IP Library Granted Patent US 10,196,537
Granted Patent B2
US 10,196,537 · App. 15/665,566 · Granted Feb 5, 2019

Dirt pick-up resistant composition

Inventors: Robert Sandoval (Crystal Lake, IL); James Harris (Crystal Lake, IL); Mary Jane Hibben (Elburn, IL); Andrew Balgeman (Woodstock, IL); Christopher Shaffer (Saint Paul, MN); Glenn Frazee (Twin Lakes, WI); Michael Wildman (Hoffman Estates, IL)
Assignee: THE SHERWIN-WILLIAMS COMPANY
C09D133/06C08K5/07C08K5/10C08K5/101C09D5/00C09D5/1687C09D7/48C09D7/63C08K5/005
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Quick Facts
Patent No.
US 10,196,537
App. No.
15/665,566
Granted
Feb 5, 2019
Kind
B2
Abstract

Water-based compositions that are resistant to dirt pickup, efflorescence, tannin bleed-through and surfactant leaching are described. The water-based composition includes a latex or water-dispersible polymer and a non-VOC UV-VIS (preferably, ultraviolet) absorber as a dirt pickup resistance additive. Methods of making water-based compositions including a non-VOC UV-VIS absorber as an additive are also described.

Claims (24)

1. A water-based composition, comprising:

a latex polymer having Tg of about 5 to 20° C.;

methyl-o-benzoyl benzoate; and

optionally, a cross linking component,

wherein methyl-o-benzoyl benzoate is present in an amount of at least 0.1 wt-% and up to 5.0 wt-%, based on the weight of the polymer solids, and

wherein the water-based composition does not contain benzophenone.

2. The composition of claim 1 , wherein the latex polymer has Tg of about 8 to 14° C.

3. The composition of claim 1 , wherein methyl-o-benzoyl benzoate is present in an amount of at least about 0.6 weight percent based on the total weight of polymer solids in the composition.

4. The composition of claim 1 , wherein methyl-o-benzoyl benzoate is present in an amount of at least about 0.9 weight percent based on the total weight of polymer solids in the composition.

5. The composition of claim 1 , wherein the cross linking component is present and is selected from 2-(acetoacetoxy)ethyl methacrylate (AAEM), diacetone acrylamide (DAAM), and mixtures or combinations thereof.

6. The composition of claim 1 , wherein the latex polymer is derived by polymerization in a single stage of an emulsion of one or more ethylenically unsaturated monomers.

7. The composition of claim 1 , wherein the latex polymer is derived by polymerization in a single stage of an emulsion of one or more ethylenically unsaturated monomers selected from alkyl acrylates, alkoxy acrylates, alkyl methacrylates, alkoxy methacrylates, vinyl esters of saturated carboxylic acids, mono olefins, conjugated dienes, styrene, vinyl chloride, and combinations thereof.

8. The composition of claim 1 , wherein the latex polymer is derived by polymerization in a single stage emulsion process, the emulsion comprising:

about 30 to 55 wt percent methyl methacrylate;

about 0 to 40 wt percent 2-ethyl hexyl acrylate;

about 15 to 55 wt percent butyl acrylate

about 0 to 30 wt percent butyl methacrylate; and

about 1 to 5 wt percent methacrylic acid.

9. The composition of claim 1 , wherein the composition is a water-based paint, sealer, caulk, or sealant.

10. The composition of claim 1 , wherein the composition is a water-based durable paint for exterior use.

11. The composition of claim 1 , wherein the composition is a water-based durable paint with a pigment volume concentration of at least 40%.

12. The composition of claim 1 , wherein the composition has extractables of less than about 0.3%.

13. The composition of claim 1 , wherein the composition has extractables of less than about 0.2%.

14. The water-based composition of claim 1 , wherein the latex polymer is a multistage latex polymer.

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2023
From: THE SHERWIN-WILLIAMS HEADQUARTERS COMPANY
To: SWIMC LLC
Reel/Frame 063275/0494 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 11, 2022
From: THE SHERWIN-WILLIAMS COMPANY
To: THE SHERWIN-WILLIAMS HEADQUARTERS COMPANY
Reel/Frame 060366/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2021
From: THE VALSPAR CORPORATION
To: THE SHERWIN-WILLIAMS COMPANY
Reel/Frame 057204/0946 →
MERGER Recorded Oct 29, 2020
From: ENGINEERED POLYMER SOLUTIONS, INC.
To: THE VALSPAR CORPORATION
Reel/Frame 054443/0772 →
MERGER Recorded Sep 2, 2020
From: VALSPAR SOURCING, INC.
To: ENGINEERED POLYMER SOLUTIONS, INC.
Reel/Frame 053826/0606 →
NUNC PRO TUNC ASSIGNMENT Recorded Mar 24, 2020
From: THE SHERWIN-WILLIAMS COMPANY
To: VALSPAR SOURCING, INC.
Reel/Frame 052217/0640 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT PATENT NO. 8465946 PREVIOUSLY RECORDED AT REEL: 045281 FRAME: 0529. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER. Recorded May 4, 2018
From: VALSPAR SOURCING, INC.
To: THE SHERWIN-WILLIAMS COMPANY
Reel/Frame 046087/0150 →
MERGER Recorded Feb 8, 2018
From: VALSPAR SOURCING. INC
To: THE SHERWIN-WILLIAMS COMPANY
Reel/Frame 045281/0529 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 22, 2017
From: SANDOVAL, ROBERT; HARRIS, JAMES; HIBBEN, MARY JANE; WILDMAN, MICHAEL; BALGEMAN, ANDREW; FRAZEE, GLENN; SHAFFER, CHRISTOPHER
To: VALSPAR SOURCING, INC.
Reel/Frame 043357/0928 →
Continuity (5)
Continuation In Part 15295264 · Oct 17, 2016
Continuation In Part 14770123
Provisional Application 61799995 · Mar 15, 2013
Provisional Application 61836884 · Jun 19, 2013
Related Publication 20170327709A1 · Nov 16, 2017
Cited By (3)
US 12,297,368 US 12,428,575 US 12,655,302