Concentric flow reactor
A gas phase nanowire growth apparatus including a reaction chamber, a first input and a second input. The first input is located concentrically within the second input and the first and second input are configured such that a second fluid delivered from the second input provides a sheath between a first fluid delivered from the first input and a wall of the reaction chamber.
1. A method of fabricating semiconductor nanowires comprising:
providing a first gas stream to a reaction chamber, wherein the first gas stream comprises a first precursor for fabricating the semiconductor nanowires; and
providing a second gas stream to the reaction chamber, wherein the second gas stream forms a sheath separating the first gas stream from a wall of the reaction chamber, wherein the first gas stream has a velocity that is higher than the second gas stream to result in an expansion in a diameter of the first gas stream;
providing nanowire growth catalyst particles;
wherein the semiconductor nanowires comprise single crystal Si, Ge, or Si x Ge 1−x semiconductor nanowires, wherein 0≤x≤1.
2. The method of claim 1 , wherein the nanowire growth catalyst particles are provided from an aerosol in at least one of the first gas stream or the second gas stream.
3. The method of claim 2 , wherein:
the nanowire growth catalyst particles are provided from an aerosol in the first gas stream; and
the first gas stream containing the catalyst particles flows sequentially through one or more reaction zones of the reaction chamber such that the semiconductor nanowires grow from the catalyst particles and the semiconductor nanowires grown after passage through the reaction zones are carried by the first gas stream surrounded the second gas stream sheath.
4. The method of claim 1 , wherein the sheath gas comprises nitrogen, hydrogen or a noble gas.
5. The method of claim 4 , wherein the noble gas comprises helium or argon.
6. The method of claim 1 , wherein the semiconductor nanowires comprise the single crystal Si semiconductor nanowires.
7. The method of claim 1 , wherein the semiconductor nanowires comprise the single crystal Ge semiconductor nanowires.
8. The method of claim 1 , wherein the semiconductor nanowires comprise the single crystal Si x Ge 1−x semiconductor nanowires.
9. A method of fabricating semiconductor nanowires comprising:
providing a first gas stream to a first reaction chamber, wherein the first gas stream comprises a core flow stream containing a first precursor for fabricating the semiconductor nanowires;
providing a second gas stream to the first reaction chamber, wherein the second gas stream forms a sheath separating the first gas stream from a wall of the first reaction chamber;
providing nanowire growth catalyst particles;
adding a first dopant gas having a first conductivity type to the first gas stream to grow semiconductor nanowires of the first conductivity type in a gas phase in the first reaction chamber;
removing the second gas stream from the first reaction chamber before it reaches a second reaction chamber;
providing the semiconductor nanowires from the first reaction chamber to the second reaction chamber;
providing a third gas stream to the second reaction chamber, wherein the third gas stream comprises a second precursor for fabricating the semiconductor nanowires;
providing a fourth gas stream to the second reaction chamber, wherein the fourth gas stream forms a sheath separating the third gas stream from a wall of the second reaction chamber; and
adding a second dopant gas having a second conductivity type into the second reaction chamber after the step of adding the first dopant gas to grow a p-n or p-i-n junction in the semiconductor nanowires in a gas phase in the second reaction chamber;
wherein the semiconductor nanowires comprise single crystal Si, Ge, or Si x Ge 1−x semiconductor nanowires, wherein 0≤x≤1.
10. The method of claim 9 , wherein the sheath gas comprises nitrogen, hydrogen or a noble gas.
11. The method of claim 10 , wherein the noble gas comprises helium or argon.
12. The method of claim 9 , wherein the nanowire growth catalyst particles are provided from an aerosol in at least one of the first gas stream or the second gas stream.
13. The method of claim 9 , wherein the nanowire growth catalyst particles are provided from an aerosol in the first gas stream.
14. The method of claim 9 , wherein the semiconductor nanowires comprise the single crystal Si semiconductor nanowires.
15. The method of claim 9 , wherein the semiconductor nanowires comprise the single crystal Ge semiconductor nanowires.
16. The method of claim 9 , wherein the semiconductor nanowires comprise the single crystal Si x Ge 1−x semiconductor nanowires.