Resin composition, optical fiber, and method for producing optical fiber
A resin composition for secondary coating of an optical fiber includes a photopolymerizable compound including a urethane (meth)acrylamide, and a photopolymerization initiator. The urethane (meth)acrylamide has a (meth)acrylamide group at at least one end of a urethane bond.
1 . An optical fiber comprising:
a glass fiber including a core and a cladding;
a primary resin layer covering the glass fiber so as to be in contact with the glass fiber; and
a secondary resin layer covering the primary resin layer;
wherein the secondary resin layer includes a cured product of a resin composition for secondary coating of the optical fiber, the resin composition comprising:
a photopolymerizable compound including a urethane (meth)acrylamide; and
a photopolymerization initiator,
wherein the urethane (meth)acrylamide has a (meth)acrylamide group at at least one end of a urethane bond, and
wherein a Young's modulus of the secondary resin layer is 800 MPa to 3000 MPa at 23° C. +2° C.
2 . The optical fiber according to claim 1 , wherein the urethane (meth)acrylamide includes a urethane oligomer having a (meth)acrylamide group at one end of a urethane bond, a urethane oligomer having (meth)acrylamide groups at both ends of a urethane bond, or a mixture of the urethane oligomers.
3 . The optical fiber according to claim 2 , wherein the urethane oligomer having a (meth)acrylamide group at one end of a urethane bond includes a urethane oligomer having a (meth)acrylamide group at one end of a urethane bond and having a (meth)acryloyloxy group at the other end.
4 . The optical fiber according to claim 1 , wherein the urethane (meth)acrylamide has a number-average molecular weight of 500 to 6000.
5 . The optical fiber according to claim 1 , wherein a content of the urethane (meth)acrylamide is 5 parts by mass to 60 parts by mass based on 100 parts by mass of a total amount of the resin composition.
6 . The optical fiber according to claim 1 , wherein the photopolymerizable compound further includes a (meth)acrylic acid ester.
7 . The optical fiber according to claim 6 , wherein the (meth)acrylic acid ester includes a (meth)acrylate having a bisphenol skeleton.
8 . A method for producing an optical fiber, the method comprising:
applying a resin composition to an outer periphery of a glass fiber including a core and a cladding; and
curing the resin composition by ultraviolet irradiation after the applying, wherein the resin composition comprises:
a photopolymerizable compound including a urethane (meth)acrylamide; and
a photopolymerization initiator,
wherein the urethane (meth)acrylamide has a (meth)acrylamide group at at least one end of a urethane bond, and
wherein a Young's modulus of a cured product of the resin composition is 800 MPa to 3000 MPa at 23° C.±2° C.
9 . The optical fiber according to claim 1 , wherein a glass transition temperature of the secondary resin layer is 70° C. to 105° C.