Positive photosensitive resin composition

1. A positive photosensitive resin composition comprising a binder resin (A), a quinonediazide compound (B), and at least one black dye (C) selected from black dyes specified by a Colour Index of Solvent Black 27 to 47,

wherein the binder resin (A) comprises at least one selected from the group consisting of

(a) a polyalkenyl phenol resin having a structure represented by formula (1):

wherein R 1 , R 2 and R 3 each independently represent a hydrogen atom, a C 1-5 alkyl group, an alkenyl group represented by formula (2):

wherein R 6 , R 7 , R 8 , R 9 , and R 10 each independently represent a hydrogen atom, a C 1-5 alkyl group, a C 5-10 cycloalkyl group, or C 6-12 aryl group, and a symbol * in formula (2) represents a bond with a carbon atom that constitutes an aromatic ring,

a C 1-2 alkoxy group, or a hydroxyl group,

at least one of R 1 , R 2 and R 3 is an alkenyl group represented by formula (2), and

Q represents an alkylene group represented by —CR 4 R 5 —, a C 5-10 cycloalkylene group, a divalent organic group having an aromatic ring, a divalent organic group having an alicyclic condensed ring, or a divalent group of any combination thereof, wherein R 4 and R 5 each independently represent a hydrogen atom, a C 1-5 alkyl group, a C 2-6 alkenyl group, a C 5-10 cycloalkyl group, or a C 6-12 aryl group;

(b) a hydroxy polystyrene resin derivative having a structural unit represented by formula (3):

wherein R 11 represents a hydrogen atom or a C 1-5 alkyl group, m represents an integer of 1 to 4, n represents an integer of 1 to 4, m+n is from 2 to 5, R 12 represents at least one selected from the group consisting of a hydrogen atom, a methyl group, an ethyl group, and a propyl group; and

(c) an aqueous alkaline solution-soluble resin having an epoxy group and a phenolic hydroxyl group.

2. The positive photosensitive resin composition according to claim 1 , wherein the black dye (C) is specified by a Colour Index of Solvent Black 27, 29, or 34.

3. The positive photosensitive resin composition according to claim 1 , comprising from 40 to 85 parts by weight of the binder resin (A), from 5 to 45 parts by weight of the quinonediazide compound (B), and from 0.1 to 50 parts by weight of the black dye (C), based on 100 parts by weight in total of the binder resin (A), the quinonediazide compound (B), and the black dye (C).

4. The positive photosensitive resin composition according to claim 1 , wherein a cured product of the positive photosensitive resin composition has a hue which corresponds to an L* value of not more than 75, an a* value of −15 to 15, and a b* value of −15 to 15 in the L*a*b* color system.

5. The positive photosensitive resin composition according to claim 1 , wherein the binder resin (A) further comprises (d) an aqueous alkaline solution-soluble copolymer of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer.

6. The positive photosensitive resin composition according to claim 5 , wherein Q in formula (1) is —CH 2 — for the polyalkenyl phenol resin (a), which means that formula (1) corresponds to formula (4):

wherein R 1 , R 2 and R 3 are the same as in formula (1).

7. The positive photosensitive resin composition according to claim 5 , wherein the alkenyl group represented by formula (2) is an allyl group.

8. The positive photosensitive resin composition according to claim 5 , wherein the hydroxy polystyrene resin derivative (b) is a copolymer having a structural unit represented by formula (3) and a structural unit represented by formula (5):

wherein R 13 represents a hydrogen atom or a C 1-5 alkyl group, and p represents an integer of 1 to 5.

9. The positive photosensitive resin composition according to claim 5 , wherein the aqueous alkaline solution-soluble resin (c) having an epoxy group and a phenolic hydroxyl group is a reaction product of a compound having at least two epoxy groups in its molecule and a hydroxybenzoic acid, which is a compound having a structure represented by formula (8):

wherein q represents an integer of 1 to 5.

10. The positive photosensitive resin composition according to claim 9 , wherein the compound having at least two epoxy groups in its molecule is a cresol novolac epoxy resin.

11. The positive photosensitive resin composition according to claim 9 , wherein the hydroxybenzoic acid is dihydroxybenzoic acid.

12. The positive photosensitive resin composition according to claim 5 , wherein the aqueous alkaline solution-soluble copolymer (d) of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer has a structural unit represented by formula (10):

wherein R 14 represents a hydrogen atom or a C 1-5 alkyl group, and r represents an integer of 1 to 5,

and a structural unit represented by formula (11):

wherein R 15 and R 16 each independently represent a hydrogen atom, a C 1-3 alkyl group, a fully or partially fluorinated C 1-3 alkyl group, or a halogen atom, R 17 represents a hydrogen atom, a C 1-6 linear or cyclic alkyl group, a phenyl group, or a phenyl group substituted by at least one selected from the group consisting of a hydroxyl group, a C 1-6 alkyl group, and a C 1-6 alkoxy group.

13. The positive photosensitive resin composition according to claim 5 , wherein the binder resin (A) comprises the aqueous alkaline solution-soluble resin (c) having an epoxy group and a phenolic hydroxyl group and the aqueous alkaline solution-soluble copolymer (d) of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer.

14. A barrier rib of an organic EL element, comprising a cured product of the positive photosensitive resin composition according to claim 1 .

15. An insulating film of an organic EL element, comprising a cured product of the positive photosensitive resin composition according to claim 1 .

16. An organic EL element comprising a cured product of the positive photosensitive resin composition according to claim 1 .

17. A method of producing a radiation lithography construct, comprising

(1) a coating step of dissolving the positive photosensitive resin composition according to claim 1 in a solvent and coating a base material therewith;

(2) a drying step of removing the solvent in the coating of the positive photosensitive resin composition;

(3) an exposure step of performing radiation irradiation through a photomask;

(4) a development step of forming a pattern by alkaline development; and

(5) a heat treatment step of heating at 100° C. to 350° C.

18. A positive photosensitive resin composition comprising a binder resin (A), a quinonediazide compound (B), and at least one black dye (C) selected from black dyes specified by a Colour Index of Solvent Black 27 to 47,

wherein the binder resin (A) comprises at least two selected from the group consisting of

(a) a polyalkenyl phenol resin having a structure represented by formula (1):

wherein R 1 , R 2 and R 3 each independently represent a hydrogen atom, a C 1-5 alkyl group, an alkenyl group represented by formula (2):

wherein R 6 , R 7 , R 8 , R 9 , and R 10 each independently represent a hydrogen atom, a C 1-5 alkyl group, a C 5-10 cycloalkyl group, or C 6-12 aryl group, and a symbol * in formula (2) represents a bond with a carbon atom that constitutes an aromatic ring,

a C 1-2 alkoxy group, or a hydroxyl group,

at least one of R 1 , R 2 and R 3 is an alkenyl group represented by formula (2), and

Q represents an alkylene group represented by —CR 4 R 5 —, a C 5-10 cycloalkylene group, a divalent organic group having an aromatic ring, a divalent organic group having an alicyclic condensed ring, or a divalent group of any combination thereof, wherein R 4 and R 5 each independently represent a hydrogen atom, a C 1-5 alkyl group, a C 2-6 alkenyl group, a C 5-10 cycloalkyl group, or a C 6-12 aryl group;

(c) an aqueous alkaline solution-soluble resin having an epoxy group and a phenolic hydroxyl group; and

(d) an aqueous alkaline solution-soluble copolymer of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer.

19. A positive photosensitive resin composition comprising a binder resin (A), a quinonediazide compound (B), and at least one black dye (C) selected from black dyes specified by a Colour Index of Solvent Black 27 to 47,

wherein the binder resin (A) comprises (d) an aqueous alkaline solution-soluble copolymer of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer,

wherein the aqueous alkaline solution-soluble copolymer (d) of a polymerizable monomer having an alkali-soluble functional group and another polymerizable monomer has a structural unit represented by formula (10):

wherein R 14 represents a hydrogen atom or a C 1-5 alkyl group, and r represents an integer of 1 to 5,

and a structural unit represented by formula (11):

wherein R 15 and R 16 each independently represent a hydrogen atom, a C 1-3 alkyl group, a fully or partially fluorinated C 1-3 alkyl group, or a halogen atom, R 17 represents a hydrogen atom, a C 1-6 linear or cyclic alkyl group, a phenyl group, or a phenyl group substituted by at least one selected from the group consisting of a hydroxyl group, a C 1-6 alkyl group, and a C 1-6 alkoxy group.