IP Library Granted Patent US 12,403,421
Granted Patent B2
US 12,403,421 · App. 17/570,633 · Granted Sep 2, 2025

Methods for absorbing a targeted compound from a gas stream for subsequent processing or use

Inventors: Stephen R. Temple (Santa Cruz, CA); Bjorn Temple (Santa Cruz, CA)
B01D53/1418B01D53/002B01D53/1406B01D53/1456B01D53/1493B01D53/265C05C3/00C05G5/23
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,403,421
App. No.
17/570,633
Granted
Sep 2, 2025
Kind
B2
Abstract

The present invention describes methods for absorbing a targeted chemical compound from a gas stream into a scrubbing solution for various uses and with various benefits. Methods are described to produce a gas stream that can be further processed with operational benefits, such as through condensing and wastewater treatment with a lower load on the wastewater treatment system. Methods are described for adsorbing the targeted compound with reduced condensation of water from the gas stream. Methods are described for producing a liquid stream comprising an absorbed form of the targeted compound for use as a saleable product, such as adsorbing ammonia for the production of a fertilizer, wherein the concentration of the absorbed form may be increased through reduced condensation from the gas stream. Methods are described for producing a lower volume liquid waste stream from the absorption process through the use of reduced condensation of the gas stream.

Claims (22)

1. A method for removing a chemical compound from a waste gas stream to prepare the waste gas stream for further processing, comprising:

feeding a waste gas stream to a gas/liquid contactor, wherein the waste gas stream comprises a targeted chemical compound to be removed from the waste gas stream; and

absorbing the targeted chemical compound from the waste gas stream into a scrubbing solution in the gas/liquid contactor, thereby producing an exit gas stream from the gas/liquid contactor; wherein said absorbing is performed prior to any condensing of the waste gas stream;

condensing the exit gas stream from the gas/liquid contactor to produce a condensed gas stream for further processing;

after said condensing, optionally combining a second waste gas stream comprising the targeted chemical compound with the condensed gas stream;

removing a portion of solid matter from the condensed gas stream;

after said removing, scrubbing the condensed gas stream with an alkaline scrubbing solution to remove a portion of an acidic gaseous compound from the condensed gas stream;

after said scrubbing the condensed gas stream with the alkaline scrubbing solution, scrubbing the condensed gas stream with an acidic scrubbing solution to remove a portion of any of the targeted chemical compound in the condensed gas stream; and

after said scrubbing the condensed gas stream with an acidic scrubbing solution, discharging the condensed gas stream.

2. The method of claim 1 , wherein said condensing the exit gas stream produces a condensate stream and wherein said absorbing the targeted chemical compound from the waste gas stream in the gas/liquid contactor provides a corresponding reduced concentration of the targeted chemical compound in the condensate stream and further comprising:

treating the condensate stream to remove the targeted chemical compound in the condensate stream.

3. The method of claim 2 , wherein said treating the condensate stream provides a condensate stream having a lower biological oxygen demand compared to the condensate stream prior to said treating and is performed upstream of a wastewater treatment facility.

4. The method of claim 1 , wherein said waste gas stream is produced in an animal byproduct process.

5. The method of claim 1 , wherein said waste gas stream is produced in an animal waste process.

6. The method of claim 5 , wherein said animal waste process comprises a rendering process.

7. The method of claim 6 , wherein said waste gas stream is produced by a piece of equipment consisting of a cooker, dryer, evaporator, concentrator, or a combination thereof.

8. The method of claim 1 , wherein the targeted chemical compound comprises ammonia.

9. The method of claim 1 , wherein said absorbing the targeted chemical compound from the waste gas stream into the scrubbing solution produces an absorbed form of the targeted chemical compound in the scrubbing solution, and further comprising:

removing a portion of the scrubbing solution comprising the absorbed form of the targeted chemical compound as a product stream.

10. The method of claim 9 , wherein the targeted chemical compound comprises a nitrogen-based compound, the scrubbing solution comprises an acid, and said absorbing the targeted chemical compound from the waste gas stream into the scrubbing solution produces an absorbed form of the targeted chemical compound in the scrubbing solution comprising a conjugate base form of the nitrogen-based compound corresponding to the acid.

11. The method of claim 10 , wherein the nitrogen-based compound is ammonia and the product stream comprises a fertilizer.

12. The method of claim 11 , wherein the acid comprises a non-synthetic acid and the product stream comprises a fertilizer suitable for organic agriculture.

Continuity (2)
Continuation 17566961 · Dec 31, 2021
Related Publication 20230211280A1 · Jul 6, 2023
References Cited (43)
US 3320906A · Domahidy · 1967 [cited by examiner]
US 4058375A · Lawrence · 1977 [cited by applicant]
US 4689156A · Zibrida · 1987 [cited by examiner]
US 7160358B2 · Spink · 2007 [cited by applicant]
US 7258848B1 · Blackwell · 2007 [cited by applicant]
US 8961915B1 · Zhao · 2015 [cited by applicant]
US 9808758B2 · Zhao · 2017 [cited by applicant]
US 10343115B2 · Temple · 2019 [cited by applicant]
US 10434468B2 · Carlessi et al. · 2019 [cited by applicant]
US 11389763B2 · Temple et al. · 2022 [cited by applicant]
US 11458436B2 · Temple · 2022 [cited by applicant]
US 11667588B2 · Hazen · 2023 [cited by applicant]
US 20090282977A1 · Koss · 2009 [cited by examiner]
US 20120174431A1 · Cash · 2012 [cited by applicant]
US 20130186272A1 · Balfe · 2013 [cited by examiner]
US 20140202206A1 · Temple · 2014 [cited by examiner]
US 20170136386A1 · Temple · 2017 [cited by examiner]
US 20190321781A1 · Temple · 2019 [cited by applicant]
US 20200188840A1 · Novek · 2020 [cited by examiner]
US 20210121820A1 · Temple et al. · 2021 [cited by applicant]
US 20240342651A1 · Temple et al. · 2024 [cited by applicant]
CN 101844977 · 2010 [cited by applicant]
CN 103539569 · 2014 [cited by applicant]
CN 108085013 · 2018 [cited by applicant]
CN 108424318 · 2018 [cited by applicant]
WO WO9102582A1 · 1991 [cited by applicant]
WO WO2008030235A2 · 2008 [cited by examiner]
WO WO2009028948 · 2009 [cited by applicant]
WO WO2017068038 · 2017 [cited by applicant]
WO WO2018208163A1 · 2018 [cited by examiner]
U.S. Appl. No. 17/939,490, Temple et al. [cited by applicant]
Jayathilakan et al., Utilization of Byproduct and Waste Materials form Meat, Poultry and Fish Processing Industries: A Review, J. Food Sci. Technol, May-Jun. 2012, 49(3):278-293. [cited by applicant]
Eggeman, et al., Recovery of Organic Acids from Fermentation Broths, Applied Biochemistry and Biotechnology, vol. 121-124, 2005, 605-618. [cited by applicant]
Cai et al., Tracking human sewage microbiome in a municipal wastewater treatment plant, Environmental Biotechnology, Appl. Microbial Biotechnol, pp. 3317-3326, 2014. [cited by applicant]
Ristic et al., (Waste Gases Arising in Rendering Plants for Harmless Removal of Animal By-Products by Technological Processing, Annals ofThe Faculty of Engineering Hunedoara, Tome III, Fascicole 3, pp. 105-112, 2005. [cited by applicant]
Komesu et al. (Evaluation of lactic acid purification from fermentation broth by hybrid short path evaporation using factorial experimental design, Separation and Purification Technology, 136, pp. 233-240, 2014. [cited by applicant]
Whirlston, How to Process Chicken Manure into Organic Fertilizer, MC Modern Ghana, 6 pages, 2017. [cited by applicant]
Canete-Rodriguez et al., Gluconic acid: Properties, Production methods and Applications—An excellent opportunity for agro-industrial by-products and waste bio-valorization, Process Biochemistry, 51, pp. 1891-1903, 2016. [cited by applicant]
Klavins et al., Properties and Structure of Raised Bog Peat Humic Acids, Journal of Molecular Structure, 1050, pp. 103-113, 2013. [cited by applicant]
Grossman, As Dairy Farms Grow Bigger, New Concerns About Pollution, Yale Environment, pp. 1-6, 2014. [cited by applicant]
Melse, et al. “Air Scrubbing Techniques for Ammonia and Odor Reduction at Livestock Operations: Review of On-Farm Research in the Netherlands,” American Society of Agricultural Engineers, vol. 48(6), pp. 2303-2313, 2005. [cited by applicant]
Liao, P.H. et al., Removal of Nitrogen From Swine Manure Wastewaters by Ammonia Stripping, Bioresource Technology, 1995, 17-20, 54, Elsevier Science Limited, Great Britian. [cited by applicant]
Temple et al., Methods for Absorbing a Targeted Compound from a Gas Stream for Subsequent Processing or Use, U.S. Appl. No. 18/762,597, filed Jul. 2, 2024 (copending application). [cited by applicant]