Low ash lubricant and fuel additive comprising alkoxylated amine
A lubricating oil detergent composition comprises an overbased calcium sulfonate and a low ash detergent, which low ash detergent is metal free and comprises the reaction product of an acidic organic compound such as an alkylated salicylic acid, a boron compound and an amine component.
1. A phenate-free lubricating oil composition comprising:
greater than 70 wt %, based on the weight of the lubricating oil composition, of an oil of lubricating viscosity; and
an effective amount of a detergent composition, the detergent composition comprising an overbased calcium sulfonate and a low ash detergent, wherein the low ash detergent comprises the reaction product of one or more acidic organic compound, one or more boron compound and an amine component comprising one or more amine, and which low ash detergent contains no metals, phosphorus or sulfur,
wherein the one or more acidic organic compound is one or more carboxylic acids selected from the group consisting of
substituted salicylic acids of formula I:
wherein R 1 is independently a hydrocarbyl group having from 1 to about 30 carbon atoms, and ‘a’ is an integer of 1 or 2;
the boron compound is selected from the group consisting of boric acid, trialkyl borates, alkyl boric acids, dialkyl boric acids, boric oxide, boric acid complex, cycloalkyl boric acids, dicycloalkyl boric acids, diaryl boric acids, and substitution products of the foregoing with alkoxy groups or alkyl groups;
and the amine component comprises one or more amine selected from the group consisting of alkoxylated amines, poly-alkyleneamines, poly-oxyalkyleneamines and polyalkylphenoxyaminoalkanes, and
wherein the lubricating oil composition contains no phenate.
2. The phenate-free lubricating oil composition according to claim 1 wherein R 1 is independently alkyl, alkenyl, cycloalkyl, cycloalkenyl, aromatic, aromatic substituted by aliphatic or aromatic having from 1 to about 30 carbon atoms, or said alkyl, alkenyl, cycloalkyl, cycloalkenyl, aromatic, aromatic substituted by aliphatic or aromatic substituted by halo or hydroxyl, or said alkyl, alkenyl, cycloalkyl or cycloalkenyl which contains in a chain otherwise composed of carbon a heteroatom selected from oxygen or nitrogen.
3. The phenate-free lubricating oil composition according to claim 1 wherein R 1 is independently a hydrocarbyl having from 1 to about 30 carbon atoms which is purely hydrocarbon.
4. The phenate-free lubricating oil composition according to claim 1 wherein the amine component further comprises one or more alkoxylated amides.
5. The phenate-free lubricating oil composition according to claim 1 , wherein the one or more boron compound comprises boric acid.
6. The phenate-free lubricating oil composition according to claim 5 , wherein the one or more boron compound comprises boric acid.
7. The phenate-free lubricating oil composition according to claim 1 , wherein the oil of lubricating viscosity is a marine cylinder oil.
8. The phenate-free lubricating oil composition according to claim 1 , wherein R 1 is independently alkyl or cyclic alkyl.
9. The phenate-free lubricating oil composition according to claim 1 , wherein R 1 is independently dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl or an isomer thereof.
10. The phenate-free lubricating oil composition according to claim 1 , wherein R 1 is tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl or an isomer thereof.