Lubricating oil compositions with engine wear protection
A method for improving wear control, while maintaining or improving solubility and fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component; and at least one metal salt of a carboxylic acid, as a minor component; wherein the metal salt of the carboxylic acid contains no sulfur or phosphorus; wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; wherein the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof; wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0. The lubricating oils are useful in internal combustion engines.
1. A method for improving wear control, while maintaining or improving solubility and fuel efficiency, in an engine or other mechanical component lubricated with a low phosphorus lubricating oil by using as the low phosphorus lubricating oil a low phosphorus formulated oil, said low phosphorus formulated oil having a composition comprising:
a lubricating oil base stock as a major component;
at least one phosphorus-containing additive; and
at least one metal salt of a carboxylic acid, as a minor component, that contains no sulfur or phosphorus, wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; and the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof;
wherein a molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0; and wear control is improved and solubility and fuel efficiency are maintained or improved as compared to wear control, solubility and fuel efficiency achieved using a lubricating oil containing a minor component other than the at least one metal salt of a carboxylic acid.
2. The method of claim 1 wherein the lubricating oil base stock comprises a Group I, Group II, Group III, Group IV or Group V base oil.
3. The method of claim 1 wherein the carboxylic acid is an aliphatic, saturated, unbranched carboxylic acid having from 8 to 26 carbon atoms, and mixtures thereof.
4. The method of claim 1 wherein the carboxylic acid is selected from the group consisting of caprylic acid (C8), pelargonic acid (C9), capric acid (C10), undecylic acid (C11), lauric acid (C12), tridecylic acid (C13), myristic acid (C14), pentadecylic acid (C15), palmitic acid (C16), margaric acid (C17), isostearic acid (C18), stearic acid (C18), nonadecylic acid (C19), arachidic acid (C20), heneicosylic acid (C21), behenic acid (C22), tricosylic acid (C23), lignoceric acid (C24), pentacosylic acid (C25), cerotic acid (C26), and mixtures thereof.
5. The method of claim 1 wherein the at least one metal salt of a carboxylic acid comprises zinc stearate, silver stearate, palladium stearate, zinc palmitate, silver palmitate, palladium palmitate, or mixtures thereof.
6. The method of claim 1 wherein the at least one metal salt of a carboxylic acid is present in an amount of from 0.01 weight percent to 5 weight percent, based on the total weight of the formulated oil.
7. The method of claim 1 wherein the formulated oil further comprises at least one metal salt of an organic acid, or at least one metal salt of an inorganic acid, or at least one metal salt of a phenol, or mixtures thereof, as a minor component.
8. The method of claim 7 wherein the metal comprises an alkali metal, an alkaline earth metal, or mixtures thereof.
9. The method of claim 8 wherein the metal comprises calcium (Ca), or magnesium (Mg), or mixtures thereof.
10. The method of claim 7 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or the at least one metal salt of a phenol comprises calcium sulfonate, magnesium sulfonate, calcium salicylate, magnesium salicylate, calcium phenate, magnesium phenate, or mixtures thereof.
11. The method of claim 7 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or at least one metal salt of a phenol is present in an amount of from 0.01 weight percent to 5 weight percent, based on the total weight of the formulated oil.
12. The method of claim 1 wherein the lubricating oil base stock is present in an amount of from 70 weight percent to 95 weight percent, based on the total weight of the formulated oil.
13. The method of claim 1 wherein the formulated oil further comprises one or more of a viscosity modifier, antioxidant, detergent, dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.
14. The method of claim 1 wherein the phosphorus of the formulated oil is derived from a zinc dialkyl dithiophosphate.
15. The method of claim 1 wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 10.0.
16. A lubricating oil having a low phosphorus composition comprising:
a lubricating oil base stock as a major component;
at least one phosphorus-containing additive; and
at least one metal salt of a carboxylic acid, as a minor component, that contains no sulfur or phosphorus, wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; and the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof;
wherein a molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0; and wear control is improved and solubility and fuel efficiency are maintained or improved as compared to wear control, solubility and fuel efficiency achieved using a lubricating oil containing a minor component other than the at least one metal salt of a carboxylic acid.
17. The lubricating oil of claim 16 wherein the lubricating oil base stock comprises a Group I, Group II, Group III, Group IV or Group V base oil.
18. The lubricating oil of claim 16 wherein the carboxylic acid is an aliphatic, saturated, unbranched carboxylic acid having from 8 to 26 carbon atoms, and mixtures thereof.
19. The lubricating oil of claim 16 wherein the carboxylic acid is selected from the group consisting of caprylic acid (C8), pelargonic acid (C9), capric acid (C10), undecylic acid (C11), lauric acid (C12), tridecylic acid (C13), myristic acid (C14), pentadecylic acid (C15), palmitic acid (C16), margaric acid (C17), isostearic acid (C18), stearic acid (C18), nonadecylic acid (C19), arachidic acid (C20), heneicosylic acid (C21), behenic acid (C22), tricosylic acid (C23), lignoceric acid (C24), pentacosylic acid (C25), cerotic acid (C26), and mixtures thereof.
20. The lubricating oil of claim 16 wherein the at least one metal salt of a carboxylic acid comprises zinc stearate, silver stearate, palladium stearate, zinc palmitate, silver palmitate, palladium palmitate, or mixtures thereof.
21. The lubricating oil of claim 16 wherein the at least one metal salt of a carboxylic acid is present in an amount of from 0.01 weight percent to 5 weight percent, based on the total weight of the formulated oil.
22. The lubricating oil of claim 16 further comprising at least one metal salt of an organic acid, or at least one metal salt of an inorganic acid, or at least one metal salt of a phenol, or mixtures thereof, as a minor component.
23. The lubricating oil of claim 22 wherein the metal comprises an alkali metal, an alkaline earth metal, or mixtures thereof.
24. The lubricating oil of claim 23 wherein the metal comprises calcium (Ca), magnesium (Mg), or mixtures thereof.
25. The lubricating oil of claim 22 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or the at least one metal salt of a phenol comprises calcium sulfonate, magnesium sulfonate, calcium salicylate, magnesium salicylate, calcium phenate, magnesium phenate, or mixtures thereof.
26. The lubricating oil of claim 22 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or at least one metal salt of a phenol is present in an amount of from 0.01 weight percent to 5 weight percent, based on the total weight of the formulated oil.
27. The lubricating oil of claim 16 wherein the lubricating oil base stock is present in an amount of from 70 weight percent to 95 weight percent, based on the total weight of the formulated oil.
28. The lubricating oil of claim 16 further comprising one or more of a viscosity modifier, antioxidant, detergent, dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.
29. The lubricating oil of claim 16 which is a passenger vehicle engine oil (PVEO).
30. The lubricating oil of claim 16 wherein the at least one phosphorus-containing additive comprises zinc dialkyl dithiophosphate.
31. The lubricating oil of claim 16 wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 10.0.
32. The method of claim 7 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or the at least one metal salt of a phenol comprises an overbased detergent, or mixtures thereof.
33. The lubricating oil of claim 16 wherein the at least one metal salt of an organic acid, the at least one metal salt of an inorganic acid, or the at least one metal salt of a phenol comprises an overbased detergent, or mixtures thereof.