Systems and methods for separating gases
View Patent ↗The invention pertains to processes for separating gases, acid gas, hydrocarbons, air gases, or combinations thereof. The processes may employ using a liquid phase cloud point with or without subsequent liquid-liquid separation. In some embodiments membranes can be employed with reverse osmosis to regenerate a solvent and/or an antisolvent. In some embodiments thermal switching phase changes may be employed during absorption or desorption to facilitate separation.
1. A process for separating gas comprising:
absorbing one or more gases in a liquid system comprising one or more physical solvents,
wherein said one or more physical solvents comprise one or more liquid phases in the liquid system; and
changing the number or composition or combination thereof of liquid phases in said liquid system by changing one or more system conditions wherein the temperature of said liquid system is greater than −30° C. and less than 500° C. during the changing; desorbing
at least one gas of said one or more gases; and
reversing said change to the number or composition or combination thereof of liquid phases in said liquid system.
2. The process of claim 1 wherein two or more steps occur simultaneously.
3. The process of claim 1 wherein the temperature of said liquid system is greater than −15° C. and less than 50° C. during the changing.
4. The process of claim 1 wherein the liquid system phases change during, or after said absorbing step.
5. The process of claim 1 wherein the liquid system changes from two or more liquid phases to one liquid phase.
6. The process of claim 1 wherein the liquid system changes from one liquid phase to two or more liquid phases.
7. The process of claim 1 wherein, during said absorbing one or more gases step, the liquid system phases change at a lower critical solution temperature or an upper critical solution temperature to generate heat and wherein at least a portion of any heat generated is absorbed.
8. The process of claim 7 , further comprising releasing at least a portion of absorbed heat.
9. The process of claim 1 which further comprises a separation step prior to said absorbing step.
10. The process of claim 1 , wherein the liquid system changes from two or more phases to one phase prior or during desorbing of at least one gas from at least one liquid solution phase.
11. The process of claim 1 wherein the one or more physical solvents comprise at least a portion of an organic solvent, or an organic polymer, or a combination thereof.
12. The process of claim 1 wherein said changing the number or composition or combination thereof of liquid phases in said liquid system results in one or more of the following: (1) change in the solubility of one or more gases; (2) change in the partial pressure of one or more gases; (3) change in the partial pressure of one or more gases to facilitate the desorption of one or more gases; (4) change in the partial pressure of one or more gases to facilitate the absorption of one or more gases; (5) release heat; (6) absorb heat; (7) change the solubility of one or more gases relative to the solubility of one or more other gases; or (8) a combination thereof.
13. The process of claim 12 wherein one or more liquid phases comprise a physical solvent and one or more liquid phases comprise an antisolvent;
further comprising desorbing one or more gases and separating said antisolvent from said physical solvent during or following desorbing.
14. The process of claim 12 wherein one or more liquid phases comprise a physical solvent and one or more liquid phases comprise an antisolvent;
wherein said antisolvent comprises at least a portion of water, or an ionic compound, or a reagent possessing low solubility of one or more gases, or a combination thereof.
15. The process of claim 12 wherein one or more liquid phases comprise a physical solvent and one or more liquid phases comprise an antisolvent;
and where the process further comprises regenerating said one or more liquid phases by controlling the conditions such that at least one liquid phase comprises a substantial concentration of said antisolvent, or at least one liquid phase comprises a substantial concentration of said physical solvent, or both.