IP Library Granted Patent US 10,787,601
Granted Patent B2
US 10,787,601 · App. 16/250,134 · Granted Sep 29, 2020

Breaker fluids and methods of use thereof

Inventor: Thomas Donovan Welton (Conroe, TX)
Assignee: Shrieve Chemical Products, Inc.
C09K8/52C08F220/54C08F220/56C09K8/035C09K8/12C09K8/5083C09K8/512E21B21/003E21B37/00E21B37/08E21B43/082E21B43/10E21B43/25G01V3/20G01V3/34C08F212/14C08F228/02C09K2208/26
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Quick Facts
Patent No.
US 10,787,601
App. No.
16/250,134
Granted
Sep 29, 2020
Kind
B2
Abstract

A method may include circulating a breaker fluid into a wellbore having a filtercake on the walls thereon, the filter cake including copolymer formed from at least one acrylamide monomer and at least one sulfonated anionic monomer, the breaker fluid comprising: a base fluid; and a mixture of hydrolysable esters of dicarboxylic acids.

Claims (19)

1. A method of breaking a filter cake in a wellbore having a wall, comprising:

circulating a breaker fluid into the wellbore having a filter cake on the walls of the wellbore, the filter cake including at least one polymer, the breaker fluid comprising:

a base fluid;

a mixture of hydrolysable esters of dicarboxylic acids comprising about 27-67 wt. % dimethyl glutarate, about 9-28 wt. % dimethyl succinate, and about 4-22 wt. % dimethyl adipate; and

lactide.

2. The method of claim 1 , wherein the breaker fluid comprises about 50 wt. % lactide, about 27-34 wt. % dimethyl glutarate, about 9-14 wt. % dimethyl succinate, and about 4-11 wt. % dimethyl adipate and further wherein the breaker fluid further comprises at least one chelant agent at about 5-20% by volume of the breaker fluid.

3. The method of claim 1 , wherein relative to the total amount of lactide and the mixture of hydrolysable esters of dicarboxylic acid esters in the breaker fluid, the mixture of dicarboxylic acid esters forms about 10-99 wt. % and lactide forms about 1 to 90 wt. %.

4. A downhole treatment composition, comprising:

a glycol ether;

lactide; and

an aqueous fluid wherein the weight percent of the glycol ether to the lactide is within the range of about 20-80%;

wherein the downhole treatment composition comprises a single-phase composition.

5. The composition of claim 4 , wherein the glycol ether is formed from C1-C6 alcohols and C2-12 glycols.

6. The composition of claim 5 , wherein the glycol ether is dipropylene glycol methyl ether.

7. The composition of claim 4 , wherein the aqueous fluid comprises sea water, tap water, freshwater, produced water, brine or combinations thereof.

8. The composition of claim 7 , wherein the brine comprises a saturated solution of an inorganic salt.

9. The composition of claim 8 , wherein the inorganic salt comprises sodium bromide.

10. The composition of claim 4 further comprising dimethyl glutarate, dimethyl succinate, dimethyl adipate or combinations thereof.

11. The composition of claim 4 further comprising a surfactant.

Assignments (4)
PATENT SECURITY AGREEMENT Recorded Oct 31, 2024
From: SHRIEVE CHEMICAL PRODUCTS, LLC
To: SILVER POINT FINANCE, LLC
Reel/Frame 069286/0282 →
RELEASE OF GRANT OF A SECURITY INTEREST -- PATENTS Recorded Oct 31, 2024
From: CERBERUS BUSINESS FINANCE AGENCY, LLC
To: SHRIEVE CHEMICAL PRODUCTS, LLC
Reel/Frame 069288/0628 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 24, 2020
From: WELTON, THOMAS DONOVAN
To: SHRIEVE CHEMICAL PRODUCTS, INC.
Reel/Frame 053572/0174 →
GRANT OF A SECURITY INTEREST -- PATENTS Recorded Dec 2, 2019
From: SHRIEVE CHEMICAL PRODUCTS, LLC
To: CERBERUS BUSINESS FINANCE AGENCY, LLC, AS COLLATERAL AGENT
Reel/Frame 051157/0611 →
Continuity (3)
Continuation 15400354 · Jan 6, 2017
Provisional Application 62276080 · Jan 7, 2016
Related Publication 20190144736A1 · May 16, 2019
Cited By (1)
US 12,391,863