Aqueous adhesive compositions
A latex emulsion that includes an aqueous carrier liquid and a latex copolymer formed from reactants comprising butyl methacrylate, wherein the reactants comprise at least 20 wt. % a vinyl monomer, based on the total weight of ethylenically unsaturated monomers in the latex copolymer. A homopolymer formed from the vinyl monomer preferably exhibits a glass transition temperature of between about −10° C. and about 30° C. A coating formed from the latex emulsion preferably exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate. The latex emulsion may include a second latex copolymer or stage, and may be used as part of an aqueous adhesive composition.
1. A composition comprising:
an aqueous carrier liquid;
a latex copolymer formed from reactants comprising a chain transfer agent and a vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, wherein the reactants comprise at least 20 wt. % of the vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer, and wherein a homopolymer formed from the vinyl monomer exhibits a glass transition temperature of between about −10° C. and about 30° C., and wherein the latex copolymer exhibits a glass transition temperature of less than about −15° C.; and
wherein the latex copolymer exhibits a gel fraction of between 0% and about 5% and a solubilized portion of the latex copolymer exhibits a weight average molecular weight of less than about 230,000 g/mol,
wherein a coating formed from the aqueous adhesive composition exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate.
2. The composition of claim 1 , wherein the vinyl monomer comprises butyl methacrylate, ethylhexyl methacrylate, a vinyl ester of neodecanoic acid, or combinations thereof.
3. The composition of claim 1 , wherein the latex copolymer is a first latex copolymer or stage, further comprising a second latex copolymer or stage formed from second reactants comprising a (meth)acrylate monomer other than butyl methacrylate.
4. The composition of claim 3 , wherein the first latex copolymer or stage is formed as an initial stage of a multi-stage latex and the second latex copolymer or stage is formed as a subsequent stage of the multi-stage latex.
5. The composition of claim 3 , wherein the second latex copolymer or stage is formed as an initial stage of a multi-stage latex and the first latex copolymer or stage is formed as a subsequent stage of the multi-stage latex.
6. The composition of claim 3 , wherein the first latex copolymer or stage and the second latex copolymer or stage are separate polymers mechanically mixed in the latex emulsion.
7. The composition of claim 3 , wherein the first latex copolymer is chemically different from the second latex copolymer.
8. The composition of claim 1 , further comprising a dispersant, a biocide, a fungicide, an UV stabilizer, a thickener, a wetting agent, a defoamer, a filler, a pigment or colorizer, a tackifier, or combinations thereof.
9. The composition of claim 1 , wherein the reactants comprise between 20 and 50 wt. % of the vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer or the first latex copolymer or stage.
10. The composition of claim 1 , wherein the vinyl monomer comprises n-butyl methacrylate or a mixture of n-butyl methacrylate and ethylhexyl methacrylate.
11. The composition of claim 1 , wherein the reactants or the first reactants further comprise:
an ethylenically unsaturated polar monomer.
12. The composition of claim 11 , wherein the chain transfer agent comprises dodecyl mercaptan.
13. The composition of claim 1 , wherein the reactants further comprise a second (meth)acrylate, wherein the second (meth)acrylate forms a homopolymer that has a glass transition temperature that is less than −25° C.
14. The composition of claim 1 , wherein the reactants further comprise a ureido-functional monomer.
15. The composition of claim 1 , wherein a coating formed from the latex emulsion or the aqueous adhesive composition exhibits a dry adhesion of greater than about 8 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate and subjected to 180° peel testing.
16. The composition of claim 1 , wherein the latex copolymer exhibits a glass transition temperature of less than about −20° C.
17. A roofing material comprising:
a polymeric roofing membrane; and
an adhesive on a surface of the polymeric roofing membrane, wherein the adhesive comprises:
an aqueous carrier liquid;
a latex copolymer formed from reactants comprising a chain transfer agent and a vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, wherein the reactants comprise at least 20 wt. % of the vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer, and wherein a homopolymer formed from the vinyl monomer exhibits a glass transition temperature of between about −10° C. and about 30° C., and wherein the latex copolymer exhibits a glass transition temperature of less than about −15° C.; and
wherein the latex copolymer exhibits a gel fraction of between 0% and about 5% and a solubilized portion of the latex copolymer exhibits a weight average molecular weight of less than about 230,000 g/mol,
wherein a coating formed from the aqueous adhesive composition exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate; and
a backing membrane removably on the adhesive.
18. The roofing material of claim 17 , wherein the polymeric roofing membrane comprises thermoplastic polyolefin (TPO) membrane, ethylene propylene diene monomer (EPDM) rubber membrane, or poly(vinyl chloride) membrane.
19. A method comprising:
reacting reactants comprising a chain transfer agent and a vinyl monomer having an alkyl group including between 2 and 20 carbon atoms to form a latex emulsion including a latex copolymer, wherein the reactants comprise at least 20 wt. % of the vinyl monomer having an alkyl group including between 2 and 20 carbon atoms, based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer, wherein a homopolymer formed from the vinyl monomer exhibits a glass transition temperature of between about −10° C. and about 30° C., wherein the latex copolymer exhibits a glass transition temperature of less than about −15° C., wherein the latex copolymer exhibits a gel fraction of between 0% and about 5% and a solubilized portion of the latex copolymer exhibits a weight average molecular weight of less than about 230,000 g/mol, and wherein a coating formed from the latex emulsion exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate.
20. The method of claim 19 , wherein the reactants comprise first reactants, further comprising:
reacting second reactants comprising a (meth)acrylate monomer other than the vinyl monomer having an alkyl group including between 2 and 20 carbon atoms to form a second latex copolymer or stage.