IP Library Granted Patent US 11,221,554
Granted Patent B2
US 11,221,554 · App. 16/746,640 · Granted Jan 11, 2022

EUV masks to prevent carbon contamination

Inventors: Pei-Cheng Hsu (Taipei, TW); Ta-Cheng Lien (Hsinchu County, TW); Hsin-Chang Lee (Hsinchu County, TW)
Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
G03F1/24G03F1/22
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Quick Facts
Patent No.
US 11,221,554
App. No.
16/746,640
Granted
Jan 11, 2022
Kind
B2
Abstract

An extreme ultra-violet (EUV) mask and method for fabricating the same is disclosed. For example, the EUV mask includes a substrate, a multi-layered mirror layer formed on the substrate, a metal capping layer formed on the multi-layered mirror layer, and a multi-layered absorber layer formed on the metal capping layer. The multi-layered absorber layer includes features etched into the multi-layered absorber layer to define structures on a semiconductor device.

Claims (31)

1. An extreme ultra-violet (EUV) mask, comprising:

a substrate;

a multi-layered mirror layer formed on the substrate;

a metal capping layer formed on the multi-layered mirror layer; and

a multi-layered absorber layer comprising at least one oxide layer formed over the multi-layered mirror layer, wherein the multi-layered absorber layer comprises features etched into the multi-layered absorber layer to define structures on a semiconductor device.

2. The EUV mask of claim 1 , wherein the substrate comprises a low thermal expansion material.

3. The EUV mask of claim 1 , wherein the multi-layered absorber layer comprises a first metal oxide layer, a metal nitride layer, and a second metal oxide layer.

4. The EUV mask of claim 3 , wherein the first metal oxide layer comprises at least one of: Tantalum Boro-oxide (TaBO), Tantalum Pentoxide (Ta 2 O 5 ), Ruthenium oxide (RuO), Ruthenium Niobium Oxide (RuNbO), or Niobium Pentoxide (Nb 2 O 5 ).

5. The EUV mask of claim 4 , wherein the first metal oxide layer comprises TaBO having a thickness of approximately 1-2 nanometers.

6. The EUV mask of claim 4 , wherein the metal capping layer comprises TaBO or Ta 2 O 5 .

7. The EUV mask of claim 6 , wherein the metal capping layer comprises Ruthenium (Ru) or Ruthenium oxide (RuO).

8. The EUV mask of claim 7 , wherein the metal capping layer has a thickness of approximately 0-4 nanometers.

9. The EUV mask of claim 3 , wherein the metal nitride layer comprises a Tantalum Boro-nitride (TaBN).

10. The EUV mask of claim 3 , wherein the second metal oxide layer comprises Tantalum Boro-oxide (TaBO).

11. An extreme ultra-violet (EUV) mask, comprising:

a substrate;

a multi-layered mirror layer formed on the substrate;

a metal capping layer formed on the multi-layered mirror layer; and

an oxide containing absorber layer formed over the multi-layered mirror layer, wherein the oxide containing absorber layer comprises features etched into the oxide containing absorber layer to define structures on a semiconductor device.

12. The EUV mask of claim 11 , wherein the metal capping layer comprises Ruthenium (Ru) or Ruthenium oxide (RuO) having a thickness of approximately 0-4 nanometers.

13. The EUV mask of claim 11 , wherein the oxide containing absorber layer comprises a first layer of Tantalum Boro-oxide (TaBO), a layer of Tantalum Boro-nitride (TaBN), and a second layer of Tantalum Boro-oxide (TaBO) formed on a metal capping layer.

14. The EUV mask of claim 11 , wherein the oxide containing absorber layer comprises a layer of Tantalum Boro-oxide (TaBO), a layer of Tantalum Boro-nitride (TaBN), and a layer of Tantalum Pentoxide (Ta 2 O 5 ) formed on a metal capping layer.

15. The EUV mask of claim 11 , wherein the oxide containing absorber layer comprises a layer of Tantalum Boro-oxide (TaBO), a layer of Tantalum Boro-nitride (TaBN), and a layer of Ruthenium oxide (RuO).

16. The EUV mask of claim 11 , wherein the oxide containing absorber layer comprises a layer of Tantalum Boro-oxide (TaBO), a layer of Tantalum Boro-nitride (TaBN), and a layer of Ruthenium Niobium Oxide (RuNbO).

17. The EUV mask of claim 11 , wherein the oxide containing absorber layer comprises a layer of Tantalum Boro-oxide (TaBO), a layer of Tantalum Boro-nitride (TaBN), and a layer of Niobium Pentoxide (Nb 2 O 5 ).

18. A method for fabricating an extreme ultra-violet (EUV) mask, comprising:

depositing a multi-layered absorber layer containing at least one oxide layer on a multi-layered mirror layer;

defining features in the multi-layered mirror layer via an expose, bake, and develop process of photoresist coated on a hard mark layer; and

etching the multi-layered absorber layer to form the features in the multi-layered absorber layer to define structures on a semiconductor device.

19. The method of claim 18 , wherein the multi-layered absorber layer comprises layer of a first metal oxide layer, a layer of Tantalum Boro-nitride (TaBN), and Tantalum Boro-oxide (TaBO).

20. The method of claim 18 , wherein the first metal oxide layer comprises at least one of: Tantalum Boro-oxide (TaBO), Tantalum Pentoxide (Ta 2 O 5 ), Ruthenium oxide (RuO), Ruthenium Niobium Oxide (RuNbO), or Niobium Pentoxide (Nb 2 O 5 ).

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 22, 2020
From: HSU, PEI-CHENG; LIEN, TA-CHENG; LEE, HSIN-CHANG
To: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Reel/Frame 051589/0530 →
Continuity (1)
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