Stabilized liquid ammonia fertilizer from animal waste
A liquid fertilizer is produced from off-gassed ammonia resulting from the processing of animal waste materials, particular animal manure. The vaporized ammonia is generated primarily by heating the animal waste materials and capturing the resulting vapors and particulate materials. The ammonia vapors and particles are removed from the gas stream through a scrubbing operation, which creates an ammonium-enriched liquid stream that can be concentrated into an organic fertilizer having a high-nitrogen content.
1. A method of processing manure comprising water and ammonia into a liquid fertilizer composition comprising the steps of:
(a) reducing the pH of the manure to generate ammonium from the ammonia;
(b) heating the manure to vaporize at least a portion of the water contained therein, generate fine carbonaceous particles having ammonium sorbed thereon, and disperse the fine carbonaceous particles in an air stream;
(c) contacting the air stream comprising the vaporized water and fine carbonaceous particles with a liquid water stream and dispersing the carbonaceous particles within the liquid water stream to form a nitrogen-rich liquid, wherein the air stream comprising the vaporized water and the fine carbonaceous particles processed in step (c) is unmodified from step (b); and
(d) removing water from the nitrogen-rich liquid to form the liquid fertilizer composition.
2. The method of claim 1 , wherein the method further comprises the step of removing at least a portion of the carbonaceous particles from the nitrogen-rich liquid.
3. The method of claim 2 , wherein the step of removing at least a portion of the carbonaceous particles from the nitrogen-rich liquid comprises one or more centrifugation or filtration steps.
4. The method of claim 3 , wherein the portion of the carbonaceous particles removed from the nitrogen-rich liquid are recombined with the manure.
5. The method of claim 2 , wherein the step of removing at least a portion of the carbonaceous particles comprises forming a liquid fertilizer composition that comprises less than 15,000 ppm of suspended solids.
6. The method of claim 1 , wherein the step of heating the manure comprises heating the manure to a temperature from about 100° F. to about 450° F.
7. The method of claim 1 , wherein the heating step is carried out using a rotating drum dryer.
8. The method of claim 1 , wherein the water vapor and carbonaceous particles from the heating step are conducted away from the manure and directed toward a scrubber in which the contacting step is performed.
9. The method of claim 8 , wherein the scrubber is a venturi scrubber.
10. The method of claim 1 , wherein the step of removing water from the nitrogen-rich liquid comprises concentrating the nitrogen-rich liquid to a total nitrogen concentration of about 4% to about 16% by weight.
11. The method of claim 1 , wherein the moisture content of the manure is decreased during the heating step from above 25% to below 10% by weight.
12. A method of processing manure comprising water and ammonia into a liquid fertilizer composition comprising the steps of:
(a) reducing the pH of the manure to generate ammonium from the ammonia;
(b) heating the manure to vaporize at least a portion of the water and ammonium contained therein;
(c) introducing fine carbonaceous particles into the vaporized water and ammonium and causing at least a portion of the ammonium to become sorbed thereon thereby forming a stream comprising the fine carbonaceous particles having ammonium sorbed thereon;
(d) contacting the stream comprising the fine carbonaceous particles having ammonium sorbed thereon with a liquid water stream and dispersing the carbonaceous particles within the liquid water stream to form a nitrogen-rich liquid, wherein the stream comprising the fine carbonaceous particles processed in step (d) is unmodified from step (c); and
(e) removing water from the nitrogen-rich liquid to form the liquid fertilizer composition.
13. The method of claim 12 , wherein the fine carbonaceous particles are selected from the group consisting of animal waste fines obtained from an animal waste to solid fertilizer manufacturing process, vegetable waste fines obtained from a vegetable processing process, mechanically disrupted seaweed, and citrus waste fines obtained from a citrus processing process.
14. The method of claim 12 , wherein the method further comprises the step of removing at least a portion of the fine carbonaceous particles from the nitrogen-rich liquid.
15. The method of claim 14 , wherein the portion of the fine carbonaceous particles removed from the nitrogen-rich liquid are recombined with the manure.
16. The method of claim 14 , wherein the step of removing at least a portion of the carbonaceous particles comprises forming the liquid fertilizer composition such that the liquid fertilizer composition comprises less than 15,000 ppm of suspended solids.
17. The method of claim 12 , wherein the step of heating the manure comprises heating the manure to a temperature from about 100° F. to about 450° F.
18. The method of claim 12 , wherein the heating step is carried out using a rotating drum dryer.
19. The method of claim 12 , wherein the step of removing water from the nitrogen-rich liquid comprises concentrating the nitrogen-rich liquid to a total nitrogen concentration of about 4% to about 16% by weight.
20. The method of claim 12 , wherein the moisture content of the manure is decreased during the heating step from above 25% to below 10% by weight.