Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
The present invention provides an electrophotographic photosensitive member sequentially including: a support; a photosensitive layer; and a protection layer formed on the support, wherein the protection layer has a triarylamine structure and a specific cyclic structure, and a specific A-value obtained by measurement using total reflection Fourier transform infrared spectroscopy is 0.010 or more and 0.050 or less.
1. An electrophotographic photosensitive member sequentially comprising:
a support, a photosensitive layer and a protection layer;
the protection layer being a cured film of a composition containing a first monomer and a second monomer;
the first monomer being selected from the group consisting of OCL-1 and OCL-2
and
the second monomer being selected from the group consisting of L-1, L-2, L-3, L-4, L-5, L-6, L-7 and L-8
wherein A is 0.010 to 0.050 where A=S1/S2, S1 is a peak area based on in-plane deformation vibration of a terminal olefin derived from an acrylic group among peak areas of spectrum obtained by measuring a surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°, and S2 is a peak area based on C═O stretching vibration among peak areas of spectrum obtained by measuring said surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°.
2. The electrophotographic photosensitive member according to claim 1 , wherein an elastic deformation ratio of the protection layer is 45 to 55%.
3. The electrophotographic photosensitive member according to claim 1 , wherein a molar ratio of a cyclic structure contained in the second monomer to a triarylamine structure contained in the first monomer is 0.2 to 1.4.
4. The electrophotographic photosensitive member according to claim 1 , wherein the protection layer further contains a triarylamine compound having a molecular weight of 300 to 1,000.
5. The electrophotographic photosensitive member according to claim 4 , wherein the triarylamine compound is present in a range of 1 to 30 mass % with respect to the total mass of the protection layer.
6. The electrophotographic photosensitive member according to claim 1 , wherein the protection layer further has a siloxane structure or a fluoro group.
7. A process cartridge detachably attachable to an electrophotographic apparatus main body, comprising:
an electrophotographic photosensitive member and at least one unit selected from the group consisting of a charging unit, a developing unit, a transfer unit and a cleaning unit;
the electrophotographic photosensitive member and the at least one unit being integrally supported;
the electrophotographic photosensitive member sequentially includes a support, a photosensitive layer and a protection layer;
the protection layer being a cured film of a composition containing a first monomer and a second monomer;
the first monomer being selected from the group consisting of OCL-1 and OCL-2
and
the second monomer being selected from the group consisting of L-1, L-2, L-3, L-4, L-5, L-6, L-7 and L-8
wherein A is 0.010 to 0.050 where A=S1/S2, S1 is a peak area based on in-plane deformation vibration of a terminal olefin derived from an acrylic group among peak areas of spectrum obtained by measuring a surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°, and S2 is a peak area based on C═O stretching vibration among peak areas of spectrum obtained by measuring said surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°.
8. The process cartridge according to claim 7 , wherein the cleaning unit is a cleaning blade, and the cleaning blade is made of a urethane resin.
9. An electrophotographic apparatus comprising:
an electrophotographic photosensitive member, a charging unit, an exposing unit, a developing unit and a transfer unit;
the electrophotographic photosensitive member sequentially includes a support, a photosensitive layer, and a protection layer;
the protection layer being a cured film of a composition containing a first monomer and a second monomer, wherein
the first monomer is selected from the group consisting of OCL-1 and OCL-2
the second monomer is selected from the group consisting of L-1, L-2, L-3, L-4, L-5, L-6, L-7 and L-8
and A is 0.010 to 0.050 where A=S1/S2, S1 is a peak area based on in-plane deformation vibration of a terminal olefin derived from an acrylic group among peak areas of spectrum obtained by measuring a surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°, and S2 is a peak area based on C═O stretching vibration among peak areas of spectrum obtained by measuring said surface of said protection layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and a measurement condition of an incident angle of 45°.