IP Library › Granted Patent US 11,066,929
Granted Patent B2
US 11,066,929 · App. 16/046,095 · Granted Jul 20, 2021

Identifying oil and gas reservoirs with oxygen isotopes

Inventor: Feng Hu Lu (Dhahran, SA)
Assignee: Saudi Arabian Oil Company
E21B49/02E21B49/00G01N33/241G01V9/007G01V11/005
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Quick Facts
Patent No.
US 11,066,929
App. No.
16/046,095
Granted
Jul 20, 2021
Kind
B2
Abstract

Carbonate samples are received from a wellbore formed in a geologic formation. An oxygen isotope ratio and carbon isotope ratio present within each of the carbonate samples are determined. A mineral composition of each of the carbonate samples is determined. A plot showing the determined oxygen isotope ratios versus a depth from where within the wellbore each of the carbonate samples was obtained is created. One or more negative oxygen isotope shifts are identified based on the plot. Natural carbonate cement levels within one or more of the plurality of carbonate samples that correspond to the one or more negative oxygen isotope shifts identified in the plot are determined. One or more production sweet spots are determined based on the identified negative oxygen isotope shifts and the determined natural carbonate cement levels.

Claims (29)

1. A method comprising:

receiving a plurality of carbonate samples from a wellbore formed in a geologic formation;

determining an oxygen isotope ratio and carbon isotope ratio present within each of the plurality of carbonate samples;

determining a mineral composition of each of the plurality of carbonate samples;

mixing a solution comprising a red dye, potassium ferricyanaide, water, and hydrochloric acid;

placing thin slabs made from each of the plurality of carbonate samples in the solution at 25° C. for 1-2 minutes;

identifying one or more minerals within each of the thin slabs based on a degree of color change that occurs while each of the plurality of the thin slabs is in the solution;

creating a plot showing the determined oxygen isotope ratios versus a depth from where within the wellbore each of the plurality of carbonate samples was obtained;

identifying, based on the plot, one or more negative oxygen isotope shifts;

determining natural carbonate cement levels within one or more of the plurality of carbonate samples that correspond to the one or more negative oxygen isotope shifts identified in the plot; and

determining one or more production sweet spots based on the identified negative oxygen isotope shifts and the determined natural carbonate cement levels.

2. The method of claim 1 , wherein the oxygen isotope ratio and the carbon isotope ratio is determined with an isotope ratio mass spectrometer.

3. The method of claim 1 , wherein substantially no color change indicates a presence of dolomite within the thin slab.

4. The method of claim 1 , wherein determining the natural carbonate cement levels comprises visually checking porosity of one or more of the plurality of samples with a microscope.

5. The method of claim 1 , wherein the plurality of samples comprises one sample per every one-foot interval within the wellbore.

6. The method of claim 1 , further comprising pulverizing at least a portion of each of the plurality of samples into a powder.

7. The method of claim 6 , wherein the portion of each of the plurality of samples that is pulverized into powder produces substantially 300 micrograms of powder.

8. The method of claim 6 , wherein the powder does not include cement.

9. The method of claim 6 , further comprising preparing the powdered samples, the preparation for each sample comprising:

drying the powder at substantially 50° C. for substantially 8-12 hours;

transferring the dried powder to a reaction vial;

vacuum-sealing the reaction vial;

introducing H 3 PO 4 to the powdered sample;

producing CO 2 gas in response to introducing the H 3 PO 4 ; and

determining a carbon isotope ratio and an oxygen isotope ratio simultaneously in response to producing the CO 2 gas.

10. The method of claim 1 , further comprising planning wellbore completion operations at least partially based upon the one or more determined production sweet spots.

11. The method of claim 1 , further comprising:

comparing the determined oxygen isotope ratios and the determined carbon isotope ratios; and

verifying the determined oxygen isotope ratios based on the comparison.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2018
From: LU, FENG HU
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 046470/0349 →
Continuity (2)
Provisional Application 62545637 · Aug 15, 2017
Related Publication 20190055842A1 · Feb 21, 2019
Cited By (3)
US 12,352,738 US 12,436,140 US 12,680,994