Chelating agents for quantum dot precursor materials in color conversion layers for micro-LEDs
A photocurable composition includes quantum dots, quantum dot precursor materials, a chelating agent, one or more monomers, and a photoinitiator. The quantum dots are selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range. The second wavelength band is different than the first wavelength band. The quantum dot precursor materials include metal atoms or metal ions corresponding to metal components present in the quantum dots. The chelating agent is configured to chelate the quantum dot precursor materials. The photoinitiator initiates polymerization of the one or more monomers in response to absorption of radiation in the second wavelength band.
1. A photocurable composition comprising:
quantum dots selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range, wherein the second wavelength band is different than the first wavelength band;
quantum dot precursor materials, wherein the quantum dot precursor materials comprise metal atoms or metal ions corresponding to metal components present in the quantum dots;
a chelating agent configured to chelate the quantum dot precursor materials;
one or more monomers; and
a photoinitiator that initiates polymerization of the one or more monomers in response to absorption of radiation in the second wavelength band.
2. The composition of claim 1 , wherein the composition comprises:
about 0.1 wt % to about 10 wt % of the quantum dots;
about 0.0001 wt % to about 10 wt % of the chelating agent;
about 0.5 wt % to about 5 wt % of the photoinitiator; and
about 1 wt % to about 90 wt % of the one or more monomers.
3. The composition of claim 2 , wherein the composition comprises about 1 wt % to about 2 wt % of the quantum dots.
4. The composition of claim 2 , wherein the composition further comprises a solvent.
5. The composition of claim 4 , wherein the composition comprises:
about 0.1 wt % to about 10 wt % of the quantum dots;
about 0.0001 wt % to about 10 wt % of the chelating agent;
about 0.5 wt % to about 5 wt % of the photoinitiator;
about 1 wt % to about 10 wt % of the one or more monomers; and
about 10 wt % to about 90 wt % of the solvent.
6. The composition of claim 5 , wherein the composition comprises about 2 wt % to about 3 wt % of the one or more monomers.
7. The composition of claim 1 , wherein the quantum dots comprise one or more III-V compounds.
8. The composition of claim 1 , wherein the quantum dots emit red, green or blue light.
9. The composition of claim 1 , wherein the chelating agent comprises a mono-thiol, a di-thiol, a thiocarbamate, a dithiocarbamate, a thiocarbonate, or a thiourea.
10. The composition of claim 9 , wherein each quantum dot of the quantum dots comprises one or more ligands coupled to an exterior surface of the quantum dot, wherein the ligands are selected from the group consisting of thioalkyl compounds and carboxyalkanes.
11. The composition of claim 9 , wherein the chelating agent comprises a mono-thiol selected from the group consisting of ethanethiol, propanethiols, butanethiols, pentanethiols, 1-hexadecanethiol, 2-ethylhexanethiol, 8-mercapto-1-octanol, 2-(2-methoxyethoxy)ethanethiol, 2-(trimethylsilyl)ethanethiol, 2-propene-1-thiol, thiophenols, dimercaptosuccinic acid, thioglycolic acid, thioacetic acid, glutathione, cysteine, mercaptoethanols, dithiothreitol/dithioerythritol, 2-mercaptoethanol, 2-mercaptoindole, furan-2-ylmethanethiol, 3-mercaptopropane-1,2-diol, 3-mercapto-1-propanesulfonic acid, 1-hexadecanethiol, and pentachlorobenzenethiol.
12. The composition of claim 9 , wherein the chelating agent comprises a di-thiol selected from the group consisting of 1-dithiols, 1,2-dithiols, and 1,3-dithiols, 1,2-benzene-dimethanethiol, 1,3-benzenedimethanethiol, 1,4-benzenedimethanethiol, 2,2′-(ethylenedioxy)diethanethiol, ethylene glycol bis-mercaptoacetate, tetra(ethylene glycol) dithiol, hexa(ethylene glycol) dithiol, 2,2′-thiodiethanethiol, and 1,16-hexadecanedithiol.
13. The composition of claim 9 , wherein the chelating agent comprises a thiocarbamate selected from the group consisting of R 1 R 2 N(C═S)OR 3 , where each of R 1 , R 2 , and R 3 is independently H, benzyl, substituted phenyl groups, C1-C16 linear or branched aliphatic chains, ethylene oxide oligomers, propylene oxide oligomers, copolymers of ethylene oxide and propylene oxide, and dimethylsiloxane oligomers.
14. The composition of claim 9 , wherein the chelating agent comprises a dithiocarbamate selected from the group consisting of R 1 R 2 N(C═S)SR 3 , where each of R 1 , R 2 and R 3 is independently H, benzyl, substituted phenyl groups, C1-C16 linear or branched aliphatic chains, ethylene oxide oligomers, propylene oxide oligomers, copolymers of ethylene oxide and propylene oxide, and dimethylsiloxane oligomers.
15. The composition of claim 9 , wherein the chelating agent comprises a thiocarbonate selected from the group consisting of R 1 O(C═O)S R 2 , where each of R 1 and R 2 is independently H, benzyl, substituted phenyl groups, C1-C16 linear or branched aliphatic chains, ethylene oxide oligomers, propylene oxide oligomers, copolymers of ethylene oxide and propylene oxide, and dimethylsiloxane oligomers.
16. The composition of claim 9 , wherein the chelating agent comprises a thiourea selected from the group consisting of R 1 R 2 N(C═S)NR 3 R 4 , where each of R 1 , R 2 , R 3 , and R 4 is independently H, benzyl, substituted phenyl groups, C1-C16 linear or branched aliphatic chains, ethylene oxide oligomers such as —(CH 2 CH 2 —O) n - with n=1˜50, propylene oxide oligomers such as —(CH 2 CH(CH 3 )—O) n - with n=1˜50, copolymers of ethylene oxide and propylene oxide, or dimethylsiloxane oligomers.
17. The composition of claim 1 , wherein the chelating agent comprises a di-amine, an amino acid, an amino alcohol, guanidine, or urea.
18. The composition of claim 1 , wherein the chelating agent comprises an alcohol or an acid.
19. The composition of claim 1 , wherein a surface tension of the composition is in a range of about 20 mN/m to about 60 mN/m.
20. The composition of claim 1 , wherein the one or more monomers comprise (meth)acrylate monomers.
21. A light-emitting device comprising:
a plurality of light-emitting diodes; and
a cured composition in contact with a surface through which radiation in a first wavelength band in the UV or visible light range is emitted from each of the light-emitting diodes, wherein the cured composition includes
quantum dots selected to emit radiation in a second wavelength band in the visible light range in response to absorption of the radiation in the first wavelength band from each of the light-emitting diodes,
quantum dot precursor materials, wherein the quantum dot precursor materials comprise metal atoms or metal ions corresponding to metal components present in the quantum dots,
a chelating agent bound to the quantum dot precursor materials, wherein the chelating agent is configured to inhibit aggregation of the quantum dot precursor materials,
a photopolymer, and
components of a photoinitiator that initiated polymerization of the photopolymer.
22. The device of claim 21 , further comprising:|
an additional plurality of light-emitting diodes; and
an additional cured composition in contact with an additional surface through which radiation in a third wavelength band is emitted from each of the additional plurality of light-emitting diodes, wherein the additional cured composition includes
a nanomaterial selected to emit radiation in a fourth wavelength band in the visible light range in response to absorption of radiation in the third wavelength band from each of the light-emitting diodes;
an additional photopolymer; and
components of an additional photoinitiator that initiated polymerization of the additional photopolymer in response to absorption of radiation in the third wavelength band.
23. The device of claim 21 , wherein a thickness of the cured composition is in a range of about 10 nm to about 100 microns.