IP Library Granted Patent US 10,818,611
Granted Patent B2
US 10,818,611 · App. 15/438,322 · Granted Oct 27, 2020

Stress relief in semiconductor wafers

Inventors: Kevin Chi-Wen Chang (Princeton Junction, NJ); David Hensley (Fanwood, NJ); William Wilkinson (Easton, PA)
Assignee: II-VI Delaware, Inc.
H01L23/562C23C16/06C23C16/345C23C16/402C23C16/513C30B33/00H01L21/022H01L21/0217H01L21/02164H01L21/02175H01L21/02178H01L21/02183H01L21/02186H01L21/02274H01L21/02362H01L21/02505H01L21/02513H01L22/20H01L23/29H01L23/3171H01L23/3192H01S5/0216H01S5/183
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Quick Facts
Patent No.
US 10,818,611
App. No.
15/438,322
Granted
Oct 27, 2020
Kind
B2
Abstract

Methods for compensating for bow in a semiconductor structure comprising an epitaxial layer grown on a semiconductor substrate. The methods include forming an adhesion layer on the backside of the wafer, and forming a stress compensation layer on the adhesion layer.

Claims (30)

1. A method of compensating for bow in a semiconductor wafer comprising:

obtaining a semiconductor wafer including an epitaxial layer formed on a top major surface of a semiconductor substrate, the epitaxial layer causing a wafer bow across the surface of the semiconductor substrate:

applying an adhesion layer across an exposed major surface of the semiconductor wafer; and

depositing a stress compensation layer over the adhesion layer, the stress compensation layer exhibiting a high stress state and formed to a thickness sufficient to substantially reduce the amount of wafer bow.

2. The method as defined in claim 1 wherein the adhesion layer is applied across an exposed major surface of the epitaxial layer.

3. The method as defined, in claim 1 wherein the adhesion layer is applied across an exposed bottom surface of the semiconductor substrate.

4. The method as defined in claim 1 wherein the adhesion layer comprises a dielectric material and is applied to a thickness no greater than 0.5 μm.

5. The method as defined in claim 4 wherein the adhesion layer dielectric material is selected from the group consisting of SiO 2 and SiN.

6. The method as defined in claim 1 wherein the adhesion layer comprises a metal and is applied a thickness no greater than 0.02 μm.

7. The method as defined in claim 6 wherein the adhesion layer metal is selected from the group consisting of: titanium, titanium nitride, tungsten, tantalum, aluminum and gold.

8. The method as defined in claim 1 wherein the stress compensation layer is deposited using a chemical vapor deposition process to impart a defined high stress condition within the deposited layer.

9. The method as defined in claim 8 wherein a plasma chemical or deposition (PCVD) process is used.

10. The method as defined in claim 8 wherein a plasma-enhanced chemical vapor deposition (PECVD) process is used.

11. The method as defined in claim 8 wherein a deposition process temperature is selected to be no, greater than subsequent device fabrication temperatures.

12. The method as defined in claim 1 wherein the stress compensation layer comprises a dielectric material.

13. The method as defined in claim 12 wherein the dielectric material is selected from the group consisting of: SiO2 and SiN.

14. The method as defined in claim 1 wherein the stress compensation layer comprises a metal selected from the group consisting of titanium, tungsten, nickel, aluminum, tantalum, and allows thereof.

15. The method as defined in claim 1 , wherein the method includes the additional steps of

prior to applying the adhesion layer, measuring an initial wafer bow exhibited by the obtained semiconductor wafer;

subsequent to depositing the stress compensation layer, measuring a resultant wafer bow remaining in the structure; and

if the remaining wafer bow is above a predetermined threshold, modifying the thickness of the stress compensation layer.

16. The method as defined in claim 15 , wherein the thickness of the stress compensation layer is increased to reduce the resultant wafer bow.

17. The method as defined in claim 15 , wherein the thickness of the stress compensation layer is decreased to reduce the resultant wafer bow.

18. A bow-compensated semiconductor wafer comprising:

a substrate of a semiconductor material, the substrate having first and second major surfaces;

an epitaxial layer formed on the first major surface of the substrate, the combination of the substrate and the epitaxial layer creating a wafer bow across the semiconductor wafer;

an adhesion layer formed on, an exposed major surface of the semiconductor wafer; and

a stress compensation layer formed on the adhesion layer, the stress compensation layer exhibiting a high stress state and formed to a thickness sufficient to reduce the created wafer bow.

19. The bow-compensated semiconductor wafer as defined in claim 18 wherein the adhesion layer comprises a metal layer formed on the second major surface of the substrate.

20. The bow-compensated semiconductor wafer as defined in claim 19 wherein the stress compensation layer comprises a PCVD dielectric layer deposited on the metal adhesion layer.

Assignments (5)
PATENT RELEASE AND REASSIGNMENT Recorded Jul 5, 2022
From: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
To: II-VI INCORPORATED; MARLOW INDUSTRIES, INC.; EPIWORKS, INC.; LIGHTSMYTH TECHNOLOGIES, INC.; KAILIGHT PHOTONICS, INC.; COADNA PHOTONICS, INC.; OPTIUM CORPORATION; FINISAR CORPORATION; II-VI OPTICAL SYSTEMS, INC.; M CUBED TECHNOLOGIES, INC.; II-VI PHOTONICS (US), INC.; II-VI DELAWARE, INC.; II-VI OPTOELECTRONIC DEVICES, INC.; PHOTOP TECHNOLOGIES, INC.
Reel/Frame 060574/0001 →
SECURITY INTEREST Recorded Jul 1, 2022
From: II-VI INCORPORATED; II-VI DELAWARE, INC.; M CUBED TECHNOLOGIES, INC.; II-VI PHOTONICS (US), INC.; PHOTOP TECHNOLOGIES, INC.; COHERENT, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 060562/0254 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Sep 25, 2019
From: II-VI INCORPORATED; MARLOW INDUSTRIES, INC.; EPIWORKS, INC.; LIGHTSMYTH TECHNOLOGIES, INC.; KAILIGHT PHOTONICS, INC.; COADNA PHOTONICS, INC.; OPTIUM CORPORATION; FINISAR CORPORATION; II-VI OPTICAL SYSTEMS, INC.; M CUBED TECHNOLOGIES, INC.; II-VI PHOTONICS (US), INC.; II-VI DELAWARE, INC.; II-VI OPTOELECTRONIC DEVICES, INC.; PHOTOP TECHNOLOGIES, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 050484/0204 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2019
From: II-VI OPTOELECTRONIC DEVICES, INC.
To: II-VI DELAWARE, INC.
Reel/Frame 048631/0445 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2017
From: CHANG, KEVIN CHI-WEN; HENSLEY, DAVID; WILKINSON, WILLIAM
To: II-VI OPTOELECTRONIC DEVICES, INC.
Reel/Frame 041322/0889 →
Continuity (3)
Continuation In Part 15253373 · Aug 31, 2016
Provisional Application 62187752 · Jul 1, 2015
Related Publication 20170162522A1 · Jun 8, 2017
Cited By (1)
US 12,300,633