Polymer composite for encapsulating quantum dots
A polymer composite comprising: (a) quantum dots; (b) polymerized units of a compound of formula (I) wherein R1 is hydrogen or methyl and R2 is a C6-C20 aliphatic polycyclic substituent; and (c) a light stabilizer compound comprising two 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents.
1. A polymer composite comprising:
(a) 0.01 to 5% by weight of quantum dots;
(b) 50 to 88% by weight of polymerized units of a compound of formula (I)
wherein R 1 is hydrogen or methyl and R 2 is a C6-C20 aliphatic polycyclic substituent; and
(c) 0.5 to 5% by weight of a light stabilizer compound comprising two 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents; wherein R 2 is a bridged polycyclic substituent.
2. The polymer composite of claim 1 in which R 2 is a C7-C17 bridged polycyclic substituent.
3. The polymer composite of claim 2 in which the light stabilizer compound comprises a linker connecting the substituents, said linker having from 4 to 20 carbon atoms.
4. The polymer composite of claim 3 in which an alkyl group in each of the 1-alkyloxy-2,2,6,6-tetramethyl-4-piperidinyl substituents has from 4 to 12 carbon atoms.
5. The polymer composite of claim 4 wherein R 2 is selected from the group consisting of adamantanes, bicyclo[2,2,1]alkanes, bicyclo[2,2,2]alkanes, bicyclo[2,1,1]alkanes and tricyclodecanes which may be substituted with (meth)acrylate esters such that the polymer composite comprises polymerized units of a compound of formula (I) having one (meth)acrylate ester substituent and a compound of formula (I) having two (meth)acrylate ester substituents in a weight ratio from 100:1 to 1:5, respectively.
6. The polymer composite of claim 5 in which R 2 has a bicyclo[2,2,1]alkane or tricyclodecane ring system.
7. The polymer composite of claim 6 in which the quantum dots comprise CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, HgS, HgSe, HgTe, GaN, GaP, GaAs, InP, InAs or a combination thereof.
8. The polymer composite of claim 5 further comprising a scattering agent.
9. The polymer composite of claim 5 which is a film.