System, device, and method for producing ion concentration gradient, and temperature-responsive electrolyte material
A system for producing an ion concentration gradient and a temperature-responsive electrolyte material which are utilizable, for example, for efficiently converting heat energy that has been discarded into reusable energy or for efficiently recovering an acid gas, such as carbon dioxide is provided. A temperature-responsive electrolyte is used to produce an ion concentration gradient by means of a temperature gradient. The temperature-responsive electrolyte is used in the state of an aqueous solution and also in the state of a solid phase.
1. A temperature-responsive electrolyte material for absorbing carbon dioxide, which is an aqueous solution of fine hydrogel particles obtained by copolymerizing
a monomer ingredient having an ionizable basic group,
a crosslinkable monomer ingredient, and
(i) a monomer ingredient having a polar group and a monomer ingredient having a hydrophobic group, or (ii) a monomer ingredient having a polar group and a hydrophobic group, wherein in said (i) a monomer ingredient having a polar group and a monomer ingredient having a hydrophobic group, or said (ii) a monomer ingredient having a polar group and a hydrophobic group, hydrophobicity of the hydrophobic group is higher than hydrophobicity of hydrophobic group of N-isopropylacrylamide.
2. The temperature-responsive electrolyte material for absorbing carbon dioxide according to claim 1 , wherein the monomer ingredient having hydrophobic group or the monomer ingredient having a polar group and a hydrophobic group is N-t-butylacrylamide.
3. The temperature-responsive electrolyte material for absorbing carbon dioxide according to claim 1 , wherein the aqueous solution of fine hydrogel particles is obtained by copolymerizing
the monomer ingredient having an ionizable basic group,
the crosslinkable monomer ingredient, and
(i) the monomer ingredient having a polar group and the monomer ingredient having a hydrophobic group, wherein in said (i) the monomer ingredient having a polar group and the monomer ingredient having a hydrophobic group, hydrophobicity of the hydrophobic group is higher than hydrophobicity of hydrophobic group of N-isopropylacrylamide.
4. The temperature-responsive electrolyte material for absorbing carbon dioxide according to claim 1 , wherein the aqueous solution of fine hydrogel particles is obtained by copolymerizing
the monomer ingredient having an ionizable basic group,
the crosslinkable monomer ingredient, and
(ii) the monomer ingredient having a polar group and a hydrophobic group, wherein in said (ii) the monomer ingredient having a polar group and a hydrophobic group, hydrophobicity of the hydrophobic group is higher than hydrophobicity of hydrophobic group of N-isopropylacrylamide.
5. The temperature-responsive electrolyte material for absorbing carbon dioxide according to claim 3 , wherein the monomer ingredient having a hydrophobic group is N-t-butylacrylamide.
6. The temperature-responsive electrolyte material for absorbing carbon dioxide according to claim 4 , wherein the monomer ingredient having a polar group and a hydrophobic group is N-t-butylacrylamide.