Plastic reference material and method of manufacturing the same
The present invention relates to a plastic reference material and a method of manufacturing the same, wherein the concentration of at least one chemical substance is characterized from a signal intensity of the chemical substance and a signal intensity of the isotope-labeled chemical substance of the chemical substance obtained using the pyrolysis GC-MS instrument by weighing a mass of a candidate material for the plastic reference material using a balance, weighing an isotope-labeled chemical substance of the chemical substance using a balance, preparing a mixed solution by dissolving the weighed candidate material for the plastic reference material and the weighed isotope-labeled chemical substance in a solvent, introducing a product resulting from evaporation of the solvent from the mixed solution into a pyrolysis GC-MS instrument, and calculating the concentration of the chemical substance included in the candidate material for the plastic reference material.
1. A plastic reference material made by dispersing at least one chemical substance in a plastic base material and used for analyzing a concentration of the at least one chemical substance,
wherein the concentration of the at least one chemical substance is characterized by:
weighing a mass of a candidate material for the plastic reference material,
weighing an isotope-labeled chemical substance of the at least one chemical substance,
preparing a mixed solution by dissolving the weighed candidate material for the plastic reference material and the weighed isotope-labeled chemical substance in a solvent,
introducing a product resulting from evaporation of the solvent from the mixed solution into a pyrolysis gas chromatography-mass spectrometry (GC-MS) instrument, and
calculating the concentration of the at least one chemical substance included in the candidate material for the plastic reference material from a signal intensity of the at least one chemical substance and a signal intensity of the isotope-labeled chemical substance of the at least one chemical substance obtained using the pyrolysis GC-MS instrument.
2. A method of manufacturing a plastic reference material made by dispersing at least one chemical substance in a plastic base material and used for analyzing a concentration of the at least one chemical substance, the method comprising:
characterizing the concentration of the at least one chemical substance through calculation from a mass of a sample of a plastic reference material candidate measured using a balance, a mass of an isotope-labeled chemical substance of the at least one chemical substance measured using a balance, and a signal intensity measured using a pyrolysis GC-MS instrument.
3. The method of claim 2 , further comprising:
weighing a mass of the at least one chemical substance to be measured and a mass of the isotope-labeled chemical substance of the at least one chemical substance,
dissolving the at least one chemical substance, the isotope-labeled substance of the at least one chemical substance, and the plastic base material in a solvent,
introducing a product resulting from evaporation of the solvent into a pyrolysis GC-MS instrument,
determining a sensitivity correction factor of the at least one chemical substance to be measured and the isotope-labeled chemical substance of the at least one chemical substance, and
correcting the concentration of the at least one chemical substance.