IP Library Granted Patent US 10,519,603
Granted Patent B2
US 10,519,603 · App. 16/422,166 · Granted Dec 31, 2019

Coating composition and coated paper and coated paperboard

Inventors: Anthony Lyons (Macon, GA); Chinmay Peshave (Milledgeville, GA)
Assignee: Imerys USA, Inc.
D21H19/64C09C1/021C09D1/00C09D7/43C09D7/61C09D101/286C09D101/32C09D103/02C09D131/04C09D133/00C09D133/08D21H19/385D21H19/40D21H19/54D21H19/58D21H19/60D21H21/50D21H21/52C08K3/26C08K3/346C08K5/098C08K2003/265Y10T428/258
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Quick Facts
Patent No.
US 10,519,603
App. No.
16/422,166
Granted
Dec 31, 2019
Kind
B2
Abstract

A coating composition may include kaolin having a shape factor less than about 70 and calcium carbonate, wherein less than about 90% by weight and greater than about 60% by weight of particles of the calcium carbonate have an equivalent spherical diameter (esd) less than 2 microns. The coating composition may include a thickener present in an amount ranging from about 0.1% to about 0.9% by active dry weight of the composition. A coating composition may include kaolin having a shape factor less than about 70 and calcium carbonate having a mean particle size (d50) of at least about 2.4 microns and a steepness factor of at least about 30. The coating composition may be a paper basecoat composition or a paperboard basecoat composition. A paper or paperboard product may include the coating composition on at least one surface of the paper product or paperboard product.

Claims (23)

1. A coating composition comprising:

kaolin having a shape factor less than about 70; and

calcium carbonate having a d 50 of at least about 2.4 microns, wherein less than 70% by weight and greater than 60% by weight of particles of the calcium carbonate have an equivalent spherical diameter less than 2 microns.

2. The coating composition of claim 1 , further comprising a thickener.

3. The coating composition of claim 2 , wherein the thickener is present in an amount ranging from about 0.1% to about 0.9% by active dry weight of the coating composition.

4. The coating composition of claim 2 , wherein the thickener is selected from the group consisting of alkali-soluble emulsion polyacrylate thickeners, hydrophobically-modified alkali-soluble emulsion polyacrylate thickeners, and carboxymethyl cellulose thickeners.

5. The coating composition of claim 1 , wherein less than about 30% by weight of the kaolin has an equivalent spherical diameter less than about 0.25 microns.

6. The coating composition of claim 1 , wherein the calcium carbonate has a d 50 of at least about 2.6 microns.

7. The coating composition of claim 1 , wherein the calcium carbonate has a steepness factor greater than 32.

8. The coating composition of claim 1 , further comprising a binder, wherein the binder comprises at least one of an adhesive binder, a starch binder, a synthetic binder, a polyvinyl acetate-based binder, or an acrylic binder.

9. The coating composition of claim 8 , wherein the binder forms from 4% to 30% by weight of a solids content of the coating composition.

10. A paperboard product comprising the coating composition of claim 1 on at least one surface of the paperboard product, wherein the paperboard product has a total weight per unit area ranging from 30 g/m 2 to 70 g/m 2 .

11. A method of reducing the cracking and/or flaking of a coated paperboard product at a fold, the method comprising:

i) providing a coating composition on a paperboard product, wherein the coating composition comprises a mixture of a binder, kaolin having a shape factor greater than 50 and less than 70; and

calcium carbonate, wherein less than 70% by weight and greater than about 60% by weight of the particles of the calcium carbonate have an equivalent spherical diameter less than 2 microns; and

ii) folding the paperboard product to form a fold, wherein the paperboard product has a higher modulus and a higher stiffness as compared to a second modulus and a second stiffness of a paperboard product coated with a coating composition devoid of the kaolin and the calcium carbonate.

12. The method of claim 11 , wherein the coating composition further comprises a thickener in an amount ranging from about 0.1% to about 0.9% by active dry weight of the coating composition.

13. The method of claim 12 , wherein the thickener is selected from the group consisting of alkali-soluble emulsion polyacrylate thickeners, hydrophobically-modified alkali-soluble emulsion polyacrylate thickeners, and carboxymethyl cellulose thickeners.

14. The method of claim 11 , wherein less than 30% by weight of the kaolin has an equivalent spherical diameter less than about 0.25 microns.

15. The method of claim 11 , wherein less than 80% by weight of the kaolin has an equivalent spherical diameter less than about 1 microns.

16. The method of claim 11 , wherein less than 70% by weight and greater than 60% by weight of the particles of the calcium carbonate have an equivalent spherical diameter less than 2 microns.

17. The method of claim 11 , wherein the binder comprises at least one of an adhesive binder, a starch binder, a synthetic binder, a polyvinyl acetate-based binder, or an acrylic binder.

18. The method of claim 11 , wherein the binder forms from 4% to 30% by weight of a solids content of the coating composition.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 28, 2019
From: LYONS, ANTHONY; PESHAVE, CHINMAY
To: IMERYS PIGMENTS, INC.
Reel/Frame 049288/0903 →
MERGER Recorded May 28, 2019
From: IMERYS PIGMENTS, INC.
To: IMERYS USA, INC.
Reel/Frame 049288/0929 →
Continuity (5)
Continuation 15334038 · Oct 25, 2016
Division 14370285
Provisional Application 61787222 · Mar 15, 2013
Provisional Application 61715628 · Oct 18, 2012
Related Publication 20190284763A1 · Sep 19, 2019