Curable resin system containing quantum dots
A polymer composite comprising quantum dots. The polymer composite comprises: (a) quantum dots; (b) a first polymer having a molecular weight from 1,000 to 100,000 and a solubility parameter from 12 to 17 (J/cm 3 ) 1/2 ; (c) a second polymer comprising polymerized units of a first compound comprising at least one readily polymerizable vinyl group and having a molecular weight from 72 to 500, wherein the second polymer has a solubility parameter from 16.5 to 20 (J/cm 3 ) 1/2 ; and (d) a third polymer comprising polymerized units of a second compound comprising at least two readily polymerizable vinyl groups and having a molecular weight from 72 to 2000; wherein the first polymer encapsulates the quantum dots; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring.
1. A polymer composite comprising quantum dots; said polymer composite comprising: (a) quantum dots; (b) a first polymer having a molecular weight from 1,000 to 100,000 kg/mol, a solubility parameter from 12 to 17 MPa 1/2 at 25° C., wherein the first polymer is selected from the group consisting of maleic anhydride (MA)-olefin copolymers, acrylic-olefin copolymers, styrene-MA copolymers, and oxidized polyethylene, and wherein the first polymer encapsulates the quantum dots; (c) a second polymer comprising polymerized units of a first compound comprising at least one readily polymerizable vinyl group and having a molecular weight from 72 to 500 kg/mol selected from the group consisting of isobornyl (meth)acrylate, C 2 -C 18 alkyl(meth)acrylates, L-menthylacrylate, tricyclo[5.2.1.0 2,6 ]-decylmethyl acrylate, C 1 -C 6 alkylstyrenes, and 3,3,5-trimethylcyclohexyl methacrylate, wherein the second polymer has a solubility parameter from 16.5 to 20 MPa 1/2 at 25° C., and wherein the second polymer surrounds the particles of encapsulated quantum dots; and (d) a third polymer comprising polymerized units of a second compound comprising at least two readily polymerizable vinyl groups and having a molecular weight from 72 to 2000 kg/mol selected from the group consisting of tricyclo [5.2.1.0 2,6 ] decane dimethanol di(meth)acrylate, Bisphenol A di(meth)acrylate, Bisphenol A glycerolate di(meth)acrylate, 2-butyl-2-ethyl-1,3-propanediol dimethacrylate, 1,10-bis(acryloyloxy)decane and
and urethane acrylate oligomers which can be polyester type, polyether type, polybutadiene type, or polycarprolactone type.
2. The polymer composite of claim 1 in which the solubility parameter of the second polymer minus the solubility parameter of the first polymer is at least 0.5 MPa 1/2 at 25° C.
3. The polymer composite of claim 1 comprising from 2 to 20 wt % of the first polymer, from 2 to 20 wt % of the second polymer, from 70 to 94 wt % of the third polymer and 0.05 to 2 wt % of quantum dots.
4. A method for producing the polymer composite; said method comprising steps of:
(a) precipitating encapsulated quantum dots from a mixture comprising quantum dots, a first polymer having a molecular weight from 1,000 to 100,000 kg/mol and a solubility parameter from 12 to 17 MPa 1/2 at 25° C. and a solvent;
(b) spray drying the solution and encapsulated quantum dots from step (a) together with a second polymer comprising polymerized units of a first compound comprising at least one readily polymerizable vinyl group and having a molecular weight from 72 to 500 kg/mol and a solubility parameter from 16.5 to 20 MPa 1/2 at 25° C. to produce an encapsulated quantum dot powder; and
(c) dispersing the encapsulated quantum dot powder in a second compound comprising at least two readily polymerizable vinyl groups and having a molecular weight from 72 to 2000 kg/mol and curing to form a polymer composite; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring.