Reactive flame retardants for flexible polyurethane foams
The present invention provides dialkyl phosphorus-containing compounds, namely reactive mono-hydroxyl-functional dialkyl phosphinates, serving as highly efficient reactive flame retardants in flexible polyurethane foams. The invention further provides fire-retarded polyurethane compositions comprising said the reaction product of the mono-hydroxyl-functional dialkyl phosphinates with polyol and isocyanate foam forming components.
1. A flame-retarded flexible polyurethane foam comprising the reaction product of a polyol, an isocyanate and a flame retardant-effective amount of a mono-hydroxyl-functional dialkyl phosphinate compound of the formula (I-A):
wherein:
R 1 and R 2 are selected from a linear or branched alkyl group containing from 1 to 4 carbon atoms; and,
X is either ------(Z) k —R 3 or
and when X is ------(Z) k —R 3 , Z is —(Y—O) n —, wherein Y is a linear or branched alkylene group containing from 2 to 8 carbon atoms and n represents an integer from 1 to 20;
k may be 0 or 1;
R 3 is selected from hydrogen, a mono-hydroxy-terminated linear or branched alkylene group containing from 2 to about 8 carbon atoms; and,
provided that when k is zero, R 3 is the mono-hydroxy-terminated linear or branched alkylene group and when k is 1, R 3 is hydrogen, and
when X is
R 4 and R 5 are each independently selected from H, a linear or branched alkyl group containing from 1 to 8 carbon atoms, a linear or branched alkenyl group containing from 2 to 8 carbon atoms, a halo-substituted alkyl group containing from 1 to 8 carbon atoms, an alkoxy group containing from 1 to 8 carbon atoms, an aryl group containing from 6 to 12 carbon atoms and an alkylaryl group containing from 7 to 16 carbon atoms, or R 4 and R 5 are bonded to each other to form a cycloalkyl group containing from 5 to about 8 carbon atoms.
2. The flame-retarded flexible polyurethane foam of claim 1 , wherein R 1 and R 2 are each an ethyl group.
3. The flame-retarded flexible polyurethane foam of claim 1 , wherein the mono-hydroxyl-functional dialkyl phosphinate compound has the formula (I-A-1):
4. The flame-retarded flexible polyurethane foam of claim 3 , wherein R 1 and R 2 are each an ethyl group.
5. The flame-retarded flexible polyurethane foam of claim 1 wherein the mono-hydroxyl-functional dialkyl phosphinate compound has the formula (I-A-2):
6. The flame-retarded flexible polyurethane foam of claim 5 , wherein R 1 and R 2 are each an ethyl group.
7. An article comprising the polyurethane foam of claim 1 .
8. The article of claim 7 , wherein the article is suitable for use in an application selected from the group consisting of furniture applications, automotive applications, boating applications, bus seating applications, train seating applications, RV seating applications, office furniture seating applications, aviation applications, tractor applications, bicycle applications, engine mount applications, compressor applications, bedding applications, insulation applications, sporting goods applications, shoe applications, carpet cushioning applications, packaging applications, textile applications, buffer cushioning applications, HVAC applications, tent applications, life raft applications, luggage applications, and hand bag applications.
9. The article of claim 8 , wherein said furniture applications are selected from upholstered furniture applications.
10. The article of claim 8 , wherein said automotive applications are selected from the group consisting of automotive seat cushions, head linings and head rests, back cushions for automobiles and trucks, bus seating, vehicle seat bottom and back bolsters, armrests, and support rings for run flat tires.
11. The article of claim 8 , wherein said bedding applications are selected from the group consisting of mattresses and mattress top applications.
12. The article of claim 8 , wherein said insulation applications are sound insulation applications.