IP Library Granted Patent US 11,370,964
Granted Patent B2
US 11,370,964 · App. 16/311,254 · Granted Jun 28, 2022

Polymer composite for encapsulating quantum dots

Inventors: Jaebum Joo (Somerville, MA); James C. Taylor (Grafton, MA); Tanya Singh-Rachford (South Grafton, MA)
Assignee: ROHM AND HAAS ELECTRONIC MATERIALS LLC
C09K11/02C08L33/066C08L35/02C08L2203/16C08L2203/20
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Quick Facts
Patent No.
US 11,370,964
App. No.
16/311,254
Granted
Jun 28, 2022
Kind
B2
Abstract

A polymer composite comprising: (a) quantum dots; (b) polymerized units of a compound of formula (I) wherein R1 is hydrogen or methyl and R2 is a C6-C20 aliphatic polycyclic substituent; and (c) a light stabilizer compound comprising two 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents.

Claims (13)

1. A polymer composite comprising:

(a) 0.01 to 5% by weight of quantum dots;

(b) 50 to 88% by weight of polymerized units of a compound of formula (I)

wherein R 1 is hydrogen or methyl and R 2 is a C6-C20 aliphatic polycyclic substituent; and

(c) 0.5 to 5% by weight of a light stabilizer compound comprising two 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents; wherein R 2 is a bridged polycyclic substituent.

2. The polymer composite of claim 1 in which R 2 is a C7-C17 bridged polycyclic substituent.

3. The polymer composite of claim 2 in which the light stabilizer compound comprises a linker connecting the substituents, said linker having from 4 to 20 carbon atoms.

4. The polymer composite of claim 3 in which an alkyl group in each of the 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents has from 4 to 12 carbon atoms.

5. The polymer composite of claim 4 wherein R 2 is selected from the group consisting of adamantanes, bicyclo[2,2,1]alkanes, bicyclo[2,2,2]alkanes, bicyclo[2,1,1]alkanes and tricyclodecanes which may be substituted with (meth)acrylate esters such that the polymer composite comprises polymerized units of a compound of formula (I) having one (meth)acrylate ester substituent and a compound of formula (I) having two (meth)acrylate ester substituents in a weight ratio from 100:1 to 1:5, respectively.

6. The polymer composite of claim 5 in which R 2 has a bicyclo[2,2,1]alkane or tricyclodecane ring system.

7. The polymer composite of claim 6 in which the quantum dots comprise CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, HgS, HgSe, HgTe, GaN, GaP, GaAs, InP, InAs or a combination thereof.

8. The polymer composite of claim 5 further comprising a scattering agent.

9. The polymer composite of claim 5 which is a film.

Assignments (3)
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 073515/0243 →
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 073517/0298 →
CHANGE OF NAME Recorded Oct 29, 2024
From: ROHM & HAAS ELECTRONIC MATERIALS LLC
To: DUPONT ELECTRONIC MATERIALS INTERNATIONAL, LLC
Reel/Frame 069272/0383 →
Continuity (2)
Provisional Application 62359986 · Jul 8, 2016
Related Publication 20190322925A1 · Oct 24, 2019