Method and apparatus for processing substrate

1. A method of processing a substrate, the method comprising:

first forming, by chemical vapor deposition and by using plasma generated from a gas containing carbon, a first film in a first region of the substrate in a chamber of a processing apparatus, and

second forming, by introducing a precursor of material adsorbed with the substrate into the chamber, introducing modifying gas into the chamber, and generating plasma from the modifying gas, a second film in a second region of the substrate in the chamber,

wherein the first forming and the second forming are performed without moving the substrate out of the chamber,

wherein the first forming deposits the first film by fluorocarbon plasmas, and

wherein the first film contains carbon.

2. The method according to claim 1 , further comprising:

etching the substrate,

wherein the first forming, the second forming, and the etching are performed without moving the substrate out of the chamber.

3. A method of processing a substrate, the method comprising:

first forming, by chemical vapor deposition, a first film in a first region of the substrate in a chamber of a processing apparatus,

second forming, by introducing a precursor of material adsorbed with the substrate into the chamber, introducing modifying gas into the chamber, and generating plasma from the modifying gas, a second film in a second region of the substrate in the chamber, and

etching the substrate,

wherein the etching performs an atomic layer etching and includes:

modifying a surface of the substrate by one of N plasma and H plasma,

purging the chamber, and

removing the surface modified by the one of N plasma and the H plasma by halogen gas, and

wherein the first forming, the second forming, and the etching are performed without moving the substrate out of the chamber.

4. The method according to claim 1 , further comprising:

applying a voltage to a lower electrode during the chemical vapor deposition, the lower electrode being arranged opposite to an antenna and configured to hold the substrate thereon, and the lower electrode and the antenna being controlled by a controller, and

applying a voltage to the antenna in a modification step of the second forming step.

5. The method according to claim 1 , further comprising:

applying a voltage to a lower electrode without applying a voltage to an antenna during the chemical vapor deposition, the lower electrode being arranged opposite to the antenna and configured to hold the substrate thereon, and the lower electrode and the antenna being controlled by a controller; and

applying a voltage to the antenna without applying a voltage to the lower electrode in a modification step of the second forming step.

6. The method according to claim 1 , further comprising:

applying a voltage to a lower electrode and an antenna during the chemical vapor deposition, the lower electrode being arranged opposite to the antenna and configured to hold the substrate thereon, and the lower electrode and the antenna being controlled by a controller, and

maintaining, by the controller, a voltage applied to the antenna at such a level as to prevent damage to the substrate.

7. The method according to claim 1 , further comprising:

applying a voltage to a lower electrode and an antenna during a modification step of the second forming step, the lower electrode being arranged opposite to the antenna and configured to hold the substrate thereon, and the lower electrode and the antenna being controlled by a controller, and

maintaining, by the controller, a voltage applied to the lower electrode at such a level as to prevent damage to the substrate or to generate plasma of a low ion energy.

8. A method of processing a substrate, the method comprising:

first forming, by chemical vapor deposition, a first film as a hydrophobic surface on a first region of a hydrophilic surface of the substrate in a chamber of a processing apparatus, and

second forming, by introducing a precursor of material adsorbed with the substrate into the chamber, introducing modifying gas into the chamber, and generating plasma from the modifying gas, a second film by adsorbing, on a second region of the hydrophilic surface of the substrate in the chamber, the precursor which reacts with a hydroxyl group,

the first forming and the second forming being performed without moving the substrate out of the chamber.

9. The method according to claim 1 , wherein

the second forming removes at least a part of the first film from the substrate.

10. The method according to claim 1 , wherein

the first forming performs one of an anisotropic CVD and an isotropic CVD by controlling a voltage applied to the lower electrode.

11. The method according to claim 1 , wherein

the first forming forms the first film on a top region and a bottom region of a feature of the substrate, and

the second forming forms the second film on a sidewall of the feature of the substrate.

12. The method according to claim 1 , wherein

the substrate contains at least one of SiO 2 , SiN, Si and Ge, and

the second forming forms a Si-containing film as the second film.

13. The method according to claim 1 , wherein the first forming and the second forming are performed repeatedly in this order.

14. The method according to claim 13 , further comprising

ceasing the second forming before the second forming removes the first film completely, and

performing the first forming while the first film remains on the substrate.

15. The method according to claim 1 , wherein the first forming and the second forming are performed by using inductively-coupled plasmas or capacitively-coupled plasmas.

16. The method according to claim 1 , wherein the substrate has a hydrophilic surface or a surface subjected to hydrophilic treatment.

17. The method according to claim 1 , further comprising

etching the substrate,

wherein the etching is performed in a different chamber from the chamber in which the first forming and the second forming are performed.

18. The method according to claim 1 , further comprising

determining whether a predetermined condition has been met after the first forming and the second forming, and

repeating a cycle including the first forming and the second forming when the determining determines that the predetermined condition has not been met.

19. The method according to claim 1 , wherein

the gas containing carbon is selected from the group consisting of fluoro-carbon gas, hydro-fluoro carbon gas, and hydro carbon gas.

20. The method according to claim 1 , wherein the first region of the substrate and the second region of the substrate do not substantially overlap.

21. The method according to claim 1 , wherein the second forming step is conducted after the first forming step.