Methods of forming si
A method of forming Si 3 N x , where “x” is less than 4 and at least 3, comprises decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si. An outer substrate surface is contacted with the at least two decomposition species. At least one of the decomposition species that comprises Si attaches to the outer substrate surface to comprise an attached species. The attached species is contacted with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3. Other embodiments are disclosed, including constructions made in accordance with method embodiments of the invention and constructions independent of method of manufacture.
1. A method of forming Si 3 N x , where “x” is less than 4 and at least 3, comprising:
decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another within a chamber having a chamber pressure of from 100 to 500 mTorr, at least one of the at least two different decomposition species comprising Si;
after the decomposing the Si-precursor molecule, contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting the outer substrate surface, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3.
2. The method of claim 1 wherein the decomposing comprises thermal decomposition of the Si-comprising precursor molecule and at a temperature of at least 500° C.
3. The method of claim 2 wherein the decomposing consists essentially of thermal decomposition.
4. The method of claim 1 comprising attaching the at least one of the decomposition species that comprises Si to the attached species.
5. The method of claim 1 wherein the decomposing occurs directly above the outer substrate surface.
6. The method of claim 1 comprising repeating said sequence.
7. The method of claim 1 wherein the Si-comprising precursor molecule comprises a silane.
8. The method of claim 7 wherein the silane comprises a chlorosilane.
9. The method of claim 1 wherein the N-comprising precursor comprises ammonia.
10. The method of claim 1 comprising during at least one of said contactings also contacting the outer substrate surface with N 2 .
11. The method of claim 10 comprising contacting the outer substrate surface with N 2 during both of said contactings.
12. The method of claim 1 wherein “x” in the reaction product is at least 3.5.
13. The method of claim 1 wherein “x” in the reaction product is no more than 3.90.
14. The method of claim 1 wherein “x” in the reaction product is 3.75.
15. The method of claim 1 wherein only one of all said different decomposition species comprises Si.
16. The method of claim 1 wherein the decomposing and the contacting of the outer substrate surface with the at least two decomposition species occur in the deposition chamber under identical the temperature and pressure conditions.
17. A method of forming Si 3 N x , where “x” is less than 4 and at least 3, comprising:
decomposing silicon tetrachloride into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
after the decomposing the Si-precursor molecule, contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting the outer substrate surface, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3.
18. A method of forming Si 3 N x , where “x” is less than 4 and at least 3, comprising:
providing a single Si-comprising precursor into a chamber;
decomposing the single Si-comprising precursor into at least two decomposition species that are different from one another, wherein each of at least two of said different decomposition species comprises Si;
after the decomposing the Si-precursor molecule, contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting the outer substrate surface, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3.
19. A method of forming Si 3 N x , where “x” is less than 4 and at least 3, comprising:
providing a single silicon- and chlorine-comprising precursor into a chamber, the single silicon- and chlorine-comprising precursor being selected from silicon tetrachloride, hexachlorodisilane and trichlorosilane;
decomposing the silicon- and chlorine-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si, the decomposing comprising thermal decomposition of the silicon- and chlorine-comprising precursor molecule directly above an outer substrate surface at a temperature of at least 500° C.;
contacting the outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species and attaching the at least one of the decomposition species that comprises Si to the attached species; and
after contacting the outer substrate surface with the at least two decomposition species, contacting the attached species with ammonia that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” no more than 3.90 and at least 3.
20. A method of forming insulator material that is ultimately between a control gate and charge-storage material of a programmable charge-storage transistor, comprising:
decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species;
contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3; and
providing the reaction product between a control gate and charge-storage material of a programmable charge-storage transistor.
21. The method of claim 20 comprising forming the programmable charge-storage transistor to be elevationally extending.
22. The method of claim 21 comprising forming the programmable charge-storage transistor to be vertical or within 10° of vertical.
23. The method of claim 20 comprising forming the programmable charge-storage transistor to be horizontal or within 10° of horizontal.
24. A programmable charge-storage transistor produced by the method of claim 20 .
25. A method of forming an array of elevationally-extending strings of memory cells, the method comprising:
forming a stack comprising vertically-alternating insulative tiers and wordline tiers, the wordline tiers comprising control-gate material, channel openings extending into the alternating tiers;
forming charge-blocking material comprising Si 3 N x , where “x” is less than 4 and at least 3, in the channel openings elevationally along the control-gate material, the forming of the Si 3 N x comprising:
decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting the outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3;
forming charge-storage material in the channel openings elevationally along the charge-blocking material comprising Si 3 N x ; and
forming insulative charge-passage material then transistor channel material in the channel openings laterally over the charge-storage material;
providing the control-gate material to have terminal ends corresponding to control-gate regions of individual memory cells, with the charge-blocking material being between the charge-storage material and individual of the control-gate regions.
26. A method of forming an array of elevationally-extending strings of memory cells, the method comprising:
forming a stack comprising vertically-alternating insulative tiers and wordline tiers, the wordline tiers comprising control-gate material having terminal ends corresponding to control-gate regions of individual memory cells, channel openings extending into the alternating tiers, the control-gate material being laterally-recessed from laterally-innermost surfaces of the channel openings;
forming charge-blocking material comprising Si 3 N x , where “x” is less than 4 and at least 3, in the channel openings elevationally along the laterally-recessed control-gate material, the forming of the Si 3 N x comprising:
decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting an outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3;
forming charge-storage material in the channel openings elevationally along the charge-blocking material comprising Si 3 N x ; and
forming insulative charge-passage material then transistor channel material in the channel openings laterally over the charge-storage material.
27. A method of forming an array of elevationally-extending strings of memory cells, the method comprising:
forming a stack comprising vertically-alternating tiers of different composition first and second materials, the first material being insulative;
forming elevationally-extending channel openings into the alternating tiers;
forming charge-blocking material comprising Si 3 N x , where “x” is less than 4 and at least 3, in the channel openings elevationally along the alternating tiers, the forming of the Si 3 N x comprising:
decomposing a Si-comprising precursor molecule into at least two decomposition species that are different from one another, at least one of the at least two different decomposition species comprising Si;
contacting an outer substrate surface with the at least two decomposition species, at least one of the decomposition species that comprises Si attaching to the outer substrate surface to comprise an attached species; and
after the contacting an outer substrate surface with the at least two decomposition species, contacting the attached species with a N-comprising precursor that reacts with the attached species to form a reaction product comprising Si 3 N x , where “x” is less than 4 and at least 3;
forming charge-storage material in the channel openings elevationally along the alternating tiers and the charge-blocking material comprising Si 3 N x ;
forming insulative charge-passage material in the channel openings elevationally along the charge-storage material;
forming transistor channel material in the channel openings elevationally along the insulative charge-passage material; and
after forming the transistor channel material, replacing at least some of the second material with control-gate material having terminal ends corresponding to control-gate regions of individual memory cells.
28. A programmable charge-storage transistor comprising:
channel material;
insulative charge-passage material;
charge-storage material;
a control gate; and
charge-blocking insulator material between the charge-storage material and the control gate, the charge-blocking insulator material comprising Si 3 N x , where “x” is less than 4 and at least 3.