Coated copper particles and use thereof
Disclosed herein are coated copper particles formed of copper cores that are surface coated with a coating composition comprising one or more conductive oxides. Further disclosed herein are electrically conductive adhesives (ECA) comprising: (a) organic binder, (b) surface coated copper particles, and optional (c) solvent.
1. Coated copper particles comprised of copper cores that are surface coated with about 0.15-4.5 parts by weight of a coating composition, relative to 100 parts by weight of the copper cores, and wherein, the coating composition comprising at least one conductive oxide selected from the group consisting of antimony doped tin oxide (ATO), indium tin oxide (ITO), gallium doped zinc oxide (GZO), aluminum doped zinc oxide (AZO), fluorine doped tin oxide (FTO), and combinations of two or more thereof.
2. The coated copper particles of claim 1 , wherein, the copper cores have a particle size distribution D50 ranging from about 0.08-50 μm.
3. The coated copper particles of claim 2 , wherein, the copper cores have a particle size distribution D50 ranging from about 0.5-35 μm.
4. The coated copper particles of claim 3 , wherein, the copper cores have a particle size distribution D50 ranging from about 0.5-20 μm.
5. The coated copper particles of claim 1 , wherein the copper cores that are surface coated with about 0.15-3 parts by weight of a coating composition, relative to 100 parts by weight of the copper cores.
6. An electrically conductive adhesive comprising (a) organic binder, (b) the coated copper particles recited in claim 1 , and optional (c) solvent.
7. The electrically conductive adhesive of claim 6 , wherein, the weight ratio of the coated copper particles to the organic binder is in the range of about 95:5-70:30.
8. The electrically conductive adhesive of claim 7 , wherein, the weight ratio of the coated copper particles to the organic binder is in the range of about 95:5-75:25.
9. The electrically conductive adhesive of claim 8 , wherein, the weight ratio of the coated copper particles to the organic binder is in the range of about 95:5-82:18.
10. The electrically conductive adhesive of claim 6 , wherein, the organic binder comprises an organic material selected from the group consisting of thermoset resins, thermoplastic resins, elastomers, and combinations of two or more thereof.
11. The electrically conductive adhesive of claim 10 , wherein, the organic binder further comprises at least one cross-linking agent.
12. The electrically conductive adhesive of claim 6 , wherein the optional solvent is included at a balance amount.
13. A bonded assembly comprising two substrates aligned in a spaced apart relationship, each of which having an inwardly facing surface and an outwardly facing surface, wherein, the inwardly facing surfaces of each of the two substrates is bonded by an electrically conductive bond, and wherein, the electrically conductive bond is formed by curing the electrically conductive adhesive recited in claim 6 .
14. An article comprising the bonded assembly of claim 13 .
15. The article of claim 14 , which is selected from the group consisting of electronic devices, integrated circuits, semiconductor devices, solar cells, and light emitting diodes.
16. A method for forming a bonded assembly comprising:
providing two substrates aligned in a spaced apart relationship, each of which having an inwardly facing surface and an outwardly facing surface;
placing the electrically conductive adhesive recited in claim 6 between the inwardly facing surfaces of each of the two substrates; and
curing the electrically conductive adhesive to form electrically conductive bond between the two substrates.