Varied silicon richness silicon nitride formation
A method to fabricate a non-planar memory device including forming a multi-layer silicon nitride structure substantially perpendicular to a top surface of the substrate. There may be multiple non-stoichiometric silicon nitride layers, each including a different or same silicon richness value from one another.
1. A method of fabricating a non-planar memory device, comprising:
forming a stack including alternating sacrificial nitride and inter-cell dielectric layers;
forming a device opening in the stack that is substantially vertical and depositing a blocking dielectric layer onto an inner wall of the device opening; and
forming a multi-layer silicon nitride structure abutting the blocking dielectric layer, wherein the multi-layer silicon nitride structure includes,
a first stoichiometric silicon nitride layer abutting the blocking dielectric layer, and
N layers of non-stoichiometric silicon nitride layers disposed sequentially overlying the first stoichiometric silicon nitride layer, wherein N is a natural number greater than 1, a first layer of the N layers abutting the first stoichiometric silicon nitride layer and an N th layer abutting an (N−1) th layer, wherein each of the N layers of non-stoichiometric silicon nitride layers has a silicon richness value that is mutually different from one another.
2. The method of claim 1 , further comprising:
terminating the forming of the multi-layer silicon nitride structure when a silicon richness value of the N th layer of non-stoichiometric silicon nitride layers reaches a pre-determined limit.
3. The method of claim 2 , further comprising:
forming a tunnel oxide layer abutting the N th layer of non-stoichiometric silicon nitride layers.
4. The method of claim 2 , wherein the silicon richness values of the N layers of non-stoichiometric silicon nitride layers increase unidirectionally from the first layer to the N th layer.
5. The method of claim 2 , wherein the silicon richness values of the N layers of non-stoichiometric silicon nitride layers decrease unidirectionally from the first layer to the N th layer.
6. The method of claim 2 , wherein the multi-layer silicon nitride structure is formed spanning at least two memory cells of the non-planar memory device.