IP Library Granted Patent US 10,566,595
Granted Patent B2
US 10,566,595 · App. 15/983,914 · Granted Feb 18, 2020

Ion conductive inks and solutions for additive manufacturing of lithium microbatteries

Inventors: Eric B. Duoss (Dublin, CA); Patrick G. Campbell (Oakland, CA); William C. Floyd, III (Oakland, CA); Julie A. Mancini (Livermore, CA); Matthew Merrill (Dublin, CA); Conner T. Sharpe (Tracy, CA); Christopher M. Spadaccini (Oakland, CA); Michael Stadermann (Pleasanton, CA); Cheng Zhu (Livermore, CA)
Assignee: Lawrence Livermore National Security, LLC
H01M2/1653C09D11/00H01M2/145H01M2/1673H01M2/18H01M6/40H01M10/0436H01M10/0525H01M2220/30
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Quick Facts
Patent No.
US 10,566,595
App. No.
15/983,914
Granted
Feb 18, 2020
Kind
B2
Abstract

A separator made of ion conductive ink is produced by additive manufacturing. A micro-battery is produced with the separator made of ion conductive ink located between the battery's anode and cathode. The separator functions to keep the anode and cathode apart and to facilitate the transport of ions to produce an operative micro-battery.

Claims (20)

1. A micro-battery apparatus, comprising:

a battery casing;

an anode electrode connected to said battery casing;

a cathode electrode connected to said battery casing;

a separator in said battery casing connected to said anode electrode and said cathode electrode, said separator made of ion conductive ink, wherein said separator is made of methacrylpropylsulfate (MPS) salts and PEGDA;

a matrix of anode micro-channels in said separator body;

a matrix of cathode micro-channels in said separator body;

an anode material in said anode micro-channels; and

an cathode material in said cathode micro-channels.

2. A micro-battery apparatus, comprising:

a battery casing;

an anode electrode connected to said battery casing;

a cathode electrode connected to said battery casing;

a separator in said battery casing connected to said anode electrode and said cathode electrode, said separator made of ion conductive ink,

wherein said separator is made of methacrylpropylsulfate salts and PEGDA/PEGMA having a

chemical structure;

a matrix of anode micro-channels in said separator body;

a matrix of cathode micro-channels in said separator body;

an anode material in said anode micro-channels; and

an cathode material in said cathode micro-channels.

Assignments (2)
CONFIRMATORY LICENSE Recorded Jul 11, 2018
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 046319/0571 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2018
From: DUOSS, ERIC B.; CAMPBELL, PATRICK G.; FLOYD, WILLIAM C., III; MANCINI, JULIE A.; MERRILL, MATTHEW; SHARPE, CONNER T.; SPADACCINI, CHRISTOPHER M.; STADERMANN, MICHAEL; ZHU, CHENG
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 045848/0251 →
Continuity (2)
Division 14882127 · Oct 13, 2015
Related Publication 20180301678A1 · Oct 18, 2018