Methods of forming resistive memory elements
A resistive memory element comprises a first electrode, an active material over the first electrode, a buffer material over the active material and comprising longitudinally extending, columnar grains of crystalline material, an ion reservoir material over the buffer material, and a second electrode over the ion reservoir material. A memory cell, a memory device, an electronic system, and a method of forming a resistive memory element are also described.
1. A method of forming a resistive memory element, comprising:
forming a buffer material over a switchable resistivity material overlying an electrode, the buffer material comprising longitudinally-extending, columnar grains of one or more of a refractory metal nitride, a refractory metal nitrogen carbide, a refractory metal nitrogen bromide, and a refractory metal nitrogen silicide;
forming one or more of a Cu-containing material, an Ag-containing material, and an Al-containing material over the buffer material; and
forming another electrode over the one or more of the Cu-containing material, the Ag-containing material, and the Al-containing material.
2. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the buffer material to comprise one or more of a composite of the refractory metal nitride and a chalcogen, a composite of the refractory metal nitrogen carbide and a chalcogen, a composite of the refractory metal nitrogen bromide and a chalcogen, and a composite of the refractory metal nitrogen silicide and a chalcogen.
3. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the buffer material to further comprise at least one electrolyte material.
4. The method of claim 3 , wherein forming the buffer material to further comprise at least one electrolyte material comprises forming the buffer material to comprise from about 0.01 atomic % of the electrolyte material to about 50 atomic % of the electrolyte material.
5. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the buffer material over one or more of a chalcogenide material, a transition metal oxide, a dielectric metal oxide, and a mixed valence oxide including two or more metals.
6. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the buffer material over at least one metal oxide.
7. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the buffer material over a chalcogenide material.
8. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming each of the longitudinally-extending, columnar grains of the buffer material to be monodisperse.
9. The method of claim 1 , wherein forming a buffer material over a switchable resistivity material comprises forming the longitudinally-extending, columnar grains of the buffer material to be polydisperse.
10. The method of claim 1 , wherein forming the buffer material comprises forming the buffer material to further comprise Te along grain boundaries of the longitudinally-extending, columnar grains.