IP Library Granted Patent US 11,260,343
Granted Patent B2
US 11,260,343 · App. 16/592,532 · Granted Mar 1, 2022

Molten hydroxide membrane for separation of acid gases from emissions

Inventors: Marcus Worsley (Hayward, CA); Patrick Campbell (Oakland, CA); Sangil Kim (Chicago, IL); Matthew Merrill (Dublin, CA)
Assignee: Lawrence Livermore National Security, LLC
B01D53/228B01D53/40B01D53/508B01D53/565B01D53/62B01D53/82B01D61/38B01D69/10B01D69/12B01D71/02B01D69/02B01D71/022B01D71/024B01D2053/221B01D2251/306B01D2251/604B01D2257/302B01D2257/404B01D2257/50B01D2257/504B01D2258/0283B01D2311/13B01D2325/02B01D2325/04B01D2325/26Y02C20/40
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 11,260,343
App. No.
16/592,532
Granted
Mar 1, 2022
Kind
B2
Abstract

In one embodiment, a method for separating acidic gases from a gas mixture includes exposing the gas mixture to a separation membrane at an elevated temperature, where the separation membrane includes a porous support and at least one molten alkali metal hydroxide disposed within pores of the porous support.

Claims (10)

1. A method for separating acidic gases from a gas mixture, the method comprising:

exposing the gas mixture to a separation membrane at an elevated temperature, wherein the separation membrane comprises a porous support and at least one molten alkali metal hydroxide disposed within pores of the porous support.

2. The method as recited in claim 1 , comprising reversibly solvating the acidic gases in the at least one molten alkali metal hydroxide at an inlet of the separation membrane.

3. The method as recited in claim 1 , comprising releasing solvated ions from an outlet of the separation membrane, the solvated ions being anionic forms of the acidic gases.

4. The method as recited in claim 1 , comprising applying a potential across the separation membrane.

5. The method as recited in claim 1 , comprising applying an alternating current (A/C) across the separation membrane.

6. The method as recited in claim 1 , comprising applying a pressure gradient across the separation membrane, wherein the pressure gradient is in a range from about 0 atmospheres to about 20 atmospheres.

7. The method as recited in claim 1 , wherein the elevated temperature is in a range from about 200 C to about 700 C.

8. The method as recited in claim 1 , wherein the acidic gases are gases having a formula selected from a group consisting of: CO x , NO y and SO z , wherein x is a value in a range from 1-2, y is a value in a range from 1-3, and z is a value in a range from 1-4.

9. The method as recited in claim 1 , comprising exposing the separation membrane to a sweep gas on a side of the separation membrane opposite a side to which the gas mixture is exposed, wherein the sweep gas comprises steam.

Assignments (3)
CONFIRMATORY LICENSE Recorded Mar 19, 2021
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC.
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 055657/0353 →
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Jan 15, 2021
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 055009/0551 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 29, 2020
From: WORSLEY, MARCUS; CAMPBELL, PATRICK; KIM, SANGIL; MERRILL, MATTHEW
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 051663/0729 →
Continuity (2)
Division 15159681 · May 19, 2016
Related Publication 20200030740A1 · Jan 30, 2020