Granted Patent
B2
US 12,355,075 · App. 17/661,898 · Granted Jul 8, 2025
Compliant solid-state ionically conductive composite materials and method for making same
Inventors:
Alexander Teran (Oakland, CA); Joanna Burdynska (Berkeley, CA); Benjamin Rupert (Hayward, CA); Eduard Nasybulin (Fremont, CA); Saranya Venugopal (Emeryville, CA); Simmi Kaur Uppal (Oakland, CA)
Assignee:
Blue Current, Inc.
H01M4/405C03C3/321C03C4/14C03C8/14C08J3/203C08J5/18C08L9/00C08L83/04C08L83/06C08L83/08H01M4/134H01M4/362H01M4/8652H01M6/181H01M10/052H01M10/0525H01M10/056H01M10/0562C03C2204/00C08J2309/00C08J2383/04C08J2383/06C08J2383/08C08J2425/08C08J2453/02C08J2483/04C08J2483/08C08K3/40C08L2203/20C08L2205/025H01M2300/0068H01M2300/0082H01M2300/0091
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Abstract
Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions.
Claims (22)
1. A solid-state alkali ion battery comprising:
an anode comprising a silicon-containing active material;
a separator comprising an inorganic phase comprising an ionically conductive inorganic particles and an organic phase comprising a binder, wherein the binder is a non-ionically-conductive polymer having a number average molecular weight of at least 100 kg/mol, and wherein the binder is soluble in a non-polar organic solvent, wherein particle-to-particle contact between the ionically conductive inorganic particles provides ionically conductive pathways through the separator such that the separator has an ion conductivity of at least 1×10 −4 S·cm.
2. The solid-state alkali ion battery of claim 1 , wherein the anode further comprises the ionically conductive inorganic particles.
3. The solid-state alkali ion battery of claim 1 , wherein the anode further comprises the binder.
4. The solid-state alkali ion battery of claim 1 , wherein the binder is styrene-ethylene butylene-styrene (SEBS).
5. The solid-state alkali ion battery of claim 1 , wherein the ionic conduction in the separator is solely due to contact between the ionically conductive inorganic particles.
6. The solid-state alkali ion battery of claim 1 , wherein the ionically conductive inorganic particles are amorphous.
7. The solid-state alkali ion battery of claim 1 , wherein the ionically conductive inorganic particles are is crystalline or semi-crystalline.
8. The solid-state alkali ion battery of claim 1 , wherein the ionically conductive inorganic particles are lithium ion conductors.
9. The solid-state alkali ion battery of claim 1 , wherein the ionically conductive inorganic particles are sodium ion conductors.
10. The solid-state alkali ion battery of claim 1 , wherein the separator comprises a homogeneous mixture of the binder and a second organic component.
11. The solid-state alkali ion battery of claim 1 , wherein all of the ionically conductive inorganic particles are crystalline.
12. A solid-state alkali ion battery comprising:
an anode comprising a silicon-containing active material, an ionically conductive inorganic particles and an organic phase comprising a binder, wherein the binder is a non-ionically-conductive polymer having a number average molecular weight of at least 100 kg/mol, and wherein the binder is soluble in a non-polar organic solvent wherein particle-to-particle contact between the ionically conductive inorganic particles provides ionically conductive pathways through the anode such that the anode has an ion conductivity of at least 1×10 −4 S·cm.
13. The solid-state alkali ion battery of claim 12 , wherein the binder is styrene-ethylene butylene-styrene (SEBS).
14. The solid-state alkali ion battery of claim 12 , wherein anode is ionically conductive and the ionic conduction in the anode is solely due to contact between the ionically conductive inorganic particles.
15. The solid-state alkali ion battery of claim 12 , wherein the ionically conductive inorganic particles are amorphous.
16. The solid-state alkali ion battery of claim 12 , wherein the ionically conductive inorganic particles are crystalline or semi-crystalline.
17. The solid-state alkali ion battery of claim 12 , wherein the ionically conductive inorganic particles are lithium ion conductors.
18. The solid-state alkali ion battery of claim 12 , wherein the ionically conductive inorganic particles are sodium ion conductors.
19. The solid-state alkali ion battery of claim 12 , wherein all of the ionically conductive inorganic particles are crystalline.
Continuity (7)
Provisional Application
62470801
· Mar 13, 2017
Provisional Application
62446253
· Jan 13, 2017
Provisional Application
62425911
· Nov 23, 2016
Provisional Application
62368403
· Jul 29, 2016
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