High energy density redox flow device
Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.
1. An electrochemical cell comprising:
an anode;
a cathode; and
an ion-permeable membrane disposed between the anode and the cathode;
wherein at least one of the anode and the cathode includes a slurry electrode composition, the slurry electrode composition comprising solid ion storage compound particles in a liquid electrolyte, and
wherein the solid ion storage compound particles are capable of taking up or releasing ions and have a polydisperse size distribution and the particle packing fraction is at least 50 vol %.
2. The electrochemical cell of claim 1 , wherein the solid ion storage compound particles have a bidisperse size distribution in which the two maxima differ in size by at least a factor of 5.
3. The electrochemical cell of claim 1 , wherein the slum, electrode composition further comprises an electronically conductive material.
4. The electrochemical cell of claim 3 , wherein the slurry electrode composition comprises 0.5% to 10% by volume of the electronically conductive material.
5. The electrochemical cell of claim 3 , wherein the electronically conductive material forms a percolative conductive pathway.
6. The electrochemical cell of claim 3 , wherein the electronically conductive material comprises an electronically conductive polymer.
7. The electrochemical cell of claim 3 , wherein the electronically conductive material comprises a conductive inorganic compound selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.
8. The electrochemical cell of claim 1 , wherein the particle packing fraction is at least 70 vol %.
9. The electrochemical cell of claim 1 , wherein the ion storage compound particles have morphology that is at least equiaxed.
10. An electrochemical cell comprising:
a semi-solid electrode including solid ion storage compound particles in a liquid electrolyte, the solid ion storage compound particles capable of taking up or releasing ions during operation of the cell,
wherein the solid ion storage compound particles have a polydisperse size distribution and the particle packing fraction is at least 50 vol %.
11. The electrochemical cell of claim 10 , wherein the particle packing fraction is at least 70 vol %.
12. The electrochemical cell of claim 10 , wherein the solid ion storage compound particles have a bidisperse size distribution in which the two maxima differ in size by at least a factor of 5.
13. The electrochemical cell of claim 12 , wherein the particle size of the maxima for the larger particles is at least 1 micrometer.
14. The electrochemical cell of claim 10 , wherein the ion storage compound particles have morphology that is at least equiaxed.
15. The electrochemical cell of claim 10 , wherein the ion storage compound particles in the semi-solid electrode are at least 25% by mass.
16. The electrochemical cell of claim 10 , wherein the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.