Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
Disclosed are ethylene polymer compositions containing a homogeneously-branched first ethylene polymer component and 15-35 wt. % of a homogeneously-branched second ethylene polymer component of higher density than the first ethylene polymer component. The ethylene polymer composition can be characterized by a density from 0.912 to 0.925 g/cm 3 , a ratio of Mw/Mn from 2 to 5, a melt index less than 2 g/10 min, and a CY-a parameter at 190° C. from 0.35 to 0.7. These polymer compositions have the excellent dart impact strength and optical properties of a metallocene-catalyzed LLDPE, but with improved machine direction tear resistance, and can be used in blown film and other end-use applications. Further, methods for improving film Elmendorf tear strength also are described.
1. A process for improving film tear strength of a homogeneously-branched first ethylene polymer having a density in a range from about 0.90 to about 0.92 g/cm 3 , the process comprising:
(a) combining the first ethylene polymer with from about 15 to about 35 wt. % of a homogeneously-branched second ethylene polymer having a density in a range from about 0.935 to about 0.972 g/cm 3 to form an ethylene polymer composition,
the composition characterized by a composition melt index of less than or equal to about 2 g/10 min, a Mw from about 100 to about 200 kg/mol, and a ratio of Mw/Mn in a range from about 2 to about 3; and
(b) melt processing the composition through a film die to form a film;
wherein the addition of the second ethylene polymer increases a MD Elmendorf tear strength of the film.
2. The process of claim 1 , wherein the film is a blown film having an average thickness in a range from about 0.5 to about 8 mils.
3. The process of claim 1 , wherein the addition of the second ethylene polymer does not substantially change a haze of the film or a dart impact strength of the film.
4. A process for producing a film with a target MD Elmendorf tear strength, the process comprising:
(a) combining a homogeneously-branched first ethylene polymer having a density in a range from about 0.90 to about 0.92 g/cm 3 with from about 15 to about 35 wt. % of a homogeneously-branched second ethylene polymer having a density in a range from about 0.935 to about 0.972 g/cm 3 and a melt index of less than or equal to about 50 g/10 min to form an ethylene polymer composition,
the composition characterized by a composition melt index of less than or equal to about 2 g/10 min and a Mw from about 100 to about 200 kg/mol; and
(b) adjusting an amount of the second ethylene polymer in the composition, and melt processing the composition through a film die to produce the film with the target MD Elmendorf tear strength;
wherein the tear strength increases as the amount of the second ethylene polymer in the composition increases.
5. The process of claim 4 , wherein the first ethylene polymer is combined with from about 20 to about 30 wt. % of the second ethylene polymer.
6. The process of claim 1 , wherein the first ethylene polymer comprises an ethylene/1-butene copolymer, an ethylene/1-hexene copolymer, and/or an ethylene/1-octene copolymer.
7. The process of claim 6 , wherein the second ethylene polymer is an ethylene/α-olefin copolymer having a density in a range from about 0.94 to about 0.96 g/cm 3 .
8. The process of claim 7 , wherein the composition melt index is in range from about 0.5 to about 1.8 g/10 min.
9. The process of claim 1 , wherein the composition is further characterized by:
a density in a range from about 0.912 to about 0.925 g/cm 3 ;
a CY-a parameter in a range from about 0.35 to about 0.7; and
an ATREF curve containing at least two peaks, with a first peak at a temperature in a range from about 60 to about 72° C., and a second peak at a temperature in a range from about 92 to about 104° C.
10. The process of claim 1 , wherein:
the first ethylene polymer is combined with from about 15 to about 25 wt. % of the second ethylene polymer; and
the first ethylene polymer and the second ethylene polymer contain no measurable amount of hafnium or titanium.
11. The process of claim 1 , wherein the first ethylene polymer is combined with from about 25 to about 35 wt. % of the second ethylene polymer.
12. The process of claim 1 , wherein:
a total amount of the first ethylene polymer and the second ethylene polymer in the composition is at least about 85 wt. %; and
the composition further comprises an antioxidant, an acid scavenger, an antiblock additive, a slip additive, a colorant, a filler, a polymer processing aid, a UV additive, or any combination thereof.
13. The process of claim 1 , wherein the MD Elmendorf tear strength of the film is in a range from about 100 to about 500 g/mil.
14. The process of claim 4 , wherein the film is a blown film having an average thickness in a range from about 0.5 to about 8 mils.
15. The process of claim 4 , wherein adjusting the amount of the second ethylene polymer does not substantially change a haze of the film, does not substantially change a dart impact strength of the film, or both.
16. The process of claim 4 , wherein the target MD Elmendorf tear strength of the film is in a range from about 100 to about 500 g/mil.
17. The process of claim 4 , wherein the first ethylene polymer and the second ethylene polymer, independently, comprise an ethylene/α-olefin copolymer.
18. The process of claim 17 , wherein the composition melt index is in range from about 0.5 to about 1.8 g/10 min.
19. The process of claim 18 , wherein the composition is further characterized by:
a density in a range from about 0.912 to about 0.925 g/cm 3 ; and
a ratio of Mw/Mn in a range from about 2 to about 5.
20. The process of claim 19 , wherein:
the first ethylene polymer is combined with from about 20 to about 30 wt. % of the second ethylene polymer; and
the first ethylene polymer and the second ethylene polymer contain no measurable amount of hafnium or titanium.
21. A process for improving film tear strength of a homogeneously-branched first ethylene polymer having a density in a range from about 0.90 to about 0.92 g/cm 3 , the process comprising:
(a) combining the first ethylene polymer with from about 15 to about 35 wt. % of a homogeneously-branched second ethylene polymer having a density in a range from about 0.94 to about 0.97 g/cm 3 to form an ethylene polymer composition,
the composition characterized by a composition melt index of less than or equal to about 2 g/10 min, a Mw from about 100 to about 200 kg/mol, and a ratio of Mw/Mn in a range from about 2 to about 3; and
(b) melt processing the composition through a film die to form a film; wherein:
the addition of the second ethylene polymer increases a MD Elmendorf tear strength of the film and does not substantially change a haze of the film; and
the first ethylene polymer and the second ethylene polymer contain no measurable amount of hafnium or titanium.