Polymer microspheres as binders for composite electrolytes
Provided herein are composite electrolytes that include inorganic conductors and polar polymers. By providing the polar polymers as structures such as microspheres in a suspension in a non-polar solvent, the polar polymers can be used as binders in composites that include sulfide electrolytes. The resulting composites have high room temperature conductivities and good mechanical properties. Also provided are composites that include inorganic conductors and other polymers that are insoluble in non-polar solvents. Also provides methods of forming composite electrolytes using suspensions of polymer microstructures in a processing solvent and the resulting composite electrolytes.
1. A composite comprising:
ionically conductive sulfidic particles and a polymer binder comprising a first polymer, and a second polymer, wherein:
the first polymer is less soluble than the second polymer in a non-polar solvent,
the first polymer has a melting temperature (T m ) or a glass transition temperature (T g ) greater than a T m or T g of the second polymer, and
the composite is formed by melting microstructures of the first polymer resulting in loss of shape, wherein the first polymer is dispersed in the composite with lack of uniform shape.
2. The composite of claim 1 , wherein the weight percent of the first polymer in the composite is greater that the weight percent of the second polymer in the composite.
3. The composite of claim 1 , wherein the non-polar solvent has a polarity index of less than 3.5.
4. The composite of claim 1 , wherein the non-polar solvent has a polarity index of less than 3.0.
5. The composite of claim 1 , wherein the ionically conductive sulfidic particles are glass or glass ceramic particles.
6. The composite of claim 1 , wherein the ionically conductive sulfidic particles are argyrodites.
7. The composite of claim 1 , wherein the weight percent of the polymer binder in the composite is between 2.5% and 60%.
8. The composite of claim 1 , wherein the weight percent of the polymer binder in the composite is between 15% and 45%.
9. The composite of claim 8 , wherein the balance of the composite consists essentially of the ionically conductive sulfidic particles.
10. The composite of claim 1 , wherein the polymer binder consists essentially of the first polymer and the second polymer.
11. The composite of claim 1 , wherein the second polymer is one of: styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-ethylene/propylene-styrene (SEPS), styrene-ethylene-butylene-styrene (SEBS), styrene butadiene rubber (SBR), ethylene propylene diene monomer (EPDM) rubber, and polybutadiene (PBD), polyisoprene (PI), and polystyrene (PS).
12. The composite of claim 1 , wherein the first polymer is one of a polyester, poly(vinyl chloride) (PVC), poly(methyl methacrylate) (PMMA), cellulose acetate (CA), polyvinylidene fluoride (PVDF), polyethylene oxide (PEO), polypropylene oxide (PPO), polysulfone (PSU), polyurethane (PU), polyethersulfone (PES), polyetherimide (PEI), acrylonitrile butadiene styrene (ABS), polycarbonate (PC), poly(vinyl acetate-co-ethylene) (PVAE), poly(vinyl alcohol) (PVA), nitrile butadiene rubber (NBR), polyacrylonitrile (PAN), polypropylene (PP), polyethylene (PE), polytetrafluoroethylene (PTFE), and polyphenylene sulfide (PPS).
13. The composite of claim 12 , wherein the second polymer is one of: styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-ethylene/propylene-styrene (SEPS), styrene-ethylene-butylene-styrene (SEBS), styrene butadiene rubber (SBR), ethylene propylene diene monomer (EPDM) rubber, and polybutadiene (PBD), polyisoprene (PI), and polystyrene (PS).
14. The composite of claim 1 , wherein the composite is a separator in a battery.
15. An electrode composition comprising the composite of claim 1 and an active material.
16. The electrode composition of claim 15 , wherein the electrode active material comprises a transition metal oxide active material.
17. The electrode composition of claim 15 , wherein the electrode active material comprises silicon-containing active material.
18. The electrode composition of claim 15 , wherein the electrode active material comprises a graphitic active material.
19. The composite of claim 1 , wherein the first polymer is in the form of microstructures and the ionically conductive sulfidic particles and the microstructures are in a film of the second polymer.
20. A composite comprising:
ionically conductive sulfidic particles, a first polymer, and a second polymer, wherein the
the first polymer is less soluble in a non-polar solvent than the second polymer
the weight percent of the second polymer in the composite is greater that the weight percent of the first polymer in the composite, and
the composite is formed by melting microstructures of the first polymer resulting in loss of shape, wherein the first polymer is dispersed in the composite with lack of uniform shape.
21. The composite of claim 20 , wherein the first polymer has a melting temperature (T m ) or a glass transition temperature (T g ) greater than a T m or T g of the second polymer.
22. The composite of claim 20 , wherein the first polymer is the form of microstructures and the ionically conductive sulfidic particles and the microstructures are in a film of the second polymer.