All-solid secondary battery
A solid electrolyte according to an embodiment includes a lithium-containing phosphoric acid compound with a cubic crystal structure.
1. A solid electrolyte comprising:
a lithium and phosphorus-containing compound having mainly a cubic crystal structure and in the form of monocrystalline particles,
wherein the lithium and phosphorus-containing compound is represented as:
Li x M1 y M2 z M3 w P 3-w O 12 (1),
Formula (1) satisfies 0<x≤3, 0≤y<2, 0<z≤2, and 0≤w<3,
M1 represents at least one selected from the group consisting of Mg, Ca, Sr, Ba, V, Nb, Mn, Co, Ni, Cu, Ag, Ga, Al, In, Sc, and Y,
M2 represents at least one selected from the group consisting of Zr and Hf, and
M3 represents at least one selected from the group consisting of Si, B, S, V, Mo, and W.
2. The solid electrolyte according to claim 1 , further comprising:
equal to or greater than 0.01% by mass and equal to or less than 20% by mass of bound water.
3. The solid electrolyte according to claim 1 , wherein a measurement value (D50) obtained through particle size distribution measurement is equal to or greater than 0.1 μm and equal to or less than 10 μm.
4. An all-solid secondary battery comprising:
the solid electrolyte according to claim 1 .
5. The all-solid secondary battery according to claim 4 , wherein a relative density of a pair of electrode layers and a solid electrolyte layer with the solid electrolyte that is provided between the pair of electrode layers is equal to or greater than 80%.
6. The solid electrolyte according to claim 2 , wherein a measurement value (D50) obtained through particle size distribution measurement is equal to or greater than 0.1 μm and equal to or less than 10 μm.
7. An all-solid secondary battery comprising:
the solid electrolyte according to claim 2 .
8. An all-solid secondary battery comprising:
the solid electrolyte according to claim 3 .
9. An all-solid secondary battery comprising:
the solid electrolyte according to claim 6 .
10. The all-solid secondary battery according to claim 7 , wherein a relative density of a pair of electrode layers and a solid electrolyte layer with the solid electrolyte that is provided between the pair of electrode layers is equal to or greater than 80%.
11. The all-solid secondary battery according to claim 8 , wherein a relative density of a pair of electrode layers and a solid electrolyte layer with the solid electrolyte that is provided between the pair of electrode layers is equal to or greater than 80%.