Functional composite film and quantum dot film
A functional composite film includes one or more combinations of an inorganic layer and an organic layer as underlying base of the inorganic layer on a support, and having the outermost surface with an organic layer thereon, where the organic layer on the outermost surface is formed using an ultraviolet-curable urethane polymer having a weight-average molecular weight of 5,000 to 30,000 and a double bond equivalent of 300 g/mol or more, which has a urethane polymer as the main chain and a side chain having a (meth)acryloyl group at a terminal; a curable urethane polyester; and at least one phosphoric acid compound containing two or less (meth)acryloyl groups and/or a silane coupling agent containing one (meth)acryloyl group, and a quantum dot film using the same. High adhesiveness is obtained between the organic layer and the inorganic layer, and when a quantum dot layer or the like is laminated thereon.
1. A functional composite film comprising:
one or more combinations of an inorganic layer and an organic layer which becomes an underlying base of the inorganic layer on a support, and having the outermost surface with the organic layer thereon,
wherein the organic layer on the outermost surface is formed using an ultraviolet-curable urethane polymer having a weight-average molecular weight of 5,000 to 30,000 and a double bond equivalent of 300 g/mol or more, which has a urethane polymer as the main chain and a side chain having a (meth)acryloyl group at a terminal; a curable urethane polyester; and both a phosphoric acid compound containing two or less (meth)acryloyl groups and a silane coupling agent containing one (meth)acryloyl group, and
wherein a content of the ultraviolet-curable urethane polymer is 35% to 55% by mass, in a solid content of a polymerizable composition for forming the organic layer on the outermost surface.
2. The functional composite film according to claim 1 , wherein the thickness of the organic layer on the outermost surface is 10 to 1,000 nm.
3. The functional composite film according to claim 1 , wherein the organic layer on the outermost surface includes a photopolymerization initiator.
4. The functional composite film according to claim 1 , wherein the organic layer on the outermost surface is formed by thermal curing.
5. The functional composite film according to claim 1 , wherein the organic layer on the outermost surface includes a lubricant.
6. The functional composite film according to claim 5 , wherein the lubricant is a silicon particle.
7. The functional composite film according to claim 1 , wherein the inorganic layer is formed of any one of silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, and a mixture of two or more thereof.
8. A quantum dot film wherein a quantum dot layer formed by dispersing quantum dots in a binder is sandwiched between the functional composite films according to claim 1 , with the organic layer on the outermost surface being on the inside.
9. The quantum dot film according to claim 8 , wherein the binder is formed by the polymerization of a compound having a weight-average molecular weight of 500 or less.
10. The quantum dot film according to claim 8 , wherein the binder is a (meth)acrylic resin.