Breaker fluids and methods of use thereof
A method of breaking a filtercake in a wellbore may include circulating a breaker fluid into the wellbore having a filtercake on the walls thereon, the filter cake including copolymer formed from at least one acrylamide monomer and at least one sulfonated anionic monomer, the breaker fluid comprising: a base fluid; a mixture of hydrolysable esters of dicarboxylic acids; and an organic peroxide oxidant.
1. A method of breaking a filtercake in a wellbore, comprising:
circulating a breaker fluid into the wellbore, thereby breaking a filtercake on walls of the wellbore, wherein the filtercake includes a copolymer formed from at least one acrylamide monomer and at least one sulfonated anionic monomer, the breaker fluid comprising:
a base fluid;
a mixture of hydrolysable esters of dicarboxylic acids; and
an oxidant composed of an organic peroxide;
wherein the organic peroxide is tert-butyl hydroperoxide;
wherein the organic peroxide is included in the breaker fluid at about 15 ppb; and
wherein the breaker fluid achieves a flowback of at least 50% at temperatures from 300 to 400° F.
2. The method of claim 1 , wherein the at least one acrylamide monomer is at least one selected from unsubstituted acrylamide, alkylacrylamides, N-methylol acrylamide, N-isopropyl acrylamide, diacetone-acrylamide, C1 to C14 N-alkyl acrylamide, C1 to C14 N,N-dialkyl acrylamides, N-cycloalkane acrylamides, or combinations thereof.
3. The method of claim 1 , wherein the at least one sulfonated anionic monomer is selected from 2-acrylamide-2-methyl-propanesulfonic acid, vinyl sulfonate, and styrene sulfonic acid.
4. The method of claim 1 , wherein the copolymer contains covalent intermolecular crosslinking.
5. The method of claim 1 , wherein the mixture of hydrolysable esters of dicarboxylic acids includes about 57-67 wt. % dimethyl glutarate, 18-28 wt. % dimethyl succinate, and 8-22 wt. % dimethyl adipate.
6. The method of claim 1 , wherein the mixture of hydrolysable esters of dicarboxylic acids is about 5% to 30% by volume of the breaker fluid.
7. The method of claim 1 , wherein the base fluid is a divalent brine.
8. The method of claim 1 , wherein the breaker fluid further comprises a coating on the oxidant to delay release of the oxidant.
9. A method of performing a wellbore operation, comprising:
pumping a wellbore fluid into a wellbore through an earthen formation, the wellbore fluid comprising:
a first base fluid; and
a polymeric fluid loss control agent formed from at least an acrylamide monomer and a sulfonated anionic monomer;
operating a drilling tool in the wellbore during the pumping the wellbore fluid into the wellbore;
circulating a breaker fluid into the wellbore, thereby breaking a filtercake on walls of the wellbore; wherein the filtercake includes the polymeric fluid loss control agent, the breaker fluid comprising:
a second base fluid;
a mixture of hydrolysable esters of dicarboxylic acids; and
an oxidant composed of an organic peroxide;
wherein the organic peroxide is tert-butyl hydroperoxide;
wherein the organic peroxide is included in the breaker fluid at about 15 ppb; and
wherein the breaker fluid achieves a flowback of at least 50% at temperatures from 300 F to 400° F.
10. The method of claim 9 , wherein the wellbore fluid is pumped into the wellbore through a reservoir section of the wellbore during the operating the drilling tool in the wellbore.
11. The method of claim 10 , further comprising:
initiating production of hydrocarbons from the reservoir.
12. The method of claim 9 , wherein the acrylamide monomer is at least one selected from unsubstituted acrylamide, alkylacrylamides, N-methylol acrylamide, N-isopropyl acrylamide, diacetone-acrylamide, C1 to C14 N-alkyl acrylamide, C1 to C14 N,N-dialkyl acrylamides, N-cycloalkane acrylamides, or combinations thereof.
13. The method of claim 9 , wherein the sulfonated anionic monomer is selected from 2-acrylamide-2-methyl-propanesulfonic acid, vinyl sulfonate, and styrene sulfonic acid.
14. The method of claim 9 , wherein the polymeric fluid loss control agent contains covalent intermolecular crosslinking.
15. The method of claim 9 , wherein the mixture of hydrolysable esters of dicarboxylic acids includes about 57-67 wt. % dimethyl glutarate, 18-28 wt. % dimethyl succinate, and 8-22 wt. % dimethyl adipate.
16. The method of claim 9 , wherein the mixture of hydrolysable esters of dicarboxylic acids is about 5% to 30% by volume of the breaker fluid.
17. The method of claim 9 , wherein the base fluid is a divalent brine.