Stabilized quantum dot composite and method of making a stabilized quantum dot composite
View Patent ↗A stabilized quantum dot composite includes a plurality of luminescent semiconducting nanoparticles embedded in a matrix comprising an ionic metal oxide. A method of making a stabilized quantum dot composite includes forming a mixture comprising a plurality of luminescent semiconducting nanoparticles dispersed in an aqueous solution comprising an ionic metal oxide. The mixture is dried to form a stabilized quantum dot composite comprising the plurality of luminescent semiconducting nanoparticles embedded in a matrix comprising the ionic metal oxide.
1. A stabilized quantum dot composite comprising:
a plurality of luminescent semiconducting nanoparticles embedded in a matrix comprising an ionic metal oxide having a chemical formula nA x O y .mB z O w , wherein A includes one or more elements selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, wherein B includes one or more elements selected from the group consisting of B, Al, Ga, In, Si, Ge, Sn, and Pb, wherein x, y, z, and w are positive integers, and wherein n and m are stoichiometry coefficients.
2. The stabilized quantum dot composite of claim 1 having a morphology selected from the group consisting of: a microparticle, a coating, and a macroscopic body.
3. The stabilized quantum dot composite of claim 1 , wherein x=2, y=1, z=1, and w=2, and the chemical formula is nA 2 O.mBO 2 .
4. The stabilized quantum dot composite of claim 1 , wherein A comprises K, wherein B comprises Si, and wherein the ionic metal oxide comprises potassium silicate.
5. The stabilized quantum dot composite of claim 4 , wherein the potassium silicate comprises nK 2 O.mSiO 2 in a molar ratio n:m from about 1:1.5 to about 1:4.5.
6. The stabilized quantum dot composite of claim 1 , wherein the luminescent semiconducting nanoparticles comprise a semiconductor selected from the group consisting of: group IV, group II-VI semiconductors, group III-V semiconductors, group I-III-VI 2 semiconductors, and perovskite semiconductors.
7. The stabilized quantum dot composite of claim 6 , wherein an interior of each of the luminescent semiconducting nanoparticles comprises the semiconductor, and further comprising a buffer layer surrounding the interior.
8. The stabilized quantum dot composite of claim 7 , wherein the buffer layer comprises an oxide coating.
9. The stabilized quantum dot composite of claim 1 being optically transparent.
10. A light emitting device comprising:
a blue light emitting diode (LED) chip having a dominant wavelength of 425 nm to 475 nm in optical communication with the stabilized quantum dot composite of claim 1 for down conversion of light emitted from the blue LED chip.
11. The light emitting device of claim 10 disposed in a lighting fixture selected from the group consisting of: omnidirectional light bulb, candelabra bulb, downlight, troffer, street light, outdoor light, canopy light, parking garage light, waveguide-based troffer, waveguide-based garage light, and lamp.
12. The light emitting device of claim 10 , wherein a coating on the LED chip comprises the stabilized quantum dot composite.
13. The light emitting device of claim 10 , wherein an optical lens overlying the LED chip comprises the stabilized quantum dot composite.
14. The light emitting device of claim 10 , wherein a polymeric encapsulant on the LED chip comprises the stabilized quantum dot composite.
15. The light emitting device of claim 10 , wherein a coated substrate positioned remote from the LED chip comprises the stabilized quantum dot composite.