Display device, method for manufacturing same, polyimide film for display device supporting bases, and method for producing polyimide film for display device supporting bases
Provided is a display device that can be made thin, lightweight, and flexible, has no problems of cracks and peeling caused by thermal stress, and is excellent in dimension stability and the like. The display device includes: a supporting base including a polyimide film; and a gas barrier layer formed on the supporting base, in which the polyimide film has a transmittance of 80% or more in a wavelength region of from 440 nm to 780 nm, and a coefficient of thermal expansion of 15 ppm/K or less, and has a difference in coefficient of thermal expansion from the gas barrier layer of 10 ppm/K or less.
1. A display device, comprising:
a supporting base comprising a polyimide film;
a gas barrier layer formed on the supporting base and to be brought into contact with the supporting base; and
a stress relaxation layer formed on the gas barrier layer,
wherein the polyimide film has a transmittance of 80% or more in a wavelength region of from 440 nm to 780 nm, a retardation in an in-plane direction of 10 nm or less, and a coefficient of thermal expansion of 15 ppm/K or less, and has a difference in coefficient of thermal expansion from the gas barrier layer of 10 ppm/K or less,
wherein the gas barrier layer comprises one kind or two or more kinds selected from the group consisting of silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon oxycarbide, silicon carbonitride, and aluminum oxide, and the gas barrier layer has a coefficient of thermal expansion of from 0 ppm/K to 10 ppm/K,
wherein the polyimide film comprising a single polyimide layer or a plurality of polyimide layers comprising a main polyimide layer containing polyimide having a structural unit represented by the following general formula (4) and a structural unit represented by the following general formula (5) at a molar ratio “(4):(5) ” of from 50:50 to 100:0
2. A display device according to claim 1 , wherein the polyimide film has a surface roughness Ra of 5 nm or less.
3. A display device according to claim 1 or 2 , wherein the polyimide film has a heating weight loss of 1.5% or less when held at 460° C. for 90 minutes, and has a coefficient of humidity expansion of 15 ppm/% RH or less.
4. A display device according to claim 1 or 2 , wherein the display device comprises an organic EL device comprising: the supporting base comprising the polyimide film; and the gas barrier layer formed on the supporting base, and further comprising an organic EL light-emitting layer.
5. A display device according to claim 1 or 2 , wherein the display device comprises electronic paper comprising: the supporting base comprising the polyimide film; and the gas barrier layer formed on the supporting base, and further comprising an electronic ink layer.
6. A display device according to claim 1 or 2 , further comprising a color filter, wherein the supporting base comprising the polyimide film has a color filter layer formed in advance thereon.
7. A display device according to claim 1 or 2 , wherein the polyimide film comprises a plurality of polyimide layers having different moduli of elasticity, and the polyimide layer to be brought into contact with the gas barrier layer has a modulus of elasticity lower than a modulus of elasticity of another polyimide layer adjacent to the polyimide layer to be brought into contact with the gas barrier layer.
8. A display device according to claim 4 , wherein the organic EL device has a bottom-emission structure in which light is extracted from a surface of the supporting base comprising the polyimide film through the supporting base.
9. A display device according to claim 4 , wherein the organic EL device has a top-emission structure in which light is extracted from a surface on an opposite side to the supporting base comprising the polyimide film.
10. A display device according to claim 7 , wherein the polyimide layer to be brought into contact with the gas barrier layer has a modulus of elasticity of less than 5 GPa.
11. A display device, comprising:
a supporting base comprising a polyimide film;
a gas barrier layer formed on the supporting base and to be brought into contact with the supporting base; and
a stress relaxation layer formed on the gas barrier layer,
wherein the polyimide him has a transmittance of 80% or more in a wavelength region of from 440 nm to 780 nm, and a transmittance of 80% or less at 400 nm, a retardation in an in-plane direction of 10 nm or less, and a coefficient of thermal expansion of 15 ppm/K or less, and has a difference in coefficient of thermal expansion from the gas barrier layer of 10 ppm/K or less,
wherein the gas barrier layer comprises one kind or two or more kinds selected from the group consisting of silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon oxycarbide, silicon carbonitride, and aluminum oxide, and the gas barrier layer has a coefficient of thermal expansion of from 0 ppm/K to 10 ppm/K,
wherein the polyimide film comprising a single polyimide layer or a plurality of polyimide layers comprising a main polyimide layer containing polyimide having a structural unit represented by the following general formula (4) and a structural unit represented by the following general formula (5) at a molar ratio “(4):(5)” of from 50:50 to 100:0.