IP Library › Granted Patent US 11,482,528
Granted Patent B2
US 11,482,528 · App. 16/729,278 · Granted Oct 25, 2022

Pillar capacitor and method of fabricating such

Inventors: Gaurav Thareja (Santa Clara, CA); Sasikanth Manipatruni (Portland, OR); Rajeev Kumar Dokania (Beaverton, OR); Ramamoorthy Ramesh (Moraga, CA); Amrita Mathuriya (Portland, OR)
Assignee: Kepler Computing Inc.
H01L27/11502G11C11/221H01L28/40
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Quick Facts
Patent No.
US 11,482,528
App. No.
16/729,278
Granted
Oct 25, 2022
Kind
B2
Abstract

The memory bit-cell formed using the ferroelectric capacitor results in a taller and narrower bit-cell compared to traditional memory bit-cells. As such, more bit-cells can be packed in a die resulting in a higher density memory that can operate at lower voltages than traditional memories while providing the much sought after non-volatility behavior. The pillar capacitor includes a plug that assists in fabricating a narrow pillar.

Claims (63)

1. An apparatus comprising:

a transistor;

an etch stop layer (ESL); and

a pillar capacitor coupled to the transistor, wherein the pillar capacitor comprises:

a first electrode comprising a first conductive material, wherein the first electrode is substantially a U-shaped structure, wherein the U-shaped structure comprises a base portion and substantially vertical portions in contact with the base portion;

a first dielectric inside the U-shaped structure of the first electrode;

a first structure, separate and different from the first dielectric, wherein the first structure is adjacent to the first dielectric such that the first structure plugs the U-shaped structure, and wherein the first structure is laterally adjacent to first portions of the substantially vertical portions of the first electrode;

a second electrode comprising a second conductive material, the second electrode adjacent to second portions of the substantially vertical portions of the first electrode, wherein a portion of the second electrode is adjacent to the ESL;

a ferroelectric material adjacent to the second electrode;

a third electrode adjacent to the ferroelectric material, the third electrode comprising a third conductive material; and

a fourth electrode adjacent to the third electrode, the fourth electrode comprising a fourth conductive material.

2. The apparatus of claim 1 , wherein the ESL includes one or more of: Si, C, or N.

3. The apparatus of claim 1 , wherein the first conductive material and the fourth conductive material includes one or more of: Ti, Ru, Cu, Co, Ta, W, TaN, or WN.

4. The apparatus of claim 1 , wherein the second and third conductive materials include one or more of: SrO, IrO2, RuO2, PdO2, PsO2, ReO3, LaCoO3, SrCoO3, SrRuO3, LaMnO3, SrMnO3, YBa2Cu3O7, Bi2Sr2CaCu2O8, LaNiO3, or their alloys.

5. The apparatus of claim 1 , wherein the ferroelectric material includes one of:

Bismuth ferrite (BFO) with a doping material, wherein the doping material is one of Lanthanum, or elements from lanthanide series of periodic table;

Lead zirconium titanate (PZT), or PZT with a doping material, wherein the doping material is one of La or Nb;

a relaxor ferroelectric includes one of lead magnesium niobate (PMN), lead magnesium niobate-lead titanate (PMN-PT), lead lanthanum zirconate titanate (PLZT), lead scandium niobate (PSN), Barium Titanium-Bismuth Zinc Niobium Tantalum (BT-BZNT), or Barium Titanium-Barium Strontium Titanium (BT-BST);

a perovskite which includes one of: BaTiO3, PbTiO3, KNbO3, or NaTaO3;

a hexagonal ferroelectric which includes one of: YMnO3 or LuFeO3;

hexagonal ferroelectrics of a type h-RMnO3, where R is a rare earth element including one of: cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), holmium (Ho), lanthanum (La), lutetium (Lu), neodymium (Nd), praseodymium (Pr), promethium (Pm), samarium (Sm), scandium (Sc), terbium (Tb), thulium (Tm), ytterbium (Yb), or yttrium (Y);

Hafnium (Hf), Zirconium (Zr), Aluminum (Al), Silicon (Si), their oxides or their alloyed oxides;

Hafnium oxides of a form, Hf1-x Ex Oy where E can be Al, Ca, Ce, Dy, Er, Gd, Ge, La, Sc, Si, Sr, Sn, or Y;

Al(1-x)Sc(x)N, Ga(1-x)Sc(x)N, Al(1-x)Y(x)N or Al(1-x-y)Mg(x)Nb(y)N, y doped HfO2, where x includes one of: Al, Ca, Ce, Dy, Er, Gd, Ge, La, Sc, Si, Sr, Sn, or Y, wherein ‘x’ is a fraction;

Niobate type compounds LiNbO3, LiTaO3, Lithium iron Tantalum Oxy Fluoride, Barium Strontium Niobate, Sodium Barium Niobate, or Potassium strontium niobate; or

an improper ferroelectric which includes one of: [PTO/STO]n or [LAO/STO]n, where ‘n’ is between 1 to 100.

6. The apparatus of claim 1 , wherein the first dielectric comprises one of: SiO, SiOC, or SiOCN.

7. The apparatus of claim 1 , wherein the first structure comprises one of: SiN, Al2O3, or ZrO.

8. The apparatus of claim 1 , wherein the first, second, third, and fourth electrodes have a thickness in a range of 0.1 nm to 50 nm; and wherein the ESL has a thickness in a range of 0.1 nm to 50 nm.

9. The apparatus of claim 1 , wherein the transistor is one of a CMOS, TFET, a gate all around transistor, planar transistor, or a non-planar transistor.

10. A system comprising:

a processor;

a communication interface communicatively coupled to the processor; and

a memory coupled to the processor, wherein the memory includes bit-cells, wherein one of the bit-cells includes:

a transistor;

an etch stop layer (ESL); and

a pillar capacitor coupled the transistor, wherein the pillar capacitor comprises:

a first electrode comprising a first conductive material, wherein the first electrode is substantially a U-shaped structure, wherein the U-shaped structure comprises a base portion and substantially vertical portions in contact with the base portion;

a first dielectric inside the U-shaped structure of the first electrode;

a first structure, separate and different from the first dielectric, wherein the first structure is adjacent to the first dielectric such that the first structure plugs the U-shaped structure, and wherein the first structure is laterally adjacent to first portions of the substantially vertical portions of the first electrode;

a second electrode comprising a second conductive material, the second electrode adjacent to second portions of the substantially vertical portions of the first electrode,

a ferroelectric material adjacent to the second electrode;

a third electrode adjacent to the ferroelectric material, wherein the third electrode includes a third conductive material; and

a fourth electrode adjacent to the third electrode, wherein the fourth electrode includes a fourth conductive material.

11. The system of claim 10 , wherein the processor is one of an accelerator or an artificial intelligence (AI) processor.

12. The system of claim 10 , wherein:

the ESL includes one or more of: Si, C, or N;

the first conductive material and the fourth conductive material includes one or more of: Ti, Ru, Cu, Co, Ta, W, TaN, or WN;

the second conductive material includes one of: SrO, IrO2, RuO2, PdO2, PsO2, ReO3, LaCoO3, SrCoO3, SrRuO3, LaMnO3, SrMnO3, YBa2Cu3O7, Bi2Sr2CaCu2O8, or LaNiO3;

the ferroelectric material includes one of:

Bismuth ferrite (BFO) with a doping material, wherein the doping material is one of Lanthanum, or elements from lanthanide series of periodic table;

Lead zirconium titanate (PZT), or PZT with a doping material, wherein the doping material is one of La or Nb;

a relaxor ferroelectric which includes one of lead magnesium niobate (PMN), lead magnesium niobate-lead titanate (PMN-PT), lead lanthanum zirconate titanate (PLZT), lead scandium niobate (PSN), Barium Titanium-Bismuth Zinc Niobium Tantalum (BT-BZNT), or Barium Titanium-Barium Strontium Titanium (BT-BST);

a perovskite which includes one of: BaTiO3, PbTiO3, KNbO3, or NaTaO3;

a hexagonal ferroelectric which includes one of: YMnO3 or LuFeO3;

hexagonal ferroelectrics of a type h-RMnO3, where R is a rare earth element including one of: cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), holmium (Ho), lanthanum (La), lutetium (Lu), neodymium (Nd), praseodymium (Pr), promethium (Pm), samarium (Sm), scandium (Sc), terbium (Tb), thulium (Tm), ytterbium (Yb), or yttrium (Y);

Hafnium (Hf), Zirconium (Zr), Aluminum (Al), Silicon (Si), their oxides or their alloyed oxides;

Hafnium oxides of a form, Hf1-x Ex Oy where E can be Al, Ca, Ce, Dy, Er, Gd, Ge, La, Sc, Si, Sr, Sn, or Y;

Al(1-x)Sc(x)N, Ga(1-x)Sc(x)N, Al(1-x)Y(x)N or Al(1-x-y)Mg(x)Nb(y)N, y doped HfO2, where x includes one of: Al, Ca, Ce, Dy, Er, Gd, Ge, La, Sc, Si, Sr, Sn, or Y, wherein ‘x’ is a fraction;

Niobate type compounds LiNbO3, LiTaO3, Lithium iron Tantalum Oxy Fluoride, Barium Strontium Niobate, Sodium Barium Niobate, or Potassium strontium niobate; or

an improper ferroelectric which includes one of: [PTO/STO]n or [LAO/STO]n, where ‘n’ is between 1 to 100;

the first dielectric comprises one of: SiO, SiOC, or SiOCN; and

the first structure comprises: SiN, Al2O3, or ZrO.

Assignments (2)
CORRECTIVE ASSIGNMENT TO CORRECT THE INVENTORSHIP PREVIOUSLY RECORDED ON REEL 051384 FRAME 0244. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jan 28, 2020
From: THAREJA, GAURAV; MANIPATRUNI, SASIKANTH; DOKANIA, RAJEEV KUMAR; RAMESH, RAMAMOORTHY; MATHURIYA, AMRITA
To: KEPLER COMPUTING INC.
Reel/Frame 051723/0919 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 30, 2019
From: THAREJA, GAURAV; MANIPATRUNI, SASIKANTH; DOKANIA, RAJEEV KUMAR; RAMESH, RAMAMOORTHY
To: KEPLER COMPUTING INC.
Reel/Frame 051384/0244 →
Continuity (1)
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