Process for producing taurine
There is disclosed a process for producing taurine by reacting 2-oxazolidinone with ammonium sulfite, or ammonium bisulfite, or a mixture of ammonium sulfite and ammonium bisulfite in an aqueous solution to form ammonium taurinate and ammonium bicarbonate. Taurine is obtained by decomposing ammonium taurinate to taurine and ammonia and recovered by solid-liquid separation.
1. A process for producing taurine from 2-oxazolidinone, comprising:
(a) reacting 2-oxazolidinone with ammonium sulfite, or ammonium bisulfite, or a mixture of ammonium sulfite and ammonium bisulfite in an aqueous solution to form ammonium taurinate and ammonium bicarbonate;
(b) decomposing ammonium taurinate and ammonium bicarbonate to taurine, ammonia, and carbon dioxide by heating and removing ammonia and carbon dioxide to obtain a crystalline suspension of taurine; and
(c) separating taurine by means of solid-liquid separation.
2. The process according to claim 1 , wherein the molar ratio of 2-oxazolidinone to ammonium sulfite or bisulfite is from 0.9 to 10.
3. The process according to claim 1 , wherein the molar ratio of 2-oxazolidinone to ammonium sulfite or bisulfite is from 1.0 to 2.0.
4. The process according to claim 1 , wherein the molar ratio of 2-oxazolidinone to ammonium sulfite or bisulfite is from 1.0 to 1.2.
5. The process according to claim 1 , wherein the reaction of 2-oxazolidinone with ammonium sulfite or bisulfite is carried out in a pH range from 5.0 to 9.0.
6. The process according to claim 1 , wherein the reaction of 2-oxazolidinone with ammonium sulfite or bisulfite is carried out in a pH range from 6.0 to 8.0.
7. The process according to claim 1 , wherein the reaction of 2-oxazolidinone with ammonium sulfite or bisulfite is carried out at a temperature from 60° C. to 160° C.
8. The process according to claim 1 , wherein the reaction of 2-oxazolidinone with ammonium sulfite or bisulfite is carried out at a temperature from 90° C. to 120° C.
9. The process according to claim 1 , wherein the yield of taurine from 2-oxazolidinone is at least 80%.