IP Library Granted Patent US 10,066,106
Granted Patent B2
US 10,066,106 · App. 15/640,689 · Granted Sep 4, 2018

Fuel-resistant liquid asphalt binders and methods of making the same

Inventor: Ronald Corun (Ocean City, MD)
Assignee: ASSOCIATED ASPHALT MARKETING, LLC
C08L95/00C08J3/203C08J3/24C08K5/17C08J2395/00C08J2409/06
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Quick Facts
Patent No.
US 10,066,106
App. No.
15/640,689
Granted
Sep 4, 2018
Kind
B2
Abstract

A fuel-resistant liquid asphalt binder including a composition of fatty amine derivatives for improving the flowability and workability of a bituminous asphalt mix. The fuel-resistant liquid asphalt binder may include 0.4 wt % to 0.7 wt % of a composition of fatty amine derivatives, 2 wt % to 5 wt % styrene-butadiene-styrene, and 2 wt % to 5 wt % high acetate content ethyl vinyl acetate. The fuel-resistant liquid asphalt binder may be mixed with an aggregate to form a bituminous asphalt mix at temperatures ranging from 330° F. to 280° F.

Claims (34)

1. A fuel-resistant liquid asphalt binder comprising a liquid asphalt binder base, cross-linked styrene-butadiene-styrene, high acetate content ethylene vinyl acetate, and a composition of fatty amine derivatives.

2. The fuel-resistant liquid asphalt binder of claim 1 , wherein the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt %.

3. The fuel-resistant liquid asphalt binder of claim 1 , wherein the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt %.

4. The fuel-resistant liquid asphalt binder of claim 1 , wherein the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt %.

5. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has an ASTM D7173 maximum temperature difference of less than or equal to 40° F. when using an ASTM D36 Ring and Ball apparatus.

6. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder meets an AASHTO M320 performance grade.

7. The fuel-resistant liquid asphalt binder of claim 1 , wherein the fuel-resistant liquid asphalt binder has an ASTM D6084 elastic recovery at 25° C. of greater than or equal to 85%.

8. The fuel-resistant liquid asphalt binder of claim 1 , wherein:

the liquid asphalt binder base has a concentration in the range of 89.3 wt % to 95.6 wt %;

the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt %;

the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt %; and

the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt %.

9. A bituminous asphalt mix comprising:

a fuel-resistant liquid asphalt binder comprising a liquid asphalt binder base, cross-linked styrene-butadiene-styrene, high acetate content ethylene vinyl acetate, and a composition of fatty amine derivatives;

air voids; and

an aggregate.

10. The bituminous asphalt mix of claim 9 , wherein the fuel-resistant liquid asphalt binder has a concentration in the range of 4 wt % to 9 wt %.

11. The bituminous asphalt mix of claim 9 , wherein the air voids have a concentration in the range of 2 vol % to 3 vol %.

12. The bituminous asphalt mix of claim 9 , wherein the mix has a weight loss by fuel immersion of less than 2.5% when measured according to FAA P-601 test specifications.

13. The bituminous asphalt mix of claim 9 , wherein:

the liquid asphalt binder base has a concentration in the range of 89.3 wt % to 95.6 wt % in the fuel-resistant liquid asphalt binder;

the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder;

the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder; and

the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt % in the fuel-resistant liquid asphalt binder.

14. A method of making a fuel-resistant liquid asphalt binder, the method comprising mixing a liquid asphalt binder base, cross-linked styrene-butadiene-styrene, high acetate content ethylene vinyl acetate, and a composition of fatty amine derivatives to thereby form the fuel-resistant liquid asphalt binder.

15. The method of claim 14 , wherein the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder.

16. The method of claim 14 , wherein the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder.

17. The method of claim 14 , wherein the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt % in the fuel-resistant liquid asphalt binder.

18. The method of claim 14 , wherein:

the liquid asphalt binder base has a concentration in the range of 89.3 wt % to 95.6 wt % in the fuel-resistant liquid asphalt binder;

the styrene-butadiene-styrene has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder;

the high acetate content ethylene vinyl acetate has a concentration in the range of 2 wt % to 5 wt % in the fuel-resistant liquid asphalt binder; and

the composition of fatty amine derivatives has a concentration in the range of 0.4 wt % to 0.7 wt % in the fuel-resistant liquid asphalt binder.

19. The method of claim 14 , wherein the fuel-resistant liquid asphalt binder has an ASTM D7173 maximum temperature difference of less than or equal to 40° F. when using an ASTM D36 Ring and Ball apparatus, meets an AASHTO M320 performance grade, has an ASTM D6084 elastic recovery at 25° C. of greater than or equal to 85%, or a combination thereof.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2024
From: ASSOCIATED ASPHALT PARTNERS, LLC
To: ERGON ASPHALT & EMULSIONS, INC.
Reel/Frame 068329/0161 →
RELEASE OF SECURITY INTEREST Recorded Dec 15, 2023
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS SUCCESSOR COLLATERAL AGENT TO CREDIT SUISSE AG
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 065888/0503 →
RELEASE OF SECURITY INTEREST Recorded Dec 15, 2023
From: PNC BANK, NATIONAL ASSOCIATION
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 065888/0549 →
SECURITY INTEREST Recorded Jun 30, 2021
From: ASSOCIATED ASPHALT PARTNERS, LLC; ASSOCIATED ASPHALT, INC.; ASSOCIATED ASPHALT TAMPA, LLC
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 056719/0238 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2021
From: ASSOCIATED ASPHALT MARKETING, LLC
To: ASSOCIATED ASPHALT PARTNERS, LLC
Reel/Frame 055660/0418 →
SECURITY INTEREST Recorded Nov 6, 2020
From: ASSOCIATED ASPHALT MARKETING, LLC; ASSOCIATED ASPHALT PARTNERS, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 054297/0304 →
Continuity (2)
Continuation 14515202 · Oct 15, 2014
Related Publication 20170298226A1 · Oct 19, 2017