Polyamide molding compound
The present invention relates to polyamide molding compounds which contain the following components (A) to (C) or consist of these components: (A) 50 to 98% by weight of at least one amorphous or microcrystalline specific polyamide; (B) 2 to 40% by weight of at least one semi-crystalline polyamide which is selected from the group consisting of PA 616, PA 516, PA 1016 and mixtures thereof; and (C) 0 to 16% by weight of at least one additive; the constituent amounts of the components (A) to (C) adding up to 100% by weight. The present invention also relates to molded articles made of these polyamide molding compounds and the use thereof.
1. A polyamide moulding compound comprising components (A) to (C):
(A) 50 to 98% by weight of at least one amorphous or microcrystalline polyamide, selected from the group consisting of PA MACM10, PA MACM12, PA MACM14, PA MACM16, PA MACM18, PA NDT/INDT, PA TMDC10, PA TMDC12, PA TMDC14, PA TMDC16, PA TMDC18, PA PACM10/11, PA PACM10/12, PA PACM12/612, PA PACM12/PACM14/612/614, PA MACMI/12, PA MACMT/12, PA MACMI/MACM12, PA MACMI/MACMN, PA MACMT/MACM12, PA MACMT/MACMN, PA MACM36, PA TMDC36, PA MACMI/MACM36, PA 6I/MACMI/12, PA MACMT/MACM36, PA MACMI/MACMT/12, PA 6I/6T/MACMI/MACMT, PA 6I/6T/MACMI/MACMT/12, PA 6I/6T/MACMI/MACMT/MACM12, PA MACM6/11, PA MACM6/12, PA MACM10/11, PA MACM10/12, PA MACM10/1010, PA MACM12/1012, PA MACM12/1212, PA MACM14/1014, PA MACM14/1214, PA MACM16/1016, PA MACM18/1018, PA 6I/6T/MACMI/MACMT/MACM12/612, PA 6I/6T/MACMI/MACMT/MACM12/12, PA MACMI/MACMT/MACM12/12, PA MACMI/MACMT/MACM12, PA 6I/6T/MACMI/MACMT/12, PA 6I/6T/6N/MACMI/MACMT/MACMN, PA TMDC12/TMDCT/TMDC36, PA TMDC12/TMDCI, PA TMDC12/TMDCI/TMDC36, and PA TMDC12/TMDCT, and copolymers thereof, the MACM being replaceable up to max. 35% by mol by PACM and/or TMDC, relative to the sum of the molar proportions of all the monomers of 100% by mol and/or the laurinlactam being replaceable totally or partially by caprolactam,
(B) 2 to 40% by weight of at least one partially crystalline polyamide selected from the group consisting of PA 616, PA 516, and PA 1016; and
(C) 0.1 to 20% by weight of at least one additive selected from the group consisting of inorganic and organic stabilisers, antiozonants, light-protection agents, UV absorbers or UV blockers, lubricants, colourants, marking agents, pigments, carbon black, graphite, graphene, carbon nanotubes, photochromic agents, antistatic agents, mould-release agents, condensation catalysts, chain regulators, defoamers, antiblocking agents, chain-lengthening additives, optical brighteners, IR absorbers, NIR absorbers, halogen-containing flame retardants, halogen-free flame retardants, natural layer silicates, synthetic layer silicates, metallic pigments, metal flakes, metal-coated particles, carbon fibres, metal fibres, plant fibres, polymer fibres, whiskers, and mineral fibres;
wherein the polyamide moulding compound is free of glass fibres;
the quantities of components (A) to (C) adding up in total to 100% by weight;
wherein a test piece made of the polyamide moulding compound
has a stress crack resistance in toluene, determined according to DIN 53449-3 (1984) bending strip method, of at least 20 MPa; and/or
has a stress crack resistance in n-hexane, determined according to DIN 53449-3 (1984) bending strip method, of at least 20 MPa.
2. The polyamide moulding compound according to claim 1 , wherein:
the proportion of component (A) in the polyamide moulding compound is in the range of 55 to 95.9% by weight, relative to the total weight of the polyamide moulding compound, and/or
the proportion of component (B) in the polyamide moulding compound is in the range of 4 to 35% by weight, relative to the total weight of the polyamide moulding compound.
3. The polyamide moulding compound according to claim 2 , wherein the proportion of component (A) in the polyamide moulding compound is in the range of 63 to 94.7% by weight relative to the total weight of the polyamide moulding compound, and/or
the proportion of component (B) in the polyamide moulding compound is in the range of 5 to 31% by weight, relative to the total weight of the polyamide moulding compound, and/or
the proportion of component (C) in the polyamide moulding compound is in the range of 0.3 to 6% by weight, relative to the total weight of the polyamide moulding compound.
4. The polyamide moulding compound according to claim 1 , wherein
the content of naphthalenedicarboxylic acid in component (A) is 0 to 10% by mol, relative to the sum of the molar proportions of all the monomers of components (A) of 100% by mol; and/or
the lactam- and/or ω-amino acid content in component (A) is 0 to 50% by mol, relative to the sum of the molar proportions of all the monomers of component (A) of 100% by mol.
5. The polyamide moulding compound according to claim 1 , wherein
component (A) is selected from the group consisting of PA MACM10, PA MACM12, PA MACM14, PA MACM16, PA MACM18, PA MACM36, PA TMDC10, PA TMDC12, PA TMDC14, PA TMDC16, PA TMDC18, PA NDT/INDT, PA PACM10/11, PA PACM10/12, PA PACM12/612, PA PACM12/PACM14/612/614, PA MACMI/12, PA MACMT/12, PA MACMI/MACM12, PA MACMT/MACM12, PA MACMI/MACMT/12, PA MACMI/MACMT/MACM12, PA MACMI/MACMT/MACM12/12, PA MACMI/MACMT/MACM12, PA 6I/6T/MACMI/MACMT, PA 6I/6T/MACMI/MACMT/12, PA 6I/6T/MACMI/MACMT/MACM12/12, PA 6I/6T/MACMI/MACMT/MACM12, PA MACM6/11, PA MACM6/12, PA MACM10/11, PA MACM10/12, PA MACM10/1010, PA MACM12/1012, PA MACM12/1212, PA MACM14/1014, PA MACM14/1214, PA MACM16/1016, and PA MACM18/1018, and
PA MACM10/PACM10, PA MACM12/PACM12, PA MACM14/PACM14, PA MACM16/PACM16, PA MACM18/PACM18, PA 6I/6T/MACMI/MACMT/PACMI/PACMT/12, and PA 6I/6T/MACMI/MACMT/MACM12/PACMI/PACMT/PACM12, wherein the amount of PACM in each of said PA MACM10/PACM10, PA MACM12/PACM12, PA MACM14/PACM14, PA MACM16/PACM16, PA MACM18/PACM18, PA 6I/6T/MACMI/MACMT/PACMI/PACMT/12, and PA 6I/6T/MACMI/MACMT/MACM12/PACMI/PACMT/PACM12 is up to 35% by mole of a respective sum of the amounts of MACM and PACM,
and mixtures or copolymers thereof.
6. The polyamide moulding compound according to claim 5 , wherein
component (A) is selected from the group consisting of PA MACM12, PA MACM14, PA MACM16, PA MACM18, PA TMDC16, PA TMDC18, PA NDT/INDT, PA PACM12/612, PA PACM12/PACM14/612/614, PA MACMI/12, PA MACMT/12, PA MACMI/MACM12, PA MACMI/MACMT/12, PA MACMI/MACMT/MACM12, PA 6I/6T/MACMI/MACMT/12, PA MACM10/1010, PA MACM12/1012, PA MACM12/1212, PA MACM14/1014, PA MACM16/1016, PA MACM18/1018, PA MACM10/PACM10, PA MACM12/PACM12, PA MACM14/PACM14, PA MACM16/PACM16, PA MACM18/PACM18, PA 6I/6T/MACMI/MACMT/PACMI/PACMT/12 and mixtures thereof.
7. The polyamide moulding compound according to claim 6 , wherein
component (A) is selected from the group consisting of PA MACM14, PA MACM16, PA MACM18, PA MACMI/12, PA MACMI/MACMT/12, PA MACM10/1010, PA MACM14/1014, PA MACM16/1016, PA MACM18/1018, PA MACM12/PACM12, PA MACM14/PACM14, PA MACM16/PACM16, PA MACM18/PACM18 and mixtures thereof.
8. The polyamide moulding compound according to claim 1 , wherein
the partially crystalline polyamide (B) is selected from the group consisting of PA 616, PA 1016, and mixtures thereof.
9. The polyamide moulding compound according to claim 8 , wherein the partially crystalline polyamide (B) is PA 616.
10. The polyamide moulding compound according to claim 1 , wherein
the polyamide moulding compound contains precisely one amorphous or microcrystalline polyamide (A) and precisely one partially crystalline polyamide (B).
11. The polyamide moulding compound according to claim 1 , wherein
the haze of the polyamide moulding compound, measured on a moulded article produced from the polyamide moulding compound (2 mm thick plates with width and length: 60×60 mm) according to ASTM D1003 (2013), is <15%; and/or
the transparency, measured on a moulded article produced from the polyamide moulding compound (2 mm thick plates with width and length: 60×60 mm) according to ASTM D1003, is at least 80%.
12. The polyamide moulding compound according to claim 1 , wherein a test piece made of the polyamide moulding compound
has a modulus of elasticity in tension, determined according to ISO 527 (2012), of at least 1,000 MPa.
13. A moulded article comprising a polyamide moulding compound according to claim 1 .
14. The moulded article according to claim 13 , which is selected from the group consisting of decorative elements, sports articles, leisure articles, toys, household articles, components of spectacles, furniture coverings, insoles, construction and trim parts for appliances in the sanitary, hygiene and cosmetic field, parts for safety shoes, filter cups, inspection glasses, through-flow meters, bursting discs, containers, housings or housing parts for electrical and electronic appliances, depilators, measuring devices, infrared keys, mobile phones, players, personal digital assistants (PDA), smart phones or storage media, protective covers for mobile phones, trim parts in the computer and telecommunication field, pipes, hoses, films, and components of e-cigarettes.
15. The polyamide moulding compound of claim 1 , wherein the at least one additive of component (C) is selected from the group consisting of inorganic stabilisers, organic stabilisers, antiozonants, light-protection agents, UV absorbers or UV blockers, lubricants, colourants, marking agents, pigments, carbon black, graphite, graphene, carbon nanotubes, photochromic agents, antistatic agents, mould-release agents, condensation catalysts, chain regulators, defoamers, antiblocking agents, chain-lengthening additives, optical brighteners, IR absorbers, NIR absorbers, halogen-containing flame retardants, halogen-free flame retardants, metallic pigments, metal flakes, metal-coated particles, carbon fibres, metal fibres, plant fibres, polymer fibres, whiskers, and mineral fibres.