Aqueous adhesive compositions
A latex emulsion that includes an aqueous carrier liquid and a latex copolymer formed from reactants comprising butyl methacrylate, wherein the reactants comprise at least 20 wt. % a vinyl monomer, based on the total weight of ethylenically unsaturated monomers in the latex copolymer. A homopolymer formed from the vinyl monomer preferably exhibits a glass transition temperature of between about −10° C. and about 30° C. A coating formed from the latex emulsion preferably exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate. The latex emulsion may include a second latex copolymer or stage, and may be used as part of an aqueous adhesive composition.
1. A latex emulsion adhesive composition for application to polymeric roofing membranes, the latex emulsion adhesive composition comprising:
an aqueous carrier liquid;
a first latex copolymer or stage formed from reactants comprising a vinyl monomer comprising butyl methacrylate, wherein the reactants comprise about 25 to about 50 weight percent of butyl methacrylate, based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer, and wherein a homopolymer formed from the vinyl monomer exhibits a glass transition temperature of between about −10° C. and about 30° C.;
wherein the first latex copolymer or stage exhibits a glass transition temperature of less than −15° C.;
a second latex copolymer or stage formed from second reactants comprising a (meth)acrylate monomer that does not include butyl methacrylate;
wherein the first latex copolymer or stage is chemically different from the second latex copolymer or stage;
wherein the first latex copolymer or stage and the second latex copolymer or stage are present in the composition in a weight ratio of about 4:1 to about 1:4; and
wherein a coating formed from the aqueous adhesive composition exhibits a dry adhesion of greater than about 4 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate at an average coat weight of about 6 lbs/100 ft 2 and subjected to 180° peel testing according to ASTM D903 with a 2-inch per minute pull rate.
2. The composition of claim 1 , wherein the first latex copolymer or stage is formed as an initial stage of a multi-stage latex and the second latex copolymer or stage is formed as a subsequent stage of the multi-stage latex.
3. The composition of claim 1 , wherein the second latex copolymer or stage is formed as an initial stage of a multi-stage latex and the first latex copolymer or stage is formed as a subsequent stage of the multi-stage latex.
4. The composition of claim 1 , wherein the first latex copolymer or stage and the second latex copolymer or stage are separate polymers mechanically mixed in the latex emulsion.
5. The composition of claim 1 , further comprising a dispersant, a biocide, a fungicide, an UV stabilizer, a thickener, a wetting agent, a defoamer, a filler, a pigment or colorizer, a tackifier, or combinations thereof.
6. The composition of claim 1 , wherein the reactants comprise between 20 and 50 wt. % of the vinyl monomer comprising butyl methacrylate, ethylhexyl methacrylate, a vinyl ester of neodecanoic acid, or combinations thereof based on the total weight of ethylenically unsaturated monomers used to make the latex copolymer or the first latex copolymer or stage.
7. The composition of claim 1 , wherein the vinyl monomer comprises n-butyl methacrylate or a mixture of n-butyl methacrylate and ethylhexyl methacrylate.
8. The composition of claim 1 , wherein the reactants or the first reactants further comprise:
an ethylenically unsaturated polar monomer; and
a chain transfer agent.
9. The composition of claim 8 , wherein the chain transfer agent comprises dodecyl mercaptan.
10. The composition of claim 1 , wherein the reactants further comprise a second (meth)acrylate, wherein the second (meth)acrylate forms a homopolymer that has a glass transition temperature that is less than −25° C.
11. The composition of claim 1 , wherein the reactants further comprise a ureido-functional monomer.
12. The composition of claim 1 , wherein a coating formed from the latex emulsion or the aqueous adhesive composition exhibits a dry adhesion of greater than about 8 pounds per linear inch when applied between a thermoplastic polyolefin roofing membrane and a plywood roofing substrate and subjected to 180° peel testing.
13. The composition of claim 1 , wherein the latex copolymer exhibits a gel fraction of between 0% and about 5%, and wherein the solubilized portion of the latex copolymer exhibits a weight average molecular weight of less than about 230,000 g/mol.