Sulfide-based solid electrolyte for lithium ion cell, and solid electrolyte compound
Relating to a sulfide-based solid electrolyte compound for lithium ion batteries which has a cubic argyrodite-type crystal structure, to provide a compound which can suppress a generation amount of hydrogen sulfide when being left to stand in the air and which can maintain high conductivity even when being left to stand in dry air. Proposed is a sulfide-based solid electrolyte compound for lithium ion batteries containing a crystal phase of the cubic argyrodite-type crystal structure and represented by a composition formula (1): Li 7−x+y PS 6−x Cl x+y , wherein x and y in the composition formula (1) satisfy 0.05≦y≦0.9 and −3.0x+1.8≦y≦−3.0x+5.7.
1. A sulfide-based solid electrolyte compound for a lithium ion battery comprising a crystal phase of a cubic argyrodite-type crystal structure, and
being represented by a composition formula (1): Li 7−x+y PS 6−x Cl x+y , wherein x and y in the composition formula (1) satisfy 0.05≦y≦0.9 and −3.0x+1.8≦y≦−3.0x+5.7.
2. The sulfide-based solid electrolyte compound for a lithium ion battery according to claim 1 , wherein x and y in the composition formula (1) satisfy 0.05≦y≦0.4 and −3.0x+3.9≦y≦−3.0x+5.7.
3. A solid electrolyte comprising the sulfide-based solid electrolyte compound for a lithium ion battery according to claim 1 .
4. The solid electrolyte according to claim 3 comprising a single phase of the crystal phase of the cubic argyrodite-type crystal structure.
5. The solid electrolyte according to claim 3 comprising the crystal phase of the cubic argyrodite-type crystal structure and a crystal phase which is represented by LiCl.
6. The solid electrolyte according to claim 3 ,
wherein, in an X-ray diffraction pattern, a ratio [I L /(200)/I A (220)] of a peak intensity I L (200) of a (200) plane of the LiCl crystal phase with respect to a peak intensity I A (220) of a (220) plane of the cubic argyrodite-type crystal phase is 0.30 or less.
7. A method for producing the sulfide-based solid electrolyte compound for a lithium ion battery having the solid electrolyte according to claim 3 ,
wherein 38.8 to 72.0 parts (mol %) of lithium sulfide (Li 2 S) powder, 10.2 to 12.4 parts (mol %) of diphosphorus pentasulfide (P 2 S 5 ) powder, and 15.6 to 51.0 parts (mol %) of lithium chloride (LiCl) powder are mixed, and
the resultant mixture is calcined at 350 to 500 C under an inert atmosphere, or at 350 to 550 C under an atmosphere comprising a hydrogen sulfide gas.
8. A lithium ion battery comprising the solid electrolyte according to claim 3 .
9. A lithium ion battery comprising the solid electrolyte according to claim 3 , and a negative electrode active material containing carbon or silicon.
10. An application method of a lithium ion battery comprising
the solid electrolyte according to claim 3 ,
a negative electrode active material containing silicon, and
a positive electrode active material containing a lithium composite oxide,
wherein, in charge and discharge cycles, a termination voltage in a first charging is set to be higher than a termination voltage in a second or later charging.
11. A solid electrolyte comprising the sulfide-based solid electrolyte compound for a lithium ion battery according to claim 2 .
12. The solid electrolyte according to claim 11 comprising a single phase of the crystal phase of the cubic argyrodite-type crystal structure.
13. The solid electrolyte according to claim 11 comprising the crystal phase of the cubic argyrodite-type crystal structure and a crystal phase which is represented by LiCl.
14. The solid electrolyte according to claim 11 ,
wherein, in an X-ray diffraction pattern, a ratio [I L (200)/I A (220)] of a peak intensity I L (200) of a (200) plane of the LiCl crystal phase with respect to a peak intensity I A (220) of a (220) plane of the cubic argyrodite-type crystal phase is 0.30 or less.
15. A lithium ion battery comprising the solid electrolyte according to claim 4 .
16. A lithium ion battery comprising the solid electrolyte according to claim 5 .
17. A lithium ion battery comprising the solid electrolyte according to claim 6 .
18. A lithium ion battery comprising the solid electrolyte according to claim 11 .