Razor blade and manufacturing method thereof
The present disclosure provides an improvement to razor blade coating by a physical vapor deposition method, by forming a hard coating layer as a thin coating layer in which chromium boride, which is a nanocrystalline structure having high hardness, is dispersed in an amorphous mixture of chromium and boron, thereby improving the strength and hardness of the thin coating layer and securing the bonding force by chromium in the amorphous mixture between the hard coating layer and a blade substrate on which an edge of the razor blade is formed.
1. A razor blade, comprising:
a blade substrate on which a blade edge is formed;
a hard coating layer coated on the blade substrate, the hard coating layer including an amorphous region in which chromium and boron are mixed, wherein one or more nanocrystalline structures are dispersed in the amorphous region; and
a polymer coating formed on the hard coating layer,
wherein the one or more nanocrystalline structures included in the hard coating layer has a volume ratio of 30% or more.
2. The razor blade of claim 1 , wherein the one or more nanocrystalline structures comprise chromium boride.
3. The razor blade of claim 1 , wherein the hard coating layer is a single layer.
4. The razor blade of claim 1 , wherein the one or more nanocrystalline structures comprise particles with a diameter in a range of 3 to 100 nm.
5. The razor blade of claim 1 , wherein the hard coating layer has a thickness in a range of 10 to 1000 nm.
6. The razor blade of claim 1 , further comprising an adhesion-enhancing layer disposed between the hard coating layer and the blade substrate.
7. The razor blade of claim 6 , wherein an amount of chromium in the adhesion-enhancing layer is at least 90%.
8. The razor blade of claim 1 , wherein the hard coating layer is configured to have the one or more nanocrystalline structures at a ratio that varies gradually from an inner side to an outer side of the hard coating layer.
9. A method for manufacturing a razor blade, the method comprising:
performing a heat treatment on a blade substrate;
forming a blade edge on the blade substrate by polishing the heat-treated blade substrate;
forming a hard coating layer by performing physical vapor deposition (PVD) on the heat-treated blade substrate, on which the blade edge is formed, by using a single composite target including chromium and boron that are mechanically combined and mixed to provide the hard coating layer including an amorphous region in which the chromium and the boron are mixed, wherein one or more nanocrystalline structures are dispersed in the amorphous region; and
forming a polymer coating on the hard coating layer,
wherein the physical vapor deposition is performed for sputtering by a collision cascade process under a sputtering condition that the blade substrate has a bias in a range of −50 to −750 V, a temperature in a range of 0 to 200° C., and a direct current (DC) power density in a range of 1 to 12 W/cm2.
10. The method of claim 9 , wherein the hard coating layer is a single layer.
11. The method of claim 9 , wherein the one or more nanocrystalline structures comprise particles with a diameter in a range of 3 to 100 nm.
12. The method of claim 9 , wherein the physical vapor deposition that forms the hard coating layer is performed for sputtering by a collision cascade process under a sputtering condition that the blade substrate has a bias in a range of −200 to −600 V, a temperature in a range of 100 to 150° C., and a DC power density in a range of 4 to 8 W/cm2.
13. The method of claim 9 , wherein the single composite target further includes:
a material in which the chromium and the boron are crystallographically combined.
14. The method of claim 9 , wherein the hard coating layer is configured to have the one or more nanocrystalline structures of chromium boride at a volume ratio that is changed in a thickness direction by adjusting an area ratio of the chromium to the boron in the single composite target in a direction in which the blade substrate moves through a deposition with respect to the single composite target.
15. A razor blade comprising:
a blade substrate on which a blade edge is formed;
a hard coating layer coated on the blade substrate, the hard coating layer including an amorphous region in which chromium and boron are mixed, wherein one or more nanocrystalline structures are dispersed in the amorphous region;
a polymer coating formed on the hard coating layer; and
an adhesion-enhancing layer disposed between the hard coating layer and the blade substrate,
wherein an amount of chromium in the adhesion-enhancing layer is at least 90%.
16. A razor blade comprising:
a blade substrate on which a blade edge is formed;
a hard coating layer coated on the blade substrate, the hard coating layer including an amorphous region in which chromium and boron are mixed, wherein one or more nanocrystalline structures are dispersed in the amorphous region; and
a polymer coating formed on the hard coating layer,
wherein the hard coating layer is configured to have the one or more nanocrystalline structures at a ratio that varies gradually from an inner side to an outer side of the hard coating layer.