Neutral to alkaline chemical mechanical polishing compositions and methods for tungsten
View Patent ↗A neutral to alkaline chemical mechanical composition for polishing tungsten includes, as initial components: water; an oxidizing agent selected from an iodate compound, a periodate compound and mixtures thereof; colloidal silica abrasive particles including a nitrogen-containing compound; optionally, a pH adjusting agent; and, optionally, a biocide. The chemical mechanical polishing method includes providing a chemical mechanical polishing pad, having a polishing surface; creating dynamic contact at an interface between the polishing pad and the substrate; and dispensing the neutral to alkaline chemical mechanical polishing composition onto the polishing surface at or near the interface between the polishing pad and the substrate; wherein some of the tungsten is polished away from the substrate and, further, to at least inhibit static etch of the tungsten.
1. A method of chemical mechanical polishing tungsten, comprising:
providing a substrate comprising tungsten and a dielectric;
providing a chemical mechanical polishing composition, comprising, as initial components:
water;
an oxidizing agent selected from the group consisting of iodate compounds, periodate compounds and mixtures thereof;
colloidal silica abrasive particles comprising a nitrogen-containing compound;
optionally, a pH adjusting agent; and
optionally, a biocide; and wherein a pH of the chemical mechanical polishing composition is equal to or greater than 7;
providing a chemical mechanical polishing pad, having a polishing surface;
creating dynamic contact at an interface between the chemical mechanical polishing pad and the substrate; and
dispensing the chemical mechanical polishing composition onto the polishing surface of the chemical mechanical polishing pad at or near the interface between the chemical mechanical polishing pad and the substrate to remove at least some of the tungsten, wherein the chemical mechanical polishing composition has a tungsten removal rate of ≥500 Å/min with a platen speed of 93-113 revolutions per minute, a carrier speed of 87-111 revolutions per minute, a chemical mechanical polishing composition flow rate of 125-300 mL/min, a nominal down force of 21.4 kPa on a 200 mm polishing machine; and, wherein the chemical mechanical polishing pad comprises a polyurethane polishing layer containing polymeric hollow core microparticles and a polyurethane impregnated non-woven subpad.
2. The method of chemical mechanical polishing tungsten of claim 1 , wherein the iodate compounds are selected from the group consisting of alkali metal iodates, calcium diiodate, magnesium diiodate, ammonium iodate and mixtures thereof.
3. The method of chemical mechanical polishing tungsten of claim 1 , wherein the periodate compounds are selected from the group consisting of alkali metal periodates, calcium diperiodate, magnesium diperiodate, ammonium periodate and mixtures thereof.