Positive active material and method for producing the same
The present invention relates to a positive active material and a method for producing same and, more specifically, to a positive active material comprising LiAlO2 at the surface thereof as a result of reacting an Al compound with residual lithium and to a method for producing same.
1. A method for producing a positive active material comprising LiAlO 2 in a surface and being given in Formula 1 that is Li 1+a Ni b M1 c M2 d O 2 , comprising:
preparing the positive active material;
preparing a washing solution in uniform temperature;
agitating the positive active material in the washing solution;
drying the washed positive active material; and
mixedly agitating the positive active material with a compound including Al,
where
0.95≥ b≥ 0.75,
a+b+c= 1,
M1 is one or more selected from a group of Co, B, Ba, Cr, F, Li, Mo, P, Sr, Ti, and Zr, and
M2 is one or more selected from a group of Mn, Al, B, Ba, Cr, F, Li, Mo, P, Sr, Ti, and Zr.
2. The method of claim 1 , wherein the compound including the Al is selected from a group of Al(OH) 3 , Al 2 O 3 , Al(NO 3 ) 3 , Al 2 (SO 4 ) 3 , AlCl 3 , AlH 3 , AlF 3 , and AlPO 4 .
3. The method of claim 1 , wherein the washing solution is distilled water or an alkaline solution.
4. The method of claim 1 , wherein the drying includes:
vacuum-drying the washed positive active material at 80 to 200° C. for 5 to 20 hours.