Lithium secondary battery pack including thermal expansion tape fixing pouch type battery cells and method of manufacturing same
The present invention relates to a safety-improved battery cell including a thermal expansion tape and a method of manufacturing the same, wherein a battery pack including multiple battery cells is configured such that heat generated during a charging/discharging process and internal gas generated thereby are discharged to outside of a battery cell by employing a thermal expansion tape. Thus, the present invention can improve safety of a pouch-type secondary battery pack by discharging gas generated in a pouch-type secondary battery. In addition, the present invention utilizes pressure of gas generated in the secondary battery and thus can be operable without provision of a separate device and an external power source. Moreover, the present invention can perform repetitive gas discharge due to a configuration of a fixing unit having thermal expansion properties.
1. A method of manufacturing a lithium secondary battery pack, the method comprising:
forming multiple pouch-type battery cells each configured such that an electrode assembly and an electrolyte are sealed in a pouch and a positive electrode tab and a negative electrode tab protrude outside the pouch through a side of the pouch;
stacking the multiple pouch-type battery cells;
fixing the multiple pouch-type battery cells using a fixing unit to form multiple unit modules the fixing unit having a composite structure including a thermal expansion polymer and expansion graphite, the fixing unit having one or more of a tape shape, a band shape, a tube shape, or a box shape, the expansion graphite being formed in a specific region of the fixing unit in a strip shape; and
arranging the multiple unit modules in a module casing,
wherein the fixing unit is configured to discharge gas in the pouch-type battery cells when a temperature of the battery cells rises.
2. The method of claim 1 , wherein the fixing unit has thermal expansion properties.
3. The method of claim 1 , wherein the thermal expansion polymer is composed of any one selected from the group consisting of PE, PP, PS, PVC, acrylic, and a butyl resin.
4. The method of claim 1 , wherein the fixing unit is configured to discharge the gas in the pouch-type battery cell when the temperature of the battery cells is equal to or greater than 80° C.
5. The method of claim 1 , wherein an expansion pressure of the fixing unit is 0.2 to 1.5 N/mm 2 .
6. The method of claim 1 , wherein a protection circuit or a PTC circuit is formed on a surface of each unit module.
7. A device including the lithium secondary battery pack that is manufactured by the method of claim 1 .
8. The device of claim 7 , wherein the device is selected from the group consisting of an electronic device, an electric vehicle, a hybrid vehicle, and a power storage device.
9. A lithium secondary battery pack, comprising:
multiple pouch-type battery cells each including an electrode assembly and an electrolyte sealed in a pouch and a positive electrode tab and a negative electrode tab each protruding outside the pouch through a side of the pouch;
multiple unit modules each formed by stacking the multiple pouch-type battery cells and fixing the multiple pouch-type battery cells using a fixing unit, the fixing unit having a composite structure including a thermal expansion polymer and expansion graphite, the fixing unit having one or more of a tape shape, a band shape, a tube shape, or a box shape, the expansion graphite being formed in a specific region of the fixing unit in a strip shape; and
a module casing having the multiple unit modules arranged therein,
wherein the fixing unit is configured to discharge gas in the pouch-type battery cells when a temperature of the battery cells rises.
10. The lithium secondary battery pack of claim 9 , wherein the fixing unit has thermal expansion properties.
11. The lithium secondary battery pack of claim 10 , wherein the fixing unit is a band-shaped tape.