrO 2 , and a ceramic compound comprising Y 4 Al 2 O 9 and a solid-solution of Y 2 O 3 —ZrO 2 .
17. The method of claim 9 , wherein the surface of the chamber component onto which the plasma resistant coating is deposited has an aspect ratio of length to diameter of about 10:1 to about 300:1, and wherein the plasma resistant coating uniformly covers the surface.
18. The method of claim 9 , wherein the chamber component is a chamber component for a semiconductor processing chamber selected from a group consisting of a chamber wall, a shower head, a plasma generation unit, a diffuser, a nozzle, and a gas line.
19. The method of claim 9 , wherein the rare earth metal-containing oxide layer comprises a material having a naturally crystalline structure selected from a group consisting of Y 2 O 3 , Y 3 Al 5 O 12 (YAG), Er 2 O 3 , Er 3 Al 5 O 12 (EAG), Gd 2 O 3 , a solid solution of Y 2 O 3 —ZrO 2 comprising 10 mol % to 90 mol % Y 2 O 3 and 10 mol % to 90 mol % ZrO 2 , and a ceramic compound comprising Y 4 Al 2 O 9 and a solid-solution of Y 2 O 3 —ZrO 2 .
20. A method comprising:
depositing a plasma resistant coating onto a surface of a chamber component using an atomic layer deposition (ALD) process, comprising:
depositing an amorphous stress relief layer on the surface using a plurality of cycles of the ALD process to a thickness of about 10 nm to about 1.5 μm; and
depositing a stack of alternating layers of a rare earth metal-containing oxide and a second oxide to a thickness of about 10 nm to about 1.5 μm, wherein each of the layers of the rare earth metal-containing oxide are formed by performing about 1-30 cycles of the ALD process, and wherein each of the layers of the second oxide are formed by performing 1-2 cycles of the ALD process, where the layers of the second oxide prevent crystal formation in the layers of the rare earth metal-containing oxide, and
wherein the rare earth metal-containing oxide naturally occurs in a crystalline structure, and wherein a thickness ratio of the plurality of layers of the rare earth metal-containing oxide to the plurality of layers of the second oxide is 2:1 to 25:1.
21. The method of claim 20 , wherein the rare earth metal-containing oxide layer comprises a material having a naturally crystalline structure selected from a group consisting of Y 2 O 3 , Y 3 Al 5 O 12 (YAG), Er 2 O 3 , Er 3 Al 5 O 12 (EAG), Gd 2 O 3 , a solid solution of Y 2 O 3 —ZrO 2 comprising 10 mol % to 90 mol % Y 2 O 3 and 10 mol % to 90 mol % ZrO 2 , and a ceramic compound comprising Y 4 Al 2 O 9 and a solid-solution of Y 2 O 3 —ZrO 2 .